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01.03.2013 | Research Paper

Synthesis and characterization of graphene-based nanocomposites with potential use for biomedical applications

verfasst von: Daniele Nuvoli, Valeria Alzari, Roberta Sanna, Sergio Scognamillo, Jenny Alongi, Giulio Malucelli, Alberto Mariani

Erschienen in: Journal of Nanoparticle Research | Ausgabe 3/2013

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Abstract

In the present study, graphene-based nanocomposites containing different amounts of nanofiller dispersed into Bis-GMA/tetraethyleneglycol diacrylate (Bis-GMA/TEGDA) polymer matrix have been prepared. In particular, the graphene dispersions, produced at high concentration (up to 6 mg/ml) by simple sonication of graphite in TEGDA monomer, have been used for the direct preparation of nanocomposite copolymers with Bis-GMA. The morphology of the obtained nanocomposites has been investigated as well as their thermal and mechanical properties. SEM analyses have clearly shown that graphene deeply interacts with the polymer matrix, thus resulting in a reinforcing effect on the material as proved by compression and hardness tests; at variance, graphene does not seem to affect the glass transition temperature of the obtained polymer networks.

Vorheriger Artikel Effect of temperature on the stability of diamond particles and continuous thin films by Raman imaging

Nächster Artikel Gemcitabine-loaded magnetic albumin nanospheres for cancer chemohyperthermia

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Aguilar MR, Elvira C, Gallardo A, Vázquez B, Román JS (2007) Smart polymers and their applications as biomaterials. In: Ashammakhi N, Reis R, Chiellini E (eds) Topics in tissue engineering vol 3. University of Oulu, Oulu, Finland

Aizawa T, Souda R, Otani S, Ishizawa Y, Oshima C (1990) Anomalous bond of monolayer graphite on transition-metal carbide surfaces. Phys Rev Lett 64:768–771CrossRef

Alzari V, Nuvoli D, Scognamillo S, Piccinini M, Gioffredi E, Malucelli G, Marceddu S, Sechi M, Sanna V, Mariani A (2011a) Graphene-containing nanocomposite hydrogels of poly(N-isopropylacrylamide) prepared by frontal polymerization. J Mater Chem 21:8727–8733CrossRef

Alzari V, Nuvoli D, Sanna R, Scognamillo S, Piccinini M, Kenny JM, Malucelli G, Mariani A (2011b) In situ production of high filler content graphene-based polymer nanocomposites by reactive processing. J Mater Chem 21:16544–16549CrossRef

Ansari S, Giannelis EP (2009) Functionalized graphene sheetpoly(vinylidene fluoride) conductive nanocomposites. J Polym Sci Part B Polym Phys 47:888–897CrossRef

Antonucci JM, Stansbury JW (1997) Molecular designed dental polymer. In: Arshady R (ed) Desk reference of functional polymers: synthesis and application. American Chemical Society, Publication, pp 719–738

Balandin AA, Ghosh S, Bao W, Calizo I, Teweldebrhan D, Miao F, Ning Lau C (2008) Superior thermal conductivity of single-layer graphene. Nano Lett 8:902–907CrossRef

Ballo AM, Närhi TO, Akca EA, Ozenm T, Syrjänen SM, Lassila LVJ, Vallittu PK (2011) Prepolymerized vs. in situ-polymerized fiber-reinforced composite implants—a pilot study. J Dent Res 90:263–267CrossRef

Berger C, Song Z, Li X, Wu X, Brown N, Naud C, Mayou D, Li T, Hass J, Marchenkov AN, Conrad EH, First PN, de Heer WA (2006) Electronic confinement and coherence in patterned epitaxial graphene. Science 312:1191–1196CrossRef

Boukhvalov DW, Katsnelson MI (2008) Modeling of graphite oxide. J Am Chem Soc 130:10697–10701CrossRef

Bowen RL (1962) Dental filling material comprising vinyl silane treated fused silica and a binder consisting of the reaction product of bisphenol and glycidyl acrylate. U.S. Patent 3066112

Bowen RL (1963) Properties of a silica-reinforced polymer for dental restorations. J Am Dent Assoc 66:57–64

Bowen RL (1965) Method of preparing a monomer having phenoxy and methacrylate groups linked by hydroxy glycerol groups. U.S. Patent 3179623

Chen M, Chen C, Hsu S, Sun SH, Su W (2005) Low shrinkage light curable nanocomposite for dental restorative material. Dent Mater 22:138–145CrossRef

Coleman JN (2013) Liquid exfoliation of defect-free graphene. Acc Chem Res 46:14–22CrossRef

Fan H, Wang L, Zhao K, Li N, Shi Z, Ge Z, Jin Z (2010) Fabrication, mechanical properties, and biocompatibility of graphene-reinforced chitosan composites. Biomacromolecules 11:2345–2351CrossRef

Ferrari AC, Meyer JC, Scardaci V, Casiraghi C, Lazzeri M, Mauri F, Piscanec S, Jiang D, Novoselov KS, Roth S, Geim AK (2006) Quantifying defects in graphene via Raman spectroscopy at different excitation energies. Phys Rev Lett 97:187401–187403CrossRef

Garboczi EJ, Snyder KA, Douglas JF, Thorpe MF (1995) Geometrical percolation-threshold of overlapping ellipsoids. Phys Rev E 52:819–828CrossRef

Hernandez Y, Nicolosi V, Lotya M, Blighe FM, Sun Z, De S, McGovern IT, Holland B, Byrne M, Gun’ko YK, Boland JJ, Niraj P, Duesberg G, Krishnamurthy S, Goodhue R, Hutchison JH, Scardaci V, Ferrari AC, Coleman JN (2008) High-yeld production of graphene by liquid-phase exfoliation of graphite. Nat Nantechnol 3:563–568CrossRef

Khan U, O’Neill A, Lotya M, De S, Coleman JN (2010) High-concentration solvent exfoliation of graphene. Small 6:864–871CrossRef

Khan U, Porwal H, O’Neill A, Nawaz K, May P, Coleman JN (2011) Solvent-exfoliated graphene at extremely high concentration. Langmuir 27:9077–9082CrossRef

Kim H, Abdala AA, Macosko CW (2010) Graphene/polymer. nanocomposites. Macromolecules 43:6515–6530CrossRef

Lee C, Wei X, Kysar JW, Hone J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321:385–388CrossRef

Lerf A, He H, Forster M, Klinowski J (1998) Structure of graphite oxide revisited. J Phys Chem B 102:4477–4482CrossRef

Li X, Zhang G, Bai X, Sun X, Wang X, Wang E, Dai H (2008) Highly conducting graphene sheets and Langmuir-Blodgett films. Nat Nanotechnol 3:538–542CrossRef

Lu X, Yu M, Huang H, Ruoff RS (1999) Tailoring graphite with the goal of achieving single sheets. Nanotechnology 10:269–272CrossRef

Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA (2004) Electric field effect in atomically thin carbon films. Science 306:666–669CrossRef

Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA (2005) Two-dimensional gas of massless Dirac fermions in graphene. Nature 438:197–200CrossRef

Nuvoli D, Valentini L, Alzari V, Scognamillo S, Bittolo Bon S, Piccinini M, Illescas J, Mariani A (2011) High concentration few-layer graphene sheets obtained by liquid phase exfoliation of graphite in ionic liquid. J Mater Chem 21:3428–3431CrossRef

Nuvoli D, Alzari V, Sanna R, Scognamillo S, Piccinini M, Peponi L, Kenny JM, Mriani A (2012) The production of concentrated dispersions of few-layer graphene by the direct exfoliation of graphite in organosilanes. Nanoscale Res Lett 7:674–680CrossRef

Palussière J, Berge J, Gangi A, Cotten A, Pasco A, Bertagnoli R, Jaksche H, Carpeggiani P, Deramond H (2005) Clinical results of an open prospective study of a bis-GMA composite in percutaneous vertebral augmentation. Eur Spine J 14:982–991CrossRef

Park S, Ruoff RS (2009) Chemical methods for the production of graphenes. Nat Nanotechnol 4:217–224CrossRef

Ponomarenko L, Schedin F, Katsnelson MI, Yang R, Hill EW, Novoselov KS, Geim AK (2008) Chaotic Dirac billiard in graphene quantum dots. Science 320:356–358CrossRef

Potts JR, Dreyer DR, Bielawski CW, Ruoff RS (2011) Graphene-based polymer nanocomposites. Polymer 52:5–25CrossRef

Rafiee MA, Rafiee J, Wang Z, Song H, Yu ZZ, Koratkar N (2009) Enhanced mechanical properties of nanocomposites at low graphene content. ACS Nano 3:3884–3890CrossRef

Ramanathan T, Abdala AA, Stankovich S, Dikin DA, Herrera-Alonso M, Piner RD, Adamson DH, Schniepp HC, Chen X, Ruoff RS, Nguyen ST, Aksay IA, Prud’Homme RK, Brinson LC (2008) Functionalized graphene sheets for polymer nanocomposites. Nat Nanotechnol 3:327–331CrossRef

Roberson TM, Heyman H, Swift EJ (2002) Sturdevant’s art and science of operative dentistry, 4th edn. Mosby Elsevier, St Louis

Sanchez VC, Jachak A, Hurt RH, Kane AB (2012) Biological interactions of graphene-family nanomaterials: an interdisciplinary review. Chem Res Toxicol 25:15–34

Sanna R, Sanna D, Alzari V, Nuvoli D, Scognamillo S, Piccinini M, Lazzari M, Gioffredi E, Malucelli G, Mariani A (2012) Synthesis and characterization of graphene-containing thermoresponsive nanocomposite hydrogels of poly(N-vinylcaprolactam) prepared by frontal polymerization. J Pol Sci Part A Polym Chem 50:4110–4118CrossRef

Sasidharan A, Panchakarla LS, Chandran P, Menon D, Nair S, Rao CNR, Koyakutty M (2011) Differential nano-bio interactions and toxicity effects of pristine versus functionalized graphene. Nanoscale 3:2461–2464

Sasidharan A, Panchakarla LS, Chandran P, Menon D, Nair S, Rao CNR, Koyakutty M (2012) Graphene nanocomposite for biomedical applications: fabrication, antimicrobial and cytotoxic investigations. Nanotechnology 23:395101–395111CrossRef

Schedin F, Geim AK, Morozov SV, Hill EW, Blake P, Katsnelson MI, Novoselov KS (2007) Detection of individual gas molecules adsorbed on graphene. Nat Mater 6:652–655CrossRef

Scognamillo S, Gioffredi E, Piccinini M, Lazzari M, Alzari V, Nuvoli D, Sanna R, Piga D, Malucelli G, Mariani A (2012) Synthesis and characterization of nanocomposites of thermoplastic polyurethane with both graphene and graphene nanoribbon fillers. Polymer 53:4019–4024CrossRef

Slonczewski JC, Weiss PR (1958) Band structure of graphite. Phys Rev 109:272–279CrossRef

Sofo JO, Chaudhari AS, Barber GD (2007) Graphane: a two-dimensional hydrocarbon. Phys Rev B 75:153401–153404CrossRef

Soh MS, Sellinger A, Yap AUJ (2006) Dental nanocomposites. Curr Nanosci 2:373–381CrossRef

Stankovich S, Dikin DA, Dommett GHB, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen ST, Ruoff RS (2006) Graphene-based composite materials. Nature 442:282–286CrossRef

Stoller MD, Park S, Zhu Y, An J, Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 8:3498–3502CrossRef

Tuusa SM, Peltola MJ, Tirri T, Lassila LV, Vallittu PK (2007) Frontal bone defect repair with experimental glass-fiber-reinforced composite with bioactive glass granule coating. J Biomed Mater Res B Appl Biomater 82:149–155

Verdejo R, Barroso-Bujans F, Rodriguez-Perez MA, de Saja JA, Lopez-Manchado MA (2008) Functionalized graphene sheet filled silicone foam nanocomposites. J Mater Chem 18:2221–2226CrossRef

Wang X, Zhi L, Müllen K (2008) Transparent, conductive graphene electrodes for dye-sensitized solar cells. Nano Lett 8:323–327CrossRef

Wang X, Li X, Zhang L, Yoon Y, Weber PK, Wang H, Guo J, Dai H (2009) N-doping of graphene through electrothermal reactions with ammonia. Science 324:768–771CrossRef

Yoo E, Kim J, Hosono E, Zhou H, Kudo T, Honma I (2008) Large reversible Li storage of graphene nanosheet families for use in rechargeable lithium ion batteries. Nano Lett 8:2277–2282CrossRef

Zhao DS, Moritz N, Laurila P, Mattila R, Lassila LV, Strandberg N, Mäntylä T, Vallittu P, Aro HT (2009) Development of a multi-component fiber-reinforced composite implant for load-sharing conditions. Med Eng Phys 31:461–469CrossRef

Titel: Synthesis and characterization of graphene-based nanocomposites with potential use for biomedical applications
verfasst von: Daniele Nuvoli
Valeria Alzari
Roberta Sanna
Sergio Scognamillo
Jenny Alongi
Giulio Malucelli
Alberto Mariani
Publikationsdatum: 01.03.2013
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 3/2013
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-013-1512-x

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