Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 2/2017

09.11.2016

Synthesis and characterization of new triphenylamine-based dyes with novel anchoring groups for dye-sensitized solar cell applications

verfasst von: Alireza Salimi Beni, Behzad Hosseinzadeh, Masoume Azari, Raheleh Ghahary

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 2/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Three new chromophores based on the triphenylamine (MM, DM, DN) with various novel electron withdrawing anchoring groups have been synthesized for use in dye-sensitized solar cells (DSSCs). The sensitizers were characterized by 1H and 13C NMR, Mass, UV–Vis, and electrochemical analysis. The HOMO and LUMO electron distributions of the sensitizers were calculated using density functional theory on a B3LYP level for geometry optimization. The DSSC device based on DM dye showed the best photovoltaic performance among MM and DN dyes: maximum monochromatic incident photon-to-current conversion efficiency (IPCE) of 98 %, short circuit current (J SC) of 4.58 mA/cm2, open circuit voltage (V OC) of 0.62 V, fill factor (FF) of 0.77, and overall power conversion efficiency (PCE) of 2.01 %. The results reveal that the difference in number and type of anchoring groups of the dyes significantly influence the photovoltaic performance of their DSSCs.
Vorheriger Artikel Co-precipitation synthesis of V-doped titania: influence of vanadium concentration on the structural and optical properties
Nächster Artikel Enhanced photocatalytic activity and photoelectrochemical performance of InOOH nanosheets prepared via a facile solvothermal route

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
B. O’Regan, M. Gratzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 353, 737–740 (1991)CrossRef
2.
M.K. Nazeeruddin, A. Kay, A.I. Rodicio, R. Humphry-Baker, E. Muller, P. Liska, N. Vlachopoulos, M. Gratzel, Conversion of light to electricity by cis-X2bis(2,2′-bipyridyl-4,4′-dicarboxylate)ruthenium(II) charge-transfer sensitizers (X = Cl−, Br−, I−, CN−, and SCN−) on nanocrystalline titanium dioxide electrodes. J. Am. Chem. Soc. 115, 6382–6390 (1993)CrossRef
3.
M.K. Nazeeruddin, S.M. Zakeeruddin, R. Humphry-Baker, M. Jirousek, P. Liska, N. Vlachopoulos, V. Shklover, C.H. Fisher, M. Gratzel, Acid–base equilibria of (2,2′-bipyridyl-4,4′-dicarboxylic acid)ruthenium(II) complexes and the effect of protonation on charge-transfer sensitization of nanocrystalline titania. Inorg. Chem. 38, 6298–6305 (1999)CrossRef
4.
M.K. Nazeeruddin, P. Pechy, T. Renouard, S.M. Zakeeruddin, R. Humphry-Baker, P. Comte, P. Liska, L. Cevey, E. Costa, V. Shklover, L. Spiccia, G.B. Deacon, C.A. Bignozzi, M. Gratzel, Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2-based solar cells. J. Am. Chem. Soc. 123, 1613–1624 (2001)CrossRef
5.
W. Zeng, Y. Cao, Y. Bai, Y. Wang, Y. Shi, M. Zhang, F. Wang, C. Pan, P. Wang, Efficient dye-sensitized solar cells with an organic photosensitizer featuring orderly conjugated ethylenedioxythiophene and dithienosilole blocks. Chem. Mater. 22, 1915–1925 (2010)CrossRef
6.
K. Sayama, S. Tsukagoshi, K. Hara, Y. Ohga, A. Shinpou, Y. Abe, S. Suga, H. Arakawa, Photoelectrochemical properties of j aggregates of benzothiazole merocyanine dyes on a nanostructured TiO2 film. Phys. Chem. B 106, 1363–1371 (2002)CrossRef
7.
Z.-S. Wang, F.-Y. Li, C.-H. Huang, Photocurrent enhancement of hemicyanine dyes containing RSO3 − group through treating TiO2 films with hydrochloric acid. Phys. Chem. B 105, 9210–9217 (2001)CrossRef
8.
K. Kalyanasundaram, M. Grätzel, Applications of functionalized transition metal complexes in photonic and optoelectronic devices. Coord. Chem. Rev. 177, 347–414 (1998)CrossRef
9.
D. Liu, R.W. Fessenden, G.L. Hug, P.V. Kamat, Dye capped semiconductor nanoclusters. Role of back electron transfer in the photosensitization of SnO2 nanocrystallites with cresyl violet aggregates. Phys. Chem. B101, 2583–2590 (1997)
10.
N. Koumura, Z.S. Wang, S. Mori, M. Miyashita, E. Suzuki, K. Hara, Alkyl-functionalized organic dyes for efficient molecular photovoltaics. J. Am. Chem. Soc. 128, 14256–14257 (2006)CrossRef
11.
K.R.J. Thomas, A. Baheti, P. Singh, C.P. Lee, K.C. Ho, 2,7-Diaminofluorene-based organic dyes for dye-sensitized solar cells: effect of auxiliary donor on optical and electrochemical properties. J. Org. Chem. 76, 4910–4920 (2011)CrossRef
12.
J.K. Lee, M. Yang, Progress in light harvesting and charge injection of dye-sensitized solar cells. J. Mater. Sci. Eng. B. 176, 1142–1160 (2011)CrossRef
13.
S.Y. Qu, J.L. Hua, H. Tian, New D–π–A dyes for efficient dye-sensitized solar cells. Sci. China Chem. 55, 677–697 (2012)CrossRef
14.
M. Behl, E. Hattemer, M. Brehmer, R. Zentel, Tailored semiconducting polymers: living radical polymerization and NLO-functionalization of triphenylamines. Macromol. Chem. Phys. 203, 503–510 (2002)CrossRef
15.
S. Ito, T. Murakami, P. Comte, P. Liska, C. Grätzel, M. Nazeeruddin, M. Grätzel, Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10 %. Thin Solid Films 516, 4613–4619 (2008)CrossRef
16.
Q. Wang, S. Ito, M. Gratzel, F. Fabregat-Santiago, I. Mora-Sero, J. Bisquert et al., Characteristics of high efficiency dye-sensitized solar cells. J. Phys. Chem. B. 110, 25210–25221 (2006)CrossRef
17.
X. Ren, Q. Feng, G. Zhou, C.-H. Huang, Z.S. Wang, Effect of cations in coadsorbate on charge recombination and conduction band edge movement in dye-sensitized solar cells. J. Phys. Chem. C. 114, 7190–7195 (2010)CrossRef
18.
J. Tang, J.L. Hua, W.J. Wu, J. Li, Z.G. Jin, Y.T. Long, H. Tian, New starburst sensitizer with carbazole antennas for efficient and stable dye-sensitized solar cells. Energy Environ. Sci. 3, 1736–1745 (2010)CrossRef
19.
S. Roquet, A. Cravino, P. Leriche, O. Alévêque, P. Frere, J. Roncali, Triphenylamine-thienylenevinylene hybrid systems with internal charge transfer as donor materials for heterojunction solar cells. J. Am. Chem. Soc. 128, 3459–3466 (2006)CrossRef
20.
C. Teng, X. Yang, C. Yang, H. Tian, S. Li, X. Wang, A. Hagfeldt, L. Sun, Influence of triple bonds as π-spacer units in metal-free organic dyes for dye-sensitized solar cells. J. Phys. Chem. C 114, 11305–11313 (2010)CrossRef
21.
W.M. Campbell, A.K. Burrell, D.L. Officer, K.W. Jolley, Porphyrins as light harvesters in the dye-sensitised TiO2 solar cel. Coord. Chem. Rev. 248, 1363–1379 (2004)CrossRef
22.
R. Kern, R. Sastrawan, J. Ferber, R. Stangl, J. Luther, Modeling and interpretation of electrical impedance spectra of dye solar cells operated under open-circuit conditions. Electrochim. Acta 47, 4213–4225 (2002)CrossRef
23.
Q. Wang, J. Moser, M. Gratzel, Electrochemical impedance spectroscopic analysis of dye-sensitized solar cells. J. Phys. Chem. B 109, 14945–14953 (2005)CrossRef
24.
N. Koide, A. Islam, Y. Chiba, L. Han, Improvement of efficiency of dye-sensitized solar cells based on analysis of equivalent circuit. J. Photochem. Photobiol. A 182, 296–305 (2006)CrossRef
25.
M. Cheng, X. Yang, J. Li, C. Chen, J. Zhao, Y. Wang, L. Sun, Dye-sensitized solar cells based on a donor–acceptor system with a pyridine cation as an electron-withdrawing anchoring group. Chem. Eur J. 18, 16196–16202 (2012)CrossRef
26.
D. Wang, W. Ying, X. Zhang, Y. Hu, W. Wu, J. Hua, Near-infrared absorbing isoindigo sensitizers: synthesis and performance for dye-sensitized solar cells. Dyes Pigments 112, 327–334 (2015)CrossRef
27.
Z. Huang, H. Feng, X. Zang, Z. Iqbal, H. Zeng, D. Kuang, L. Wang, H. Meier, D. Cao, Dithienopyrrolobenzothiadiazole-based organic dyes for efficient dye-sensitized solar cells. J. Mater. Chem. A. 2, 15365–15376 (2014)CrossRef
Metadaten
Titel
Synthesis and characterization of new triphenylamine-based dyes with novel anchoring groups for dye-sensitized solar cell applications
verfasst von
Alireza Salimi Beni
Behzad Hosseinzadeh
Masoume Azari
Raheleh Ghahary
Publikationsdatum
09.11.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 2/2017
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-016-5737-1

Weitere Artikel der Ausgabe 2/2017

Journal of Materials Science: Materials in Electronics 2/2017 Zur Ausgabe

OriginalPaper

Brain-like cobalt manganese oxide nano-composites coated on glass surface for enhanced photocatalytic degradation of Black Nilusun: effect of precursors on properties

OriginalPaper

Energy-storage performance and pyroelectric energy harvesting effect of PNZST antiferroelectric thin films

OriginalPaper

Electrodeposition and characterization of pH transformed Cu2O thin films for electrochemical sensor

OriginalPaper

Growth of hierarchical strontium incorporated cadmium sulphide for possible application in optical and electronic devices

OriginalPaper

Pitch carbon coating graphene/carbon nanotubes lightweight composite and their excellent microwave absorption capacity

OriginalPaper

Improved fatigue property of hafnium substitute lead zirconate titanate deposited by pulse laser deposition

Neuer Inhalt

    Bildnachweise