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Polymer Bulletin
Erschienen in: Polymer Bulletin 6/2009

01.12.2009 | Original Paper

Synthesis and properties of amino acid-derived optically active photo-responsive polymers

verfasst von: Hiromitsu Sogawa, Kayo Terada, Toshio Masuda, Fumio Sanda

Erschienen in: Polymer Bulletin | Ausgabe 6/2009

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Abstract

Optically active azobenzenedicarboxylic acids were synthesized from l-alanine, and the polycondensation of the diacids with o-, m-, p-xylylenediols, 5-norbornene-2,3-endo,endo- and exo,exo-dimethanols, m-, p-xylylenediamines, and trans-1,4-cyclohexanediamine was carried in N,N-dimethylformamide. Polymers with weight-average molecular weights of 3,300–33,700 were obtained in 63%-quantitative yields. All the polymers reversibly isomerized the azobenzene units from trans to cis and vice versa upon UV- and visible-light irradiations. The polymers exhibited no evidence for the formation of a chiral secondary structure.
Vorheriger Artikel Synthesis of ABC miktoarm star block copolymers from a new heterotrifunctional initiator by combination of ATRP and ROP
Nächster Artikel Fluorene oligomer with tetrathiafulvalenes as pendant groups: synthesis, electrochemical and spectroscopic properties

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Metadaten
Titel
Synthesis and properties of amino acid-derived optically active photo-responsive polymers
verfasst von
Hiromitsu Sogawa
Kayo Terada
Toshio Masuda
Fumio Sanda
Publikationsdatum
01.12.2009
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 6/2009
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-009-0121-4

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