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27.06.2018 | Mechanochemical Synthesis

Synthesis, characterization and in situ monitoring of the mechanochemical reaction process of two manganese(II)-phosphonates with N-containing ligands

verfasst von: Irina Akhmetova, Konstantin Schutjajew, Manuel Wilke, Ana Buzanich, Klaus Rademann, Christina Roth, Franziska Emmerling

Erschienen in: Journal of Materials Science | Ausgabe 19/2018

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Abstract

Two divalent manganese aminophosphonates, manganese mono(nitrilotrimethylphosphonate) (MnNP₃) and manganese bis(N-(carboxymethyl)iminodi(methylphosphonate)) (Mn(NP₂AH)₂), have been prepared by mechanochemical synthesis and characterized by powder X-ray diffraction (PXRD). The structure of the novel compound Mn(NP₂AH)₂ was determined from PXRD data. MnNP₃ as well as Mn(NP₂AH)₂ exhibits a chain-like structure. In both cases, the manganese atom is coordinated by six oxygen atoms in a distorted octahedron. The local coordination around Mn was further characterized by extended X-ray absorption fine structure. The synthesis process was followed in situ by synchrotron X-ray diffraction revealing a three-step reaction mechanism. The as-prepared manganese(II) phosphonates were calcined on air. All samples were successfully tested for their suitability as catalyst material in the oxygen evolution reaction.

Vorheriger Artikel The effect of ball mass on the mechanochemical transformation of a single-component organic system: anhydrous caffeine

Nächster Artikel Advanced characterization technique for mechanochemically synthesized materials: neutron total scattering analysis

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Titel: Synthesis, characterization and in situ monitoring of the mechanochemical reaction process of two manganese(II)-phosphonates with N-containing ligands
verfasst von: Irina Akhmetova
Konstantin Schutjajew
Manuel Wilke
Ana Buzanich
Klaus Rademann
Christina Roth
Franziska Emmerling
Publikationsdatum: 27.06.2018
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 19/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-018-2608-6

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