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Erschienen in: Polymer Bulletin 2/2009

01.02.2009 | Original Paper

Synthesis, characterization, and optical properties of a novel alternating 3-dodecyloxythiophene-co-pyridine copolymer

verfasst von: He Yanfang, Qi Zhengjian, Yu Jing, Wang Xuemei, Wei Bin, Sun Yueming

Erschienen in: Polymer Bulletin | Ausgabe 2/2009

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Abstract

A novel soluble alternating conjugated copolymer, comprised of 3-dodecyloxythiophene and pyridine moieties, was synthesized via the Heck Couple approach. Regioregular poly(3-dodecyloxythiophenel) synthesized by McCullough was also studied for comparison. The obtained polymers were characterized by 1H NMR, HR-MS, gel permeation chromatography, UV–Vis spectroscopy, photoluminescence and Cyclic voltammetry. The photoluminescence of the copolymer exhibited extraordinary bright blue. The electrochemical study shows that the new alternating copolymer does not merely have the properties of the two units that constitute it but has mutual hole and electron charge carrier properties which might be promising material for applications in high efficiency, single or low number layers functional devices.

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Metadaten
Titel
Synthesis, characterization, and optical properties of a novel alternating 3-dodecyloxythiophene-co-pyridine copolymer
verfasst von
He Yanfang
Qi Zhengjian
Yu Jing
Wang Xuemei
Wei Bin
Sun Yueming
Publikationsdatum
01.02.2009
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 2/2009
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-008-0006-y

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