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Polymer Bulletin
Erschienen in: Polymer Bulletin 2/2009

01.02.2009 | Original Paper

Synthesis of pure (Co) polymers via supported cobalt (II)-catalyzed controlled/“living” radical polymerization

verfasst von: Huiqing Chen, Zhongxi Huang, Hong Li, Yongming Zhang, Yangang Liu

Erschienen in: Polymer Bulletin | Ausgabe 2/2009

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Abstract

Cross-linked polyacrylic resin supported-cobalt (II) catalyst was successfully employed in controlled/“living” radical polymerization of various monomers including n-butyl acrylate (BA), ethyl methacrylate (EMA) and styrene (St). Well-defined polymers with predetermined molecular weight and relatively narrow molecular weight distribution were synthesized. After polymerization, the supported cobalt (II) catalyst was easily and effectively removed from the polymerization system by simple centrifugation and very pure polymer products were obtained (Co residue <0.1 ppm). Using the obtained polymers as macroinitiators, polymerization of methyl methacrylate (MMA) and fluorinated methacrylate ether 2-[(perfluorononenyl)oxyl] ethyl methacrylate (FNEMA) were performed, respectively. Well-defined and pure diblock copolymers PBA-b-PMMA, PS-b-PMMA and PS-b-PFNEMA were synthesized.
Vorheriger Artikel Synthesis, characterization, and optical properties of a novel alternating 3-dodecyloxythiophene-co-pyridine copolymer
Nächster Artikel pH Sensitive hydrogels based on acryl amides and their swelling and diffusion characteristics with drug delivery behavior

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Literatur
1.
Wang JS, Matyjaszewski K (1995) Controlled living radical polymerization-atom-transfer radical polymerization in the presence of transition-metal complexes. J Am Chem Soc 117(20):5614–5615CrossRef
2.
Kato M, Kamigaito M, Sawamoto M, Higashimura T (1995) Polymerization of methyl methacrylate with the carbon tetrachloridel dichlorotris-(triphenylphosphine)ruthedum(II)/methylaluminum bis(2,6-di-tert-butylphenoxide) initiating system: possibility of living radical polymerization. Macromolecules 28(5):1721–1723CrossRef
3.
Matyjaszewski K, Xia JH (2001) Atom transfer radical polymerization. Chem Rev 101(9):2921–2990CrossRef
4.
Kamigaito M, Ando T, Sawamoto M (2001) Metal-catalyzed living radical polymerization. Chem Rev 101(12):3689–3745CrossRef
5.
Davis KA, Matyjaszewski K (2002) Statistical, gradient, block, and graft copolymers by controlled/living radical polymerizations. Adv Polym Sci 159:1–169CrossRef
6.
Hansen NML, Jankova K, Hvilsted S (2007) Fluoropolymer materials and architectures prepared by controlled radical polymerizations. Eur Polym J 43(2):255–293CrossRef
7.
Braunecker WA, Matyjaszewski K (2007) Controlled/living radical polymerization: features, developments, and perspectives. Prog Poly Sci 32(1):93–146CrossRef
8.
Tsarevsky NV, Matyjaszewski K (2006) Environmentally benign atom transfer radical polymerization: towards “green” processes and materials. J Polym Sci Part A Polym Chem 44(17):5098–5112CrossRef
9.
Tsarevsky NV, Matyjaszewski K (2007) “Green” atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials. Chem Rev 107(6):2270–2299CrossRef
10.
Faucher S, Zhu SP (2007) Fundamentals and development of high-efficiency supported catalyst systems for atom transfer radical polymerization. J Polym Sci Part A Polym Chem 45(4):553–565CrossRef
11.
Grignard B, Jerome C, Calberg C, Jerome R, Wang W, Howdle SM, Detrembleur C (2008) Copper bromide complexed by fluorinated macroligands: towards microspheres by ATRP of vinyl monomers in scCO(2). Chem Commun 314–316
12.
Jakubowski W, Matyjaszewski K (2006) Activators regenerated by electron transfer for atom-transfer radical polymerization of (meth)acrylates and related block copolymers. Angew Chem Int Ed 45(27):4482–4486CrossRef
13.
Jakubowski W, Min K, Matyjaszewski K (2006) Activators regenerated by electron transfer for atom transfer radical polymerization of styrene. Macromolecules 39(1):39–45CrossRef
14.
Shen YQ, Tang HD, Ding SJ (2004) Catalyst separation in atom transfer radical polymerization. Prog Polym Sci 29(10):1053–1078CrossRef
15.
Huang ZX, Zhang YM, Li H, Liu YG (2008) Controlled/“living” radical polymerization of methyl methacrylate catalyzed by cobalt acetate. Macromol Chem Phys 209(8):825–831CrossRef
16.
Huang ZX, Zhang YM, Li H, Luan YH, Liu YG (2008) Atom transfer radical polymerization of methyl methacrylate catalyzed by ion exchange resin immobilized Co(II) hybrid catalyst. J Polym Sci Part A Polym Chem 46(4):1416–1426CrossRef
17.
Huang ZX, Zhang YM, Li H, Liu YG (2007) A novel immobilized cobalt(II)/copper(II) bimetallic catalyst for atom transfer radical polymerization (ATRP) of methyl methacrylate. Appl Cata A Gen 332(2):192–199CrossRef
18.
Davis KA, Matyjaszewski K (2000) Atom transfer radical polymerization of tert-butyl acrylate and preparation of block copolymers. Macromolecules 33(11):4039–4047CrossRef
19.
Garcia MF, de la Fuente JL, Fernandez-Sanz M, Madruga EL (2001) The importance of solvent polar character on the synthesis of PMMA-b-PBA block copolymers by atom transfer radical polymerization. Polymer 42(23):9405–9412CrossRef
20.
Matyjaszewski K, Nakagawa Y, Jasieczek CB (1998) Polymerization of n-butyl acrylate by atom transfer radical polymerization. Remarkable effect of ethylene carbonate and other solvents. Macromolecules 31(5):1535–1541CrossRef
21.
Tanaka K, Matyjaszewski K (2007) Controlled copolymerization of n-butyl acrylate with nonpolar 1-alkenes using activators regenerated by electron transfer for atom-transfer radical polymerization. Macromolecules 40(15):5255–5260CrossRef
22.
Zhang HQ, Van Der Linde R (2002) Atom transfer radical polymerization of n-butyl acrylate catalyzed by CuBr/N-(n-hexyl)-2-pyridylmethanimine. J Polym Sci Part A Polym Chem 40(21):3549–3561CrossRef
23.
Moineau G, Minet M, Dubois P, Teyssie P, Senninger T, Jerome R (1999) Controlled radical polymerization of (meth)acrylates by ATRP with NiBr2(PPh3)(2) as catalyst. Macromolecules 32(1):27–35CrossRef
24.
Wang JS, Matyjaszewski K (1995) “Living”/controlled radical polymerization. Transition-metal-catalyzed atom transfer radical polymerization in the presence of a conventional radical initiator. Macromolecules 28:7572–7573CrossRef
Metadaten
Titel
Synthesis of pure (Co) polymers via supported cobalt (II)-catalyzed controlled/“living” radical polymerization
verfasst von
Huiqing Chen
Zhongxi Huang
Hong Li
Yongming Zhang
Yangang Liu
Publikationsdatum
01.02.2009
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 2/2009
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-008-0008-9

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