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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 11/2018

19.03.2018

Synthesis, characterization and photovoltaic properties of phase pure Cu2SnSe3 nanostructures using molecular precursors

verfasst von: Adish Tyagi, Alpa Y. Shah, G. Kedarnath, Amey Wadawale, Vishal Singh, Deepak Tyagi, C. A. Betty, Champa Lal, Vimal K. Jain

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 11/2018

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Abstract

Phase pure Cu2SnSe3 (CTSe) nanostructures have been synthesized using metal selenolates, [Me2Sn{SeC5H3(Me-3)N}2] (molecular structure of [Me2Sn{SeC5H3(Me-3)N}2] has been established by single crystal X-ray analysis) and [Cu{SeC5H3(Me-3)N}]4 as molecular precursors in oleylamine (OLA) and tri-n-octylphosphine oxide (TOPO). The effect of temperature on final composition of nanostructures has also been investigated. Powder X-ray diffraction, Raman and X-ray photoelectron spectroscopy (XPS) were used to investigate the crystal structure, phase purity and homogeneity of the nanostructures while the electron microscopy revealed the morphology of the nanostructures. Superconducting quantum interference device (SQUID) measurements of CTSe nanostructures showed weak magnetic ordering at low temperature (below 50 K) attributed to the presence of some defect centres in the sample. The CTSe nanostructure possess an optical band gap of 1.7 eV deduced from diffuse reflectance spectroscopy (DRS) and showed photo response which makes them promising candidate for alternative low cost photon absorber material.
Vorheriger Artikel Synthesis and study of structural, dielectric, magnetic and magnetoelectric properties of K0.5Na0.5NbO3–CoMn0.2Fe1.8O4 composites
Nächster Artikel Preparation, structural, spectroscopic and magneto-electric properties of multiferroic cadmium doped neodymium manganite

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Metadaten
Titel
Synthesis, characterization and photovoltaic properties of phase pure Cu2SnSe3 nanostructures using molecular precursors
verfasst von
Adish Tyagi
Alpa Y. Shah
G. Kedarnath
Amey Wadawale
Vishal Singh
Deepak Tyagi
C. A. Betty
Champa Lal
Vimal K. Jain
Publikationsdatum
19.03.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 11/2018
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-018-8912-8

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