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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 12/2017

30.09.2017 | Original Contribution

Synthesis, characterization, and physicochemical properties of a series of quaternary gemini surfactants with different spacer lengths

verfasst von: Nilanjan Pal, Neha Saxena, Ajay Mandal

Erschienen in: Colloid and Polymer Science | Ausgabe 12/2017

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Abstract

The study deals with the synthesis and characterization, as well as the adsorption and micellization behavior (including thermodynamics) in aqueous solution of a series of gemini surfactants with different spacer lengths. The synthesized surfactants were characterized by FTIR, 1H-NMR, FESEM, EDX, and TGA analyses. DLS measurements showed that micelles formed at critical micelle concentration (CMC) transformed into an assemblage of micelles and micellar agglomerates at higher concentrations. Surface tension was found to decrease with temperature and spacer length. However, CMC values increased with spacer length, as confirmed by surface tension and conductivity results. Surface adsorption parameters such as surface excess, minimum area, surfactant effectiveness, and efficiency were also determined. Gibbs free energy of adsorption (ΔG ads) value was found to be greater than Gibbs free energy of micellization (ΔG mic), showing that adsorption is more favored in aqueous gemini systems.
Vorheriger Artikel Simulation study on the conformational properties of an adsorbed polymer on a nanoparticle
Nächster Artikel Study of interaction between chitosan and sodium lauryl ether sulfate

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Literatur
1.
Menger FM, Littau CA (1991) Gemini-surfactants: synthesis and properties. J Am Chem Soc 113:1451–1452CrossRef
2.
Zana R (1996) Gemini dimeric surfactants. Curr Opin Colloid Interface Sci 1:566–571CrossRef
3.
Zana R (2002) Dimeric and oligomeric surfactants. Behaviour at interfaces and in aqueous solution: a review. Adv Colloid Interface Sci 97:205–253CrossRef
4.
In M, Zana R (2007) Phase behavior of gemini surfactants. J Dispers Sci Technol 28:143–154CrossRef
5.
Zana R, Talmon Y (1993) Dependence of aggregate morphology on structure of dimeric surfactants. Letters to Nature 362:228–230CrossRef
6.
Li B, Zhang Q, Xia Y, Gao Z (2015) Surface properties and aggregation behavior of cationic gemini surfactants with dipropylammonium head-groups. Colloids Surf A Physicochem Eng Asp 470:211–217CrossRef
7.
Hegazy MA, Rashwan SM, Kamel MM, El Kotb MS (2015) Synthesis, surface properties and inhibition behavior of novel cationic gemini surfactant for corrosion of carbon steel tubes in acidic solution. J Mol Liq 211:126–134CrossRef
8.
Ghosh S, Chakraborty T, Soumen G, Tanushree C (2007) Mixed micelle formation among anionic gemini surfactant (212) and its monomer (SDMA) with conventional surfactants (C12E5 and C12E8) in brine solution at pH 11. J Phys Chem B 111:8080–8088CrossRef
9.
Zhou L, Jiang X, Li Y, Chen Z, Hu X (2007) Synthesis and properties of a novel class of gemini pyridinium surfactants. Langmuir 23:11404–11408CrossRef
10.
Fereidooni T, Azizian S, Wettig S (2017) Effect of spacer length on the interfacial behavior of N,N’-bis(dimethylalkyl)–α,ω-alkanediammonium dibromide gemini surfactants in the absence and presence of ZnO nanoparticles. J Colloid Interface Sci 486:204–210CrossRef
11.
Garcia MT, Kaczerewska O, Ribosa I, Materna P (2017) Hydrophilicity and flexibility of the spacer as critical parameters on the aggregation behavior of long alkyl chain cationic gemini surfactants in aqueous solution. J Mol Liq 230:453–460CrossRef
12.
Laschewsky A, Lunkenheimer K, Rakotoaly RH, Wattebled L (2005) Spacer effects in dimeric cationic surfactants. Colloid Polym Sci 283:469–479CrossRef
13.
Wang X, Wang J, Wang Y, Yan H, Li P, Thomas RK (2004) Effect of the nature of the spacer on the aggregation properties of gemini surfactants in an aqueous solution. Langmuir 20:53–56CrossRef
14.
Alimohammadi MH, Javadian S, Gharibi H, Tehrani-Bagha A, Alavijeh MR, Kakaei K (2012) Aggregation behavior and intermicellar interactions of cationic gemini surfactants: effects of alkyl chain, spacer lengths and temperature. J Chem Thermodyn 44:107–115CrossRef
15.
Rosen MJ, Tracy DJ (1998) Gemini Surfactants. J Surfactant Deterg 1:547–554CrossRef
16.
Okano T, Fukuda M, Tanabe J, Ono M, Akabane Y, Takahashi H, Egawa N, Sakotani T, Kanao H, Yoneyanna Y. 1997 US patent 5, 681, 803
17.
Choi T, Shimizu Y, Shirai H, Hamada K (2001) Disperse dyeing of nylon 6 fiber using gemini surfactants containing ammonium cations as auxiliaries. Dyes Pigments 48:4–13CrossRef
18.
Deyab MA (2007) Effect of cationic surfactant and inorganic anions on the electrochemical behavior of carbon steel in formation water. Corrosion Sci 49:2315–2328CrossRef
19.
Shahir AA, Rashidi-alavijeh M, Javadian S, Kakeman J, Yousefi A (2011) Fluid phase equilibria molecular interaction of Congo red with conventional and cationic gemini surfactants. Fluid Phase Equilib 305:219–226CrossRef
20.
Dreja M, Pyckhout-Hintzen W, Mays H, Tieke B (1999) Cationic gemini surfactants with oligo(oxyethylene) spacer groups and their use in the polymerization of styrene in ternary microemulsion. Langmuir 15:391–399CrossRef
21.
Masuyama A, Endo C, Takeda S, Nojima M, Ono D, Takeda T (2000) Ozone-cleavable gemini surfactants. Their surface-active properties, ozonolysis, and biodegradability. Langmuir 16:368–373CrossRef
22.
Diz M, Manresa A, Pinazo A, Erraa P, Infante MR (1994) Synthesis, surface active properties and antimicrobial activity of new bis-quaternary ammonium compounds. J Chem Soc Perkin Trans 2:1871–1876CrossRef
23.
Gao B, Sharma MM (2013) A family of alkyl sulfate gemini surfactants. 2. Water–oil interfacial tension reduction. J Colloid Interface Sci 407:375–381CrossRef
24.
Lang J, Jianli L, Zhen S 2013 Gemini surfactant, preparation method thereof, and application thereof in tertiary oil recovery, CN Patent 103173197 A,
25.
Trawi A, Hallmann E, M K. The effect of alkyl chain length on synergistic effects in micellization and surface tension reduction in nonionic gemini (S-10) and anionic surfactants mixtures. Colloids Surf A Physicochem Eng Asp 2016;506:114–126
26.
Pal N, Babu K, Mandal A (2016) Surface tension, dynamic light scattering and rheological studies of a new polymeric surfactant for application in enhanced oil recovery. J Pet Sci Eng 146:591–600CrossRef
27.
Babu K, Pal N, SaxenaVK MA (2016) Synthesis and characterization of a new polymeric surfactant for chemical enhanced oil recovery. Korean J Chem Eng 33:711–719CrossRef
28.
Chang H, Cui Y, Wei W, Li X, Gao W, Zhao X, Yin S (2017) Adsorption behavior and wettability by gemini surfactants with ester bond at polymer-solution-air systems. J Mol Liq 230:429–436CrossRef
29.
Pal N, Saxena N, Mandal A (2017) Phase behavior, solubilization, and phase transition of a microemulsion system stabilized by a novel surfactant synthesized from castor oil. J Chem Eng Data  62:1278–1291
30.
Sakai K, Izumi K, Sakai H, Abe M (2010) Polymerizable gemini surfactants at solid/solution interfaces: adsorption and polymerization on melamine formaldehyde particles and capsule fabrication. J Colloid Interface Sci 343:491–495CrossRef
31.
Babu K, Pal N, Bera A, Saxena VK, Mandal A (2015) Studies on interfacial tension and contact angle of synthesized surfactant and polymeric from castor oil for enhanced oil recovery. Appl Surf Sci 353:1126–1136CrossRef
32.
Alami E, Holmberg K, Eastoe J (2002) Adsorption properties of novel gemini surfactants with nonidentical head groups. J Colloid Interface Sci 455:447–455CrossRef
33.
Song LD, Rosen MJ (1996) Surface properties, micellization, and premicellar aggregation of gemini surfactants with rigid and flexible spacers. Langmuir 12:1149–1153CrossRef
34.
Sakai K, Umezawa S, Tamura M, Takamatsu Y, Tsuchiya K (2008) Adsorption and micellization behavior of novel gluconamide-type gemini surfactants. J Colloid Interface Sci 318:440–448CrossRef
35.
Cai B, Dong J, Cheng L, Jiang Z, Yang Y, Li X (2013) Adsorption and micellization of gemini surfactants with pyrrolidinium head groups: effect of the spacer length. Soft Matter 9:7637–7646CrossRef
36.
Zhou T, Liu S, You Y, Xu R, Zhao J (2016) Micellization and adsorption of heterogemini surfactants containing a hydroxyl headgroup in aqueous solution. J Chem Eng Data 61:2915–2922CrossRef
37.
Nguyen CV, Nguyen TV, Phan CM (2015) Dynamic adsorption of a gemini surfactant at the air/water interface. Colloids Surf A Physicochem Eng Asp 482:365–370CrossRef
38.
Parikh K, Mistry B, Jana S, Gupta S, Devkar RV, Kumar S (2015) Physico-biochemical studies on cationic gemini surfactants: role of spacer. J Mol Liq 206:19–28CrossRef
39.
Plet B, Manet S, Schmitter J, Huc I, Oda R, Escarpit R, Sauers RR, Romsted LS (2008) Competing gas-phase substitution and elimination reactions of gemini surfactants with anionic counterions by mass spectrometry. Density functional theory correlations with their bolaform halide salt models. J Phys Chem B 112:14435–14445CrossRef
40.
Jahan N, Paul N, Petropolis CJ, Marangoni DG, Grindley TB (2009) Synthesis of surfactants based on pentaerythritol. I. Cationic and zwitterionic gemini surfactants. J Org Chem 74:7762–7773CrossRef
41.
Zhu D, Cheng F, Cheng Y, Jiang S (2012) Preparation, characterization and properties of anionic gemini surfactants with long rigid or semi-rigid spacers. Colloids Surf A Physicochem Eng Asp 397:1–7CrossRef
42.
Serdyuk AA, Mirgorodskaya AB, Kapitanov IV, Gathergood N, Ya L, Sinyashin OG, Karpichev Y (2016) Effect of structure of polycyclic aromatic substrates on solubilization capacity and size of cationic monomeric and gemini 14-s-14 surfactant aggregates. Colloids Surf A Physicochem Eng Asp 509:613–622CrossRef
43.
Mobin M, Aslam R, Aslam J (2017) Non toxic biodegradable cationic gemini surfactants as novel corrosion inhibitor for mild steel in hydrochloric acid medium and synergistic effect of sodium salicylate: experimental and theoretical approach. Mater Chem Phys 191:151–167CrossRef
44.
Hussain SMS, Shahzad M, Abdullah K (2017) Amido-amine-based cationic gemini surfactants: thermal and interfacial properties and interactions with cationic polyacrylamide. J Surfactant Deterg 20:47–55CrossRef
45.
Cao X, Li Z, Song X, Cui X, Wei Y, Cheng F, Wang J (2009) Effects of spacers on surface activities and aggregation properties of anionic gemini surfactants. J Surfactants Deterg 12:165–172CrossRef
46.
Siddiqui US, Kumar S, Dar AA (2006) Micellization of monomeric and dimeric surfactants in polar nonaqueous-water-mixed solvents. Colloid Polym Sci 284:807–812CrossRef
47.
Williams RJ, Phillips JN, Mysels KJ (1954) The critical micelle concentration of sodium lauryl sulphate at 25°C. Trans Faraday Soc 51:728–737CrossRef
48.
Arkhipov VP, Idiyatullin ZS, Potapova EF, Antzutkin ON, Fillipov AV (2014) Micelles and aggregates of oxyethylated isononylphenols and their extraction properties near cloud point. J Phys Chem B 118:5480–5487CrossRef
49.
Zhang T, Cao X, Wang X, Song C (2017) Synthesis, surface activity and thermodynamic properties of cationic gemini surfactants with diester and rigid spacers. J Mol Liq 230:505–510CrossRef
50.
Menger FM, Littau CA (1993) Gemini surfactants: a new class of self assembling molecules. J Am Chem Soc 115:10083–10090CrossRef
51.
Penfold J, Staples E, Tucker I, Soubiran L, Creeth A, Hubbard J (2000) Adsorption of di-chain cationic and non-ionic surfactant mixture at the air-water interface. J Phys Chem Chem Phys 2:5230–5234CrossRef
52.
Li ZX, Dong CC, Wang JB, Thomas RK (2002) Penfold Unusual surface structure in layers of cationic gemini surfactants adsorbed at the air/water interface: a neutron reflection study. Langmuir 18:6614–6622CrossRef
53.
Rosen MJ (2004) Surfactants and interfacial phenomena, Third edn. John Wiley and Sons, Inc., New York,
54.
Lu T, Lan Y, Liu C, Huang J, Wang Y (2012) Surface properties, aggregation behavior and micellization thermodynamics of a class of gemini surfactants with ethyl ammonium headgroups. J Colloid Interface Sci 377:222–230CrossRef
55.
Zhang S, Yu J, Wu J, Tong W, Lei Q, Fang W (2014) Micellization parameters of six gemini quaternary ammonium surfactants from measurements of conductivity and surface tension. J Chem Eng Data 59:2891–2900CrossRef
56.
Majumder S, Dhar J, Chakraborty S (2015) Resolving anomalies in predicting electrokinetic energy conversion efficiencies of nanofluidic devices. Nat Publ Gr 5:1–13
57.
Zana R (1996) Critical micellization concentration of surfactants in aqueous solution and free energy of micellization. Langmuir 12:1208–1211CrossRef
58.
Khan F, Siddique US, Rub MA, Khan IA, Ud-Din K (2014) Micellization and interfacial properties of cationic gemini surfactant (12-4-12) in the presence of additives in aqueous electrolyte solution: a tensiometric study. J Mol Liq 191:29–36CrossRef
59.
Sun D, Qiu X, Li L, Wei X, Yin B (2006) A study of a -cyclodextrin with a group of cationic gemini surfactants utilizing isothermal titration calorimetry and NMR. J Chem Thermodyn 38:773–777CrossRef
60.
Tikariha D, Singh N, Satnami ML, Ghosh KK, Barbero N (2012) Physicochemical characterization of cationic gemini surfactants and their effect on reaction kinetics in ethylene glycol–water medium. Colloids Surf A Physicochem Eng Asp 411:1–11CrossRef
61.
Kolay S, Ghosh KK, Quagliotto P (2009) Micellization behavior of [C16-12-C16],2Br− gemini surfactant in binary aqueous-solvent mixtures. Colloids Surf A Physicochem Eng Asp 348:234–239CrossRef
62.
Lee DJ (1995) Enthalpy-entropy compensation in ionic micelle formation. Colloid Polym Sci 273:539–543CrossRef
63.
Liu G, Gu D, Liu H, Ding W, Li Z (2011) Enthalpy-entropy compensation of ionic liquid-type gemini imidazolium surfactants in aqueous solutions: a free energy perturbation study. J Colloid Interface Sci 358:521–526CrossRef
64.
Rodrı A, Graciani M, Moya L (2006) Effects of ethylene glycol addition on the aggregation and micellar growth of gemini surfactants. Langmuir 22:9519–9595CrossRef
Metadaten
Titel
Synthesis, characterization, and physicochemical properties of a series of quaternary gemini surfactants with different spacer lengths
verfasst von
Nilanjan Pal
Neha Saxena
Ajay Mandal
Publikationsdatum
30.09.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 12/2017
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-017-4199-1

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