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Polymer Bulletin
Erschienen in: Polymer Bulletin 6/2021

20.06.2020 | Original Paper

Synthesis of carbazole-based polymer derived N-enriched porous carbon for dyes sorption

verfasst von: Qiuyu Meng, Yunfei Liu, Yali Luo, Yinong Lyu

Erschienen in: Polymer Bulletin | Ausgabe 6/2021

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Abstract

A (N-vinyl carbazole)-based polymer, namely PPVK, was subsequently synthesized by free radical polymerization and oxidative polymerization. This material exhibits permanent porosity, good physicochemical stability, and plenty of nitrogen units. All these features make PPVK promising precursor for constructing N-enriched porous carbon. Using KOH as the activating agent, porous carbon material was prepared and its adsorption performance was also evaluated. Due to the high Brunauer–Emmett–Teller surface area (1832 m2 g−1) and abundant nitrogen atoms, the porous carbon, CPVK-800, displays adsorption capacity of 1074 mg g−1 for Rhodamine B, which is far higher than that reported for commercial activated carbon (0.36 mmol g−1). Kinetic investigations indicate that the adsorption behaviour follows the Langmuir isotherm model and pseudo-second-order kinetics. Besides the cationic dye rhodamine B, CPVK-800 also can be used to adsorption removal of anionic dye methyl orange, with uptake of 739 mg g−1. Findings in this study highlight the potential of using carbonaceous polymer as an effective adsorbent for organic dyes.
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Metadaten
Titel
Synthesis of carbazole-based polymer derived N-enriched porous carbon for dyes sorption
verfasst von
Qiuyu Meng
Yunfei Liu
Yali Luo
Yinong Lyu
Publikationsdatum
20.06.2020
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 6/2021
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-020-03279-0

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