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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 12/2012

01.12.2012 | Original Paper

Synthesis of new bio-based polycarbonates derived from terpene

verfasst von: Yuanrong Xin, Hiroshi Uyama

Erschienen in: Journal of Polymer Research | Ausgabe 12/2012

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Abstract

In this work, a bio-based polycarbonate has been synthesized successfully from terpene diphenol and diphenyl carbonate by melt polymerization without using any catalysts. The polymerization process involves no usage of toxic phosgene. The reaction parameters such as monomer feed ratio, polymerization temperature and time have been systematically examined. A little excess of diphenyl carbonate for terpene diphenol affords the highest molecular weight. The chemical structure of the product is identified by 1H NMR and FT-IR. The DSC analysis shows that the glass transition temperature of the present bio-based polycarbonate is much higher than that of a conventional bisphenol A-based polycarbonate due to the rigid molecular structure of terpene diphenol. In addition, a series of copolycarbonates with adjustable glass transition temperature are prepared from terpene diphenol and bisphenol A. The present polycarbonate and copolycarbonates with high thermal stability synthesized via an environmental benign process have large potential for bio-based engineering plastics in various industrial fields.
Vorheriger Artikel Effects of adding different ethanol amines during membrane preparation on the performance and morphology of nanoporous PES membranes
Nächster Artikel Influence of matrices chemical nature on the dynamic mechanical and dielectric properties of rubber composites comprising conductive carbon black

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Literatur
1.
Bozell JJ (2008) Feedstocks for the future-biorefinery production of chemicals from renewable carbon. Clean 36:641–647
2.
Williams CK, Hillmyer MA (2008) Polymers from renewable resources: a perspective for a special issue of polymer reviews. Polym Rev 48:1–10CrossRef
3.
Jenck JF, Agterberg F, Droescher MJ (2004) Products and processes for a sustainable chemistry industry: a review of achievements and prospects. Green Chem 6:544–556CrossRef
4.
Corma A, Iborra S, Velty A (2007) Chemical routes for the transformation of biomass into chemicals. Chem Rev 107:2411–2502CrossRef
5.
Biermann U, Friedt W, Lang S, Lühs W, Machmüller G, Metzger JO, Klaas MR, Schäfer HJ, Schneider MP (2000) New synthesis with oils and fats as renewable raw materials for the chemical industry. Angew Chem Int Ed 39:2206–2224CrossRef
6.
Liu CC, Chang KY, Wang YJ (2010) A novel biodegradable amphiphilic diblock copolymers based on poly(lactic acid) and hyaluronic acid as biomaterials for drug delivery. J Polym Res 17:459–469CrossRef
7.
Xu H, Teng C, Mao Z, Yu M (2012) Study on the preparation and properties of lactic acid based copolymer. J Polym Res 19:9960CrossRef
8.
Luo SH, Wang QF, Xiong JF, Wang ZY (2012) Synthesis of biodegradable material poly(lactic acid-co-sorbitol) via direct melt polycondensation and its reaction mechanism. J Polym Res 19:9962CrossRef
9.
Fan XD, Deng Y, Waterhouse J, Pfromm P (1998) Synthesis and characterization of polyamide resins from soy-based dimer acids and different amides. J Appl Polym Sci 68:305–314CrossRef
10.
Bou JJ, Iribarren I, Muñoz-Guerra S (1994) Synthesis and properties of stereoregular polyamides derived from L-tartaric acid: poly[(2S, 3S)-2, 3-Dimethoxybutylene alkanamide]s. Macromolecules 27:5263–5270CrossRef
11.
Alam M, Ashraf SM, Ahmad S (2008) Pyridine-poly(urethane ester amide) coatings from linseed oil. J Polym Res 15:343–350CrossRef
12.
Djordjevic I, Choudhury NR, Dutta NK, Kumar S (2009) Synthesis and characterization of novel citric acid-based polyester elastomers. Polymer 50:1682–1691CrossRef
13.
Miao S, Zhang S, Su Z, Wang P (2008) Chemoenzymatic synthesis of oleic acid-based polyesters for use as highly stable biomaterials. J Polym Sci A Polym Chem 46:4243–4248CrossRef
14.
Dong W, Li H, Chen M, Ni Z, Zhao J, Yang H (2011) Biodegradable bio-based polyesters with controllable photo-crosslinkability, thermal and hydrolytic stability. J Polym Res 18:1239–1247CrossRef
15.
Jasinska L, Koning CE (2010) Unsaturated, biobased polyesters and their cross-linking via radical copolymerization. J Polym Sci A Polym Chem 48:2885–2895CrossRef
16.
Hashimoto K, Hashimoto N, Kamaya T, Yoshioka J, Okawa H (2011) Synthesis and properties of bio-based polyurethanes bearing hydroxyl groups derived from alditols. J Polym Sci A Polym Chem 49:976–985CrossRef
17.
Desai SD, Emanuel AL, Sinha VK (2003) Biomaterial based polyurethane adhesive for bonding rubber and wood joints. J Polym Res 10:275–281CrossRef
18.
Lligadas G, Ronda JC, Galià M, Cádiz V (2010) Plant oils as platform chemicals for polyurethane synthesis: current state-of-the-art. Biomacromolecules 11:2825–2835CrossRef
19.
Palaskar DV, Boyer A, Cloutet E, Alfos C, Cramail H (2010) Synthesis of biobased polyurethane from oleic and ricinoleic acids as the renewable resources via the AB-type self-condensation approach. Biomacromolecules 11:1202–1211CrossRef
20.
Oprea S (2012) Novel quinoline-based polyurethane elastomers. The effect of the hard segment structure in properties enhancement. J Polym Res 19:9697CrossRef
21.
Wang CS, Shieh JY (1999) Synthesis and flame retardancy of phosphorous containing polycarbonate. J Polym Res 6:149–154CrossRef
22.
Woo BG, Choi KY, Song KH, Lee SH (2001) Melt polymerization of bisphenol-A and diphenyl carbonate in a semibatch reactor. J Appl Polym Sci 80:1253–1266CrossRef
23.
Haba O, Itakura I, Ueda M, Kuze S (1999) Synthesis of polycarbonate from dimethyl carbonate and bispheol-A through a non-phosgene process. J Polym Sci A Polym Chem 37:2087–2093CrossRef
24.
Fukuoka S, Tojo M, Hachiya H, Aminaka M, Hasegawa K (2007) Green and sustainable chemistry in practice: development and industrialization of a novel process for polycarbonate production form CO2 without using phosgene. Polym J 39:91–114CrossRef
25.
Okuyama K, Sugiyama J, Nagahata R, Asai M, Ueda M, Takeuchi K (2003) Direct synthesis of polycarbonate from carbon monoxide and bisphenol A catalyzed by Pd-carbene complex. Macromolecules 36:6953–6955CrossRef
26.
Kim J, Gracz HS, Roberts GW, Kisrow DJ (2008) Spectroscopic analysis of poly(bisphenol A carbonate) using high resolution 13C and 1H NMR. Polymer 49:394–404CrossRef
27.
Hammani S, Moulai-Mostefa N, Benyahia L, Tassin JF (2012) Effects of composition and extrusion parameters on the morphological development and rheological properties of PP/PC blends. Co-continuity investigation. J Polym Res 19:9940CrossRef
28.
Sweileh BA, Al-Hiari YM (2006) Synthesis and thermal properties of polycarbonates based on bisphenol A by single-phase organic solvent polymerization. J Polym Res 13:181–191CrossRef
29.
Fukuoka S, Kawamura M, Komiya K, Tojo M, Hachiya H, Hasegawa K, Aminaka M, Okamoto H, Fukawa I, Konno S (2003) A novel non-phosgene polycarbonate production process using by-product CO2 as starting material. Green Chem 5:497–507CrossRef
30.
Wu R, Al-Azemi TF, Bisht KS (2008) Functionalized polycarbonate derived from tartaric acid: enzymatic ring-opening polymerization of a seven-membered cyclic carbonate. Biomacromolecules 9:2921–2928CrossRef
31.
Mei H, Zhong Z, Long F, Zhuo R (2006) Synthesis and characterization of novel glycerol-derived polycarbonate with pendant hydroxyl groups. Macromol Rapid Commun 27:1894–1899CrossRef
32.
Xia H, Suo ZY, Qiang GJ, Chang CJ (1995) Synthesis, characterization, and degradation of a novel L-tyrosine-derived polycarbonate for potential biomaterial applications. J Appl Polym Sci 110:2168–2178CrossRef
33.
Schmidhauser JC (1995) Patent JP 7-53430
34.
Morikawa T, Fujii K (1998) Patent JP 8-198791
35.
Firdaus M, Espinosa LM, Meier MAR (2011) Terpene-based renewable monomers and polymers via thiol-ene additions. Macromolecules 44:7253–7262CrossRef
36.
Satoh K, Sugiyama H, Kamigaito M (2006) Biomass-derived heat-resistant alicyclic hydrocarbon polymers: poly(terpenes) and their hydrogenated derivatives. Green Chem 8:878–882CrossRef
37.
Kimura H, Murata Y, Matsumoto A, Hasegawa K, Ohtsuka K, Fukuda A (1999) New thermosetting resin from terpenediphenol-based benzoxazine and epoxy resin. J Appl Polym Sci 74:2266–2273CrossRef
38.
Serini V (2000) Polycarbonates. In: Ullmann’s encyclopedia of industrial chemistry. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
39.
Wielgosz Z, Dobkowski Z, Krajewski B (1972) Studies on polycarbonate preparation by the interfacial polycondensation method. Eur Polym J 8:1113–1119CrossRef
40.
Hersh SN, Choi KY (1990) Melt transesterification of diphenyl carbonate with bisphenol A in a batch reactor. J Appl Polym Sci 41:1033–1046CrossRef
41.
Darensbourg DJ, Wilson SJ (2011) Synthesis of poly(indene carbonate) from indene oxide and carbon dioxide—a polycarbonate with a rigid backbone. J Am Chem Soc 133:18610–18613CrossRef
42.
Güner FS, Yağci Y, Erciyes AT (2006) Polymers from triglyceride oils. Prog Polym Sci 31:633–670CrossRef
43.
Xia Y, Larock RC (2010) Vegetable oil-based polymeric materials: synthesis, properties, and applications. Green Chem 12:1893–1909CrossRef
Metadaten
Titel
Synthesis of new bio-based polycarbonates derived from terpene
verfasst von
Yuanrong Xin
Hiroshi Uyama
Publikationsdatum
01.12.2012
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 12/2012
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-012-0015-2

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