Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Polymer Bulletin
Erschienen in: Polymer Bulletin 10/2015

01.10.2015 | Original Paper

Synthesis of peanut shell/polyacrylonitrile copolymer via Cu(0)-mediated RDRP and its adsorption behavior after modification

verfasst von: Liangjiu Bai, Dongju Wang, Hou Chen, Dongxin Li, Yuanyuan Xu, Lili Yu, Wenxiang Wang

Erschienen in: Polymer Bulletin | Ausgabe 10/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Peanut shell (PNS) was used to prepare a novel adsorbent to achieve resource recovery of the agricultural residue. The hydroxyl groups of peanut shell were turned into –C(CH3)2–Br pendant groups to initiate polymerization of acrylonitrile. Graft copolymer peanut shell/polyacrylonitrile (PNS-g-PAN) was modified by hydroxylamine hydrochloride to transform the cyano groups into amidoxime (AO) groups. The modified copolymer of AO-PNS-g-PAN was used as adsorbent. The maximum adsorption capacity for Hg(II) was 4.45 mmol g−1. The adsorption process fitted well the Freundlich isotherm model and followed pseudo-second-order model. The modified copolymer demonstrated its potential as an efficient adsorbent to solve the problem of Hg(II) contamination.

Graphical abstract

The peanut shell (PNS) macroinitiator was obtained by acylation of hydroxyl groups on the cellulose backbone of the peanut shell and initiated by Cu(0)-mediated RDRP of acrylonitrile. PNS-g-PAN was modified by NH2OH·HCl and used to remove heavy metal ions. The maximum adsorption capacity of Hg(II) was 4.45 mmol g−1.
Vorheriger Artikel Synthesis, characterization and properties of new poly(triazole-imide)s and their composites with silane-modified nanoclay
Nächster Artikel A systematic study of Nickel (II) α-diimine complex performance on ethylene polymerization: influence of cocatalyst nature

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Demirbas A (2008) Heavy metal adsorption onto agro-based waste materials: a review. J Hazard Mater 157:220–229CrossRef
2.
Wan WS, Ngah MA, Hanafiah KM (2008) Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: a review. Bioresour Technol 99:3935–3948CrossRef
3.
Aydin H, Bulut Y, Yerlikaya CJ (2008) Removal of copper (II) from aqueous solution by adsorption onto low-cost adsorbents. J Environ Manag 87:37–45CrossRef
4.
Kumar U, Bandyopadhyay M (2006) Sorption of cadmium from aqueous solution using pretreated rice husk. Bioresour Technol 97:104–109CrossRef
5.
Babarinde NAA, Oyebamiji Babalola J, Adebowale Sanni R (2006) Biosorption of lead ions from aqueous solution by maize leaf. J Phys Sci 1:23–26
6.
Quek SY, Wase DAJ, Forster CF (1998) The use of sago waste for the sorption of lead and copper. Water SA 24:251–256
7.
Zhang BW, Fischer K, Bieniek D, Kettrup A (1994) Synthesis of carboxyl group containing hydrazine-modified polyacrylonitrile fibres and application for the removal of heavy metals. React Polym 24:49–58CrossRef
8.
Deng SB, Bai RB, Chen JP (2003) Behaviors and mechanisms of copper adsorption on hydrolyzed polyacrylonitrile fibers. J Colloid Interface Sci 260:265–272CrossRef
9.
Niu YH, Qu RJ, Sun CM, Wang CH, Chen H, Ji CN (2013) Adsorption of Pb(II) from aqueous solution by silica-gel supported hyperbranched polyamidoamine dendrimers. J Hazard Mater 244–245:276–286CrossRef
10.
Vijayalakshmi A, Arockiasamy DL, Nagendran A, Mohan D (2008) Separation of proteins and toxic heavy metal ions from aqueous solution by CA/PC blend ultrafiltration membranes. Sep Purif Technol 62:32–38CrossRef
11.
Hawker CJ, Bosman AW, Harth E (2001) New polymer synthesis by nitroxide mediated living radical polymerizations. Chem Rev 101:3661–3688CrossRef
12.
Moad G, Rizzardo E, Thang SH (2008) Radical addition-fragmentation chemistry in polymer synthesis. Polymer 49:1079–1131CrossRef
13.
Barner-Kowollik C, Perrier S (2008) The future of reversible addition fragmentation chain transfer polymerization. J Polym Sci Part A: Polym Chem 46:5715–5723CrossRef
14.
Matyjaszewski K, Jiang X (2001) Atom transfer radical polymerization. Chem Rev 101:2921–2990CrossRef
15.
Nguyen NH, Percec V (2010) Dramatic acceleration of SET-LRP of methyl acrylate during catalysis with activated Cu(0) wire. J Polym Sci Part A: Polym Chem 48:5109–5119CrossRef
16.
Percec V, Guliashvili T, Ladislaw JS, Wistrand A, Stjerndahl A, Sienkowska MJ, Monteiro MJ, Sahoo S (2006) Ultrafast synthesis of ultrahigh molar mass polymers by metal-catalyzed living radical polymerization of acrylates, methacrylates, and vinyl chloride mediated by SET at 25 °C. J Am Chem Soc 128:14156–14165CrossRef
17.
Nguyen NH, Levere ME, Percec V (2012) TREN versus Me6-TREN as ligands in SET-LRP of methyl acrylate. J Polym Sci Part A: Polym Chem 50:35–46CrossRef
18.
Nguyen NH, Percec V (2011) SET-LRP of methyl acrylate catalyzed with activated Cu(0) wire in methanol in the presence of air. J Polym Sci Part A: Polym Chem 49:4756–4765CrossRef
19.
Zhai SJ, Wang B, Feng C, Li YJ, Yang D, Hu JH, Lu G, Huang XY (2010) Thermoresponsive PPEGMEA-g-PPEGEEMA well-defined double hydrophilic graft copolymer synthesized by successive SET-LRP and ATRP. J Polym Sci Part A: Polym Chem 48:647–655CrossRef
20.
Johnson PD, Watson MA, Brown J, Jefcoat IA (2002) Peanut hull pellets as a single use sorbent for the capture of Cu(II) from wastewater. Waste Manag 22:471–480CrossRef
21.
Edlund U, Albertsson AC (2012) SET-LRP goes “green”: Various hemicellulose initiating systems under non-inert conditions. J Polym Sci Part A: Polym Chem 50:2650–2658CrossRef
22.
Voepel J, Edlund U, Albertsson AC, Percec V (2011) Hemicellulose-based multifunctional macroinitiator for single-electron-transfer mediated living radical polymerization. Biomacromolecules 12:253–259CrossRef
23.
de Santa Mariaa LC, Amorimb MCV, Aguiara MRMP, Guimaraesa PIC, Aguiarb MAS, de Costaa AP, Rezende PR, de Carvalho MS, Barbosa FG, Andrade JM, Ribeiro RCC (2001) React. Chemical modification of cross-linked resin based on acrylonitrile for anchoring metal ions. Funct Polym 49:133–143CrossRef
24.
Zhao T, Zhang LF, Zhang ZB, Zhou NC, Cheng ZP, Zhu XL (2011) A novel approach to modify poly(vinylidene fluoride) via iron-mediated atom transfer radical polymerization using activators generated by electron transfer. J Polym Sci Part A Polym Chem 49:2315–2324CrossRef
25.
Anirudhan TS, Divya LPS (2009) Kinetic and equilibrium characterization of uranium(VI) adsorption onto carboxylate-functionalized poly(hydroxyethylmethacrylate)-grafted lignocellulosics. J Environ Manag 90:549–560CrossRef
26.
Liu YH, Zhou WQ, Bai LB, Zhao N, Liu YW (2006) Graft copolymerization of styrene onto casein initiated by potassium diperiodatonickelate (IV) in alkaline medium. J Appl Polym Sci 100:4247–4251CrossRef
27.
Bai LB, Zhao K, Wu YG, Li WL, Wang SJ, Wang HJ, Ba XW, Zhao HC (2014) A new method for synthesizing hyperbranched polymers with reductive groups using redox/RAFT/SCVP. Chin J Polym Sci 32:385–394CrossRef
28.
Xiong L, Chen C, Chen Q, Ni JR (2011) Adsorption of Pb(II) and Cd(II) from aqueous solutions using titanate nanotubes prepared via hydrothermal method. J Hazard Mater 189:741–748CrossRef
29.
Liu CK, Bai RB, Ly QS (2008) Selective removal of copper and lead ions by diethylenetriamine-functionalized adsorbent: behaviors and mechanisms. Water Res 42:1511–1522CrossRef
30.
Monier M, Abdel-Latif DA (2012) Preparation of cross-linked magnetic chitosan-phenylthiourea resin for adsorption of Hg(II), Cd(II) and Zn(II) ions from aqueous solutions. J Hazard Mater 209–210:240–249CrossRef
31.
Niu YZ, Qu RJ, Chen H, Mu L, Liu XG, Wang T, Zhang Y, Sun CM (2014) Synthesis of silica gel supported salicylaldehyde modified PAMAM dendrimers for the effective removal of Hg(II) from aqueous solution. J Hazard Mater 278:267–278CrossRef
Metadaten
Titel
Synthesis of peanut shell/polyacrylonitrile copolymer via Cu(0)-mediated RDRP and its adsorption behavior after modification
verfasst von
Liangjiu Bai
Dongju Wang
Hou Chen
Dongxin Li
Yuanyuan Xu
Lili Yu
Wenxiang Wang
Publikationsdatum
01.10.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 10/2015
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-015-1423-3

Weitere Artikel der Ausgabe 10/2015

Polymer Bulletin 10/2015 Zur Ausgabe

Original Paper

Fluorescent switch based on the oxidation of tetrathiafulvalene

Original Paper

Preparation and characterization of polyaniline-poly(styrene-acrylate) composite latexes

Original Paper

Hydrogel/clinoptilolite nanocomposite-coated fertilizer: swelling, water-retention and slow-release fertilizer properties

Original Paper

A systematic study of Nickel (II) α-diimine complex performance on ethylene polymerization: influence of cocatalyst nature

Original Paper

Synthesis and electro-optic properties of novel X-type polyester containing dioxynitrobenzylidenecyanoacetate with highly enhanced thermal stability of dipole alignment

Original Paper

Dielectric dispersion and relaxation studies of melt compounded poly(ethylene oxide)/silicon dioxide nanocomposites

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise