nach oben

Journal of Materials Science: Materials in Electronics

Erschienen in:

01.02.2024

Tailoring magnetic properties of α-MnO₂@NiCo₂O₄ core/shell nanostructure

verfasst von: Laxmipriya Sahoo, Niharika Mohapatra

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 6/2024

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Herein, we present a bi-magnetic hierarchical α-MnO₂@NiCo₂O₄ core–shell nanostructure synthesized through a simple two-step hydrothermal process. The structural and morphological properties of these core–shell nanostructures were studied systematically using X-ray diffraction and Field emission scanning electron microscope. The XRD patterns are concomitant with the presence of the two phases, and the formation of nanowire@nanosheet is confirmed by the SEM/EDX study. FTIR measurement results give an idea about the vibration and bond formation of the samples, while the optical properties of the samples examined through UV–visible spectroscopy suggest the presence of a spinel group along with the MnO₂ phase in the absorption spectra. The results of magnetic measurements reveal the spin-glass type behavior at very low temperature i.e., 8 K, and the saturation magnetization for the core–shell system was found to be 50 emu/g. Experimental evidence for this spin glass behavior was confirmed by the studies of memory cycles and the relaxation dynamics in thermal variation of the magnetization process.

Vorheriger Artikel The impact of 50% combined Fe and Mn ions at the B-sites on the structural, optical, magnetic and dielectric properties of double perovskite Nd2FeMnO6

Nächster Artikel Observations on the structural, piezoelectric, and impedance properties of cation-(La and Sn) modified lead zirconium titanate (PLZST) ceramics

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 340 Zeitschriften

aus folgenden Fachgebieten:

Bauwesen + Immobilien
Business IT + Informatik
Finance + Banking
Management + Führung
Marketing + Vertrieb
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

A. Joshi, N. Singh, G. Verma, “Preparation and applications of self-assembled natural and synthetic nanostructures”, in Fabrication and Self-Assembly of Nanobiomaterials (Elsevier, Amsterdam, 2016)

X. Xu, X. Fang, H. Zeng, T. Zhai, Y. Bando, D. Golberg, One-dimensional nanostructures in porous anodic alumina membranes. Sci. Adv. Mater. 2(3), 273–294 (2010). https://doi.org/10.1166/sam.2010.1094CrossRef

R. Ghosh Chaudhuri, S. Paria, Core/shell nanoparticles: classes, properties, synthesis mechanisms, characterization, and applications. Chem. Rev. 112(4), 2373–2433 (2012). https://doi.org/10.1021/cr100449nCrossRefPubMed

Z.L. Wang, T.S. Ahmad, M.A. El-Sayed, Steps, ledges and kinks on the surfaces of platinum nanoparticles of different shapes. Surf. Sci. 380(2–3), 302–310 (1997). https://doi.org/10.1016/S0039-6028(97)05180-7CrossRefADS

C.M. Lieber, One-dimensional nanostructures: chemistry, physics & applications. Solid State Commun. 107(11), 607–616 (1998). https://doi.org/10.1016/S0038-1098(98)00209-9CrossRefADS

S. Laurent et al., Magnetic iron oxide nanoparticles: synthesis, stabilization, vectorization, physicochemical characterizations, and biological applications. Chem. Rev. 108(6), 2064–2110 (2008). https://doi.org/10.1021/cr068445eCrossRefPubMed

S. Balakrishnan, M.J. Bonder, G.C. Hadjipanayis, Particle size effect on phase and magnetic properties of polymer-coated magnetic nanoparticles. J. Magn. Magn. Mater. 321(2), 117–122 (2009). https://doi.org/10.1016/j.jmmm.2008.08.055CrossRefADS

M.-J. Kim, Y.-H. Choa, D.H. Kim, K.H. Kim, “Magnetic behaviors of surface modified superparamagnetic magnetite nanoparticles.” IEEE Trans. Magn. 45(6), 2446–2449 (2009). https://doi.org/10.1109/TMAG.2009.2018606CrossRefADS

S. Sivakumar, D. Anusuya, C.P. Khatiwada, J. Sivasubramanian, A. Venkatesan, P. Soundhirarajan, “Characterizations of diverse mole of pure and Ni-doped α-Fe2O3 synthesized nanoparticles through chemical precipitation route.” Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 128, 69–75 (2014). https://doi.org/10.1016/j.saa.2014.02.136CrossRefADS

10.

A. Hernandez-Valdes, R.A. Zarate, A.I. Martinez, M.I. Pech-Canul, M.A. Garcia-Lobato, R. Villaroel, The role of solvents on the physical properties of sprayed iron oxide films. Vacuum 105, 26–32 (2014). https://doi.org/10.1016/j.vacuum.2014.02.001CrossRefADS

11.

Y. Ichiyanagi, Magnetic properties of NiO nanoparticles. Phys. B Condens. Matter 329–333, 862–863 (2003). https://doi.org/10.1016/S0921-4526(02)02578-4CrossRefADS

12.

J. Du, Y. Gao, L. Chai, G. Zou, Y. Li, Y. Qian, Hausmannite Mn 3 O 4 nanorods: synthesis, characterization and magnetic properties. Nanotechnology 17(19), 4923–4928 (2006). https://doi.org/10.1088/0957-4484/17/19/024CrossRefADS

13.

Y. Ichiyanagi, S. Yamada, The size-dependent magnetic properties of Co3O4 nanoparticles. Polyhedron 24(16–17), 2813–2816 (2005). https://doi.org/10.1016/j.poly.2005.03.158CrossRef

14.

S. Panda, M.K. Das, N. Mohapatra, Role of interfacial layer on exchange-coupled magnetic properties of bi-magnetic nanostructures : an experimental and theoretical approach. J. Magn. Magn. Mater. (2023). https://doi.org/10.1016/j.jmmm.2023.171306CrossRef

15.

L. Su, L. Hou, S. Di, J. Zhang, X. Qin, Plumage-like MnO2@NiCo2O4 core–shell architectures for high-efficiency energy storage: the synergistic effect of ultralong MnO2 ‘scaffold’ and ultrathin NiCo2O4 ‘fluff.’ Ionics (Kiel) 24(10), 3227–3235 (2018). https://doi.org/10.1007/s11581-018-2511-9CrossRef

16.

X. Wang et al., Facile synthesis of MnO2@NiCo2O4 core–shell nanowires as good performance asymmetric supercapacitor. J. Mater. Sci. Mater. Electron. 31(2), 1355–1366 (2020). https://doi.org/10.1007/s10854-019-02649-3CrossRef

17.

L. Yu, G. Zhang, C. Yuan, X.W. Lou, Hierarchical NiCo 2 O 4 @MnO 2 core–shell heterostructured nanowire arrays on Ni foam as high-performance supercapacitor electrodes. Chem. Commun. 49(2), 137–139 (2013). https://doi.org/10.1039/C2CC37117KCrossRef

18.

A. Kumar, A. Sanger, A.K. Singh, A. Kumar, M. Kumar, R. Chandra, Experimental evidence of spin glass and exchange bias behavior in sputtered grown α-MnO 2 nanorods. J. Magn. Magn. Mater. 433, 227–233 (2017). https://doi.org/10.1016/j.jmmm.2017.02.061CrossRefADS

19.

D. Gangwar, C. Rath, Structural, optical and magnetic properties of α- and β-MnO2 nanorods. Appl. Surf. Sci. 557, 149693 (2021). https://doi.org/10.1016/j.apsusc.2021.149693CrossRef

20.

T. Barudžija, V. Kusigerski, N. Cvjetićanin, S. Šorgić, M. Perović, M. Mitrić, Structural and magnetic properties of hydrothermally synthesized β-MnO2 and α-K MnO2 nanorods. J. Alloys Compd. 665, 261–270 (2016). https://doi.org/10.1016/j.jallcom.2016.01.024CrossRef

21.

W. Li, R. Zeng, Z. Sun, D. Tian, S. Dou, Uncoupled surface spin induced exchange bias in α-MnO2 nanowires. Sci. Rep. 4(1), 6641 (2014). https://doi.org/10.1038/srep06641CrossRefPubMedPubMedCentralADS

22.

W. Li et al., Performance modulation of α-MnO2 nanowires by crystal facet engineering. Sci. Rep. 5(1), 8987 (2015). https://doi.org/10.1038/srep08987CrossRefPubMedPubMedCentral

23.

N. Yamamoto, T. Endo, M. Shimada, T. Takada, Single crystal growth of α-MnO 2. Jpn. J. Appl. Phys. 13(4), 723–724 (1974). https://doi.org/10.1143/JJAP.13.723CrossRefADS

24.

L.-T. Tseng et al., Magnetic properties in α-MnO2 doped with alkaline elements. Sci. Rep. 5(1), 9094 (2015). https://doi.org/10.1038/srep09094CrossRefPubMedPubMedCentral

25.

J. Luo, H.T. Zhu, J.K. Liang, G.H. Rao, J.B. Li, Z.M. Du, Tuning magnetic properties of α-MnO 2 nanotubes by K + doping. J. Phys. Chem. C 114(19), 8782–8786 (2010). https://doi.org/10.1021/jp1006928CrossRef

26.

C. Zhou et al., Magnetic and thermodynamic properties of α, β, γ and δ-MnO 2. New J. Chem. 42(11), 8400–8407 (2018). https://doi.org/10.1039/C8NJ00896ECrossRef

27.

J.S. Smart, The Néel Theory of Ferrimagnetism. Am. J. Phys. 23(6), 356–370 (1955). https://doi.org/10.1119/1.1934006CrossRefADS

28.

T.W. Odom, G.C. Schatz, Introd. Plasmon. (2011). https://doi.org/10.1021/cr2001349CrossRef

29.

Y. Li et al., Spin-glass evolution behavior in spinel compounds Co2-Zn SnO4 (0 ≤ x ≤ 1). J. Alloys Compd. 852, 156962 (2021). https://doi.org/10.1016/j.jallcom.2020.156962CrossRef

30.

V. Tsurkan, H.-A. Krug von Nidda, J. Deisenhofer, P. Lunkenheimer, A. Loidl, On the complexity of spinels: magnetic, electronic, and polar ground states. Phys. Rep. 926, 1–86 (2021). https://doi.org/10.1016/j.physrep.2021.04.002CrossRefADS

31.

M. Kuang, Z.Q. Wen, X.L. Guo, S.M. Zhang, Y.X. Zhang, Engineering firecracker-like beta-manganese dioxides@spinel nickel cobaltates nanostructures for high-performance supercapacitors. J. Power. Sources 270, 426–433 (2014). https://doi.org/10.1016/j.jpowsour.2014.07.144CrossRefADS

32.

Y. Bitla et al., Origin of metallic behavior in NiCo2O4 ferrimagnet. Sci. Rep. 5(1), 15201 (2015). https://doi.org/10.1038/srep15201CrossRefPubMedPubMedCentralADS

33.

P.D. Battle, A.K. Cheetham, J.B. Goodenough, A neutron diffraction study of the ferrimagnetic spinel NiCo2O4. Mater. Res. Bull. 14(8), 1013–1024 (1979). https://doi.org/10.1016/0025-5408(79)90066-7CrossRef

34.

S. Verma, H.M. Joshi, T. Jagadale, A. Chawla, R. Chandra, S. Ogale, Nearly monodispersed multifunctional NiCo 2 O 4 spinel nanoparticles: magnetism, infrared transparency, and radiofrequency absorption. J. Phys. Chem. C 112(39), 15106–15112 (2008). https://doi.org/10.1021/jp804923tCrossRef

35.

S.N. Kale et al., “Characterization of biocompatible NiCo2O4 nanoparticles for applications in hyperthermia and drug delivery”, Nanomedicine Nanotechnology. Biol. Med. 8(4), 452–459 (2012). https://doi.org/10.1016/j.nano.2011.07.010CrossRef

36.

B. Cui, H. Lin, J.-B. Li, X. Li, J. Yang, J. Tao, Core-ring structured NiCo2O4 nanoplatelets: synthesis, characterization, and electrocatalytic applications. Adv. Funct. Mater. 18(9), 1440–1447 (2008). https://doi.org/10.1002/adfm.200700982CrossRef

37.

X. Yao, C. Zhao, J. Kong, D. Zhou, X. Lu, Polydopamine-assisted synthesis of hollow NiCo 2 O 4 nanospheres as high-performance lithium ion battery anodes. RSC Adv. 4(71), 37928 (2014). https://doi.org/10.1039/C4RA06816ECrossRefADS

38.

E. Umeshbabu, G. Rajeshkhanna, G.R. Rao, Urchin and sheaf-like NiCo 2 O 4 nanostructures: synthesis and electrochemical energy storage application. Int. J. Hydrogen Energy 39(28), 15627–15638 (2014). https://doi.org/10.1016/j.ijhydene.2014.07.168CrossRef

39.

N. Garg, M. Basu, A.K. Ganguli, Nickel cobaltite nanostructures with enhanced supercapacitance activity. J. Phys. Chem. C 118(31), 17332–17341 (2014). https://doi.org/10.1021/jp5039738CrossRef

40.

E. Umeshbabu, G. Rajeshkhanna, P. Justin, G.R. Rao, Magnetic, optical and electrocatalytic properties of urchin and sheaf-like NiCo2O4 nanostructures. Mater. Chem. Phys. 165, 235–244 (2015). https://doi.org/10.1016/j.matchemphys.2015.09.023CrossRef

41.

Y.-Z. Su, Q.-Z. Xu, G.-F. Chen, H. Cheng, N. Li, Z.-Q. Liu, One dimensionally spinel NiCo2O4 nanowire arrays: facile synthesis, water oxidation, and magnetic properties. Electrochim. Acta 174, 1216–1224 (2015). https://doi.org/10.1016/j.electacta.2015.06.092CrossRef

42.

Z.-Q. Liu et al., Fabrication of hierarchical flower-like super-structures consisting of porous NiCo2O4 nanosheets and their electrochemical and magnetic properties. RSC Adv. 3(13), 4372 (2013). https://doi.org/10.1039/c3ra23084hCrossRefADS

43.

M.A. Dar, D. Govindarajan, K.M. Batoo, C. Siva, Supercapacitor and magnetic properties of Fe doped SnS nanoparticles synthesized through solvothermal method. J. Energy Storage 52, 105034 (2022). https://doi.org/10.1016/j.est.2022.105034CrossRef

44.

F. Bao, Z. Zhang, W. Guo, X. Liu, Facile synthesis of three dimensional NiCo2O4@MnO2 core-shell nanosheet arrays and its supercapacitive performance. Electrochim. Acta 157, 31–40 (2015). https://doi.org/10.1016/j.electacta.2015.01.060CrossRef

45.

D. Ghosh, S. Bhandari, D. Khastgir, Synthesis of MnO 2 nanoparticles and their effective utilization as UV protectors for outdoor high voltage polymeric insulators used in power transmission lines. Phys. Chem. Chem. Phys. 18(48), 32876–32890 (2016). https://doi.org/10.1039/C6CP06611ACrossRefPubMed

46.

M. Silambarasan, P.S. Ramesh, D. Geetha, Facile one-step synthesis, structural, optical and electrochemical properties of NiCo2O4 nanostructures. J. Mater. Sci. Mater. Electron. 28(1), 323–336 (2017). https://doi.org/10.1007/s10854-016-5527-9CrossRef

47.

V. Hoseinpour, M. Souri, N. Ghaemi, Green synthesis, characterisation, and photocatalytic activity of manganese dioxide nanoparticles. Micro Nano Lett. 13(11), 1560–1563 (2018). https://doi.org/10.1049/mnl.2018.5008CrossRef

48.

T. Pluthametwisute, B. Wanthanachaisaeng, C. Saiyasombat, C. Sutthirat, Minor elements and color causing role in spinel: multi-analytical approaches. Minerals 12(8), 928 (2022). https://doi.org/10.3390/min12080928CrossRefADS

49.

N. Sakai, Y. Ebina, K. Takada, T. Sasaki, Photocurrent generation from semiconducting manganese oxide nanosheets in response to visible light. J. Phys. Chem. B 109(19), 9651–9655 (2005). https://doi.org/10.1021/jp0500485CrossRefPubMed

50.

C. Jia, F. Yang, L. Zhao, G. Cheng, G. Yang, Temperature-dependent electrical transport properties of individual NiCo2O4 nanowire. Nanoscale Res. Lett. 14(1), 10 (2019). https://doi.org/10.1186/s11671-018-2844-3CrossRefPubMedPubMedCentralADS

51.

Poonam, K. Sharma, N. Singh, S.K. Tripathi, Characterization of nickel cobalt oxide: a potential material for supercapacitor. Mater. Res. Express. 6(2), 025502 (2018). https://doi.org/10.1088/2053-1591/aae9c1CrossRefADS

52.

T. Gao, M. Glerup, F. Krumeich, R. Nesper, H. Fjellvåg, P. Norby, Microstructures and spectroscopic properties of cryptomelane-type manganese dioxide nanofibers. J. Phys. Chem. C 112(34), 13134–13140 (2008). https://doi.org/10.1021/jp804924fCrossRef

53.

Deepak, A. Kumar, S.M. Yusuf, E.V. Sampathkumaran, Insight into the negative magnetization and anomalous exchange-bias in DyFe 5 Al 7 through neutron depolarization and neutron diffraction studies. J. Phys. Condens. Matter 35(6), 065802 (2023). https://doi.org/10.1088/1361-648X/aca24dCrossRefADS

54.

M.J. Benitez et al., Evidence for core-shell magnetic behavior in antiferromagnetic Co3O4 nanowires. Phys. Rev. Lett. 101(9), 50–53 (2008). https://doi.org/10.1103/PhysRevLett.101.097206CrossRef

55.

P. Dey, T.K. Nath, P.K. Manna, S.M. Yusuf, Enhanced grain surface effect on magnetic properties of nanometric La0.7Ca0.3MnO3 manganite: evidence of surface spin freezing of manganite nanoparticles. J. Appl. Phys. (2008). https://doi.org/10.1063/13020524CrossRef

56.

J. Du, B. Zhang, R.K. Zheng, X.X. Zhang, Memory effect and spin-glass-like behavior in Co-Ag granular films. Phys. Rev. B 75(1), 014415 (2007). https://doi.org/10.1103/PhysRevB.75.014415CrossRefADS

57.

P. Thandapani, M. Ramalinga Viswanathan, J.C. Denardin, Magnetocaloric effect and universal curve behavior in superparamagnetic zinc ferrite nanoparticles synthesized via microwave assisted co-precipitation method. Phys. status solidi. (2018). https://doi.org/10.1002/pssa.201700842CrossRef

58.

S. Goswami, P. Gupta, S. Bedanta, M. Chakraborty, D. De, Coexistence of exchange bias and memory effect in nanocrystalline CoCr2O4. J. Alloys Compd. 890, 161916 (2022). https://doi.org/10.1016/j.jallcom.2021.161916CrossRef

59.

Y. Sun, M.B. Salamon, K. Garnier, R.S. Averback, Memory Effects in an Interacting Magnetic Nanoparticle System. Phys. Rev. Lett. 91(16), 167206 (2003). https://doi.org/10.1103/PhysRevLett.91.167206CrossRefPubMedADS

60.

J. Luo et al., Spin-glasslike behavior of K+-containing α-MnO2 nanotubes. J. Appl. Phys. 105(9), 093925 (2009). https://doi.org/10.1063/1.3117495CrossRefADS

61.

W. Kinzel, Remanent magnetization in spin-glasses. Phys. Rev. B 19(9), 4595–4607 (1979). https://doi.org/10.1103/PhysRevB.19.4595CrossRefADS

Titel: Tailoring magnetic properties of α-MnO2@NiCo2O4 core/shell nanostructure
verfasst von: Laxmipriya Sahoo
Niharika Mohapatra
Publikationsdatum: 01.02.2024
Verlag: Springer US
Erschienen in: Journal of Materials Science: Materials in Electronics / Ausgabe 6/2024
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-024-12131-4

Neuer Inhalt

Bildnachweise

VDI-Icon, Profil Icon, inhalt2, Springer Professional Modul/© Springer Fachmedien Wiesbaden GmbH, Internationaler Motorenkongress/© [M] ATZlive | Chisnikov / Fotolia.com, Search Icon, Banner Hanser, Benedikt Bonnmann von Adesso/© Adesso, Teilzeit/© Fokussiert / stock.adobe.com, Hans-Joachim Lefeld/© Lucht Probst Associates GmbH, Zeitschrift Wissensmanagement Cover, PatentFit-Logo/© Springer Fachmedien Wiesbaden GmbH, 2023_Antrieb/© supervisuell, ATZ-Webinar: Prototypenfreie Entwicklung durch Offline- und Driver-in-the-Loop-HiL-Tests /© (c) VI-grade, chassis.tech plus 2023/© [M] ATZlive / TÜV SÜD PRODUCT SERVICE GMBH

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Springer Professional "Wirtschaft"

Weitere Artikel der Ausgabe 6/2024

The effect of different protonic acid doping on the sensitivity of polyaniline to ammonia gas

Enhanced electrocaloric effect in Al2O3/P (VDF-TrFE-CTFE) nanocomposite: direct measurement by infrared thermal imaging

Three-dimensional graphene gel/carbon cloth electrode for detection of Cu2+ through two electrochemical methods of interactive verification

Chinese baijiu spent grains-based high-performance porous hard carbon for sodium-ion battery anodes

Ethanol gas sensing properties of electron beam deposited Zn-doped NiO thin films

Efficient nonlinear optical single crystal synthesized using L-threonine with maleic acid

Neuer Inhalt

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.