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Journal of Materials Science
Erschienen in: Journal of Materials Science 5/2021

05.11.2020 | Composites & nanocomposites

The correlated effects of filler loading on the curing reaction and mechanical properties of graphene oxide reinforced epoxy nanocomposites

verfasst von: Junpeng Tian, Cheng Yang, Jiping Yang, Sijia Hao

Erschienen in: Journal of Materials Science | Ausgabe 5/2021

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Abstract

Graphene oxide (GO)/epoxy nanocomposites are prepared by means of the phase extraction method. FTIR and XPS characterizations have confirmed the charge transfer between GO and epoxy that promotes the uniform dispersion and exfoliation of GO. The effects of GO sheets on the curing reaction and interfacial bonding are investigated and correlated with mechanical properties of epoxy nanocomposites. The results show that the GO sheets have a facilitation effect on the curing reaction of epoxy resin, in which the oxygen groups of GO covalently react with epoxy matrix and establish chemical interfacial bonding in epoxy nanocomposites. Therefore, the mechanical properties of nanocomposites are enhanced, showing the highest tensile strength of 88.1 ± 2.5 MPa, flexural strength of 134.2 ± 6.1 MPa and flexural modulus of 3.15 ± 0.11 GPa, respectively. However, GO sheets could simultaneously physically restrict the curing reactivity and reduce the cross-link density in the interface, which results in weakened interfacial property of nanocomposites, especially at high loading. Thus, the reinforcing effect of GO sheets is reduced and the mechanical properties of GO/epoxy nanocomposites decline at relatively higher loading.

Graphical abstract

Vorheriger Artikel Reducing particle size of biodegradable nanomaterial for efficient curcumin loading
Nächster Artikel Chemical and structural properties of reduced graphene oxide—dependence on the reducing agent

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Metadaten
Titel
The correlated effects of filler loading on the curing reaction and mechanical properties of graphene oxide reinforced epoxy nanocomposites
verfasst von
Junpeng Tian
Cheng Yang
Jiping Yang
Sijia Hao
Publikationsdatum
05.11.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 5/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-05336-5

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