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Erschienen in: Journal of Materials Science: Materials in Electronics 5/2019

28.02.2019

The effect of different Cu/Sn ratios on the properties of monoclinic Cu2SnS3 thin films and solar cells fabricated by the sol–gel method

verfasst von: Jie Wu, Chunhui Gao, Lu Han, Shanshan Shen, Ming Jia, Li Wang, Liangxing Jiang, Fangyang Liu

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 5/2019

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Abstract

Ternary Cu2SnS3 (CTS) is a promising material for thin-film solar cells because it consists of nontoxic and earth-abundant elements. The present paper reports the preparation of monoclinic CTS thin films by a sol–gel solution-based method. The effects of the Cu/Sn atomic ratio on the structure and morphology were investigated. As the atomic ratio of Cu/Sn varied from 1.6 to 2.0, the compactness of the CTS films improved; furthermore, secondary phases, such as SnS, gradually disappeared; and the grain size of the films decreased. The CTS film with a Cu/Sn ratio of 1.9 showed a monoclinic structure with homogeneous morphology and a band gap of 1.12 eV, yielding a power conversion efficiency of 0.58%. These results could pave the way for the development of CTS thin-film solar cells.

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Metadaten
Titel
The effect of different Cu/Sn ratios on the properties of monoclinic Cu2SnS3 thin films and solar cells fabricated by the sol–gel method
verfasst von
Jie Wu
Chunhui Gao
Lu Han
Shanshan Shen
Ming Jia
Li Wang
Liangxing Jiang
Fangyang Liu
Publikationsdatum
28.02.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 5/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-00725-2

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