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Erschienen in: Surface Engineering and Applied Electrochemistry 3/2023

01.06.2023

The Effect of the Proportion and Clay Mineralogical Composition on the Rheological Properties of the Raw Clay and the Sodium Carbonate Treated Clay Suspensions

verfasst von: Abderazak Elhechi, Olfa Ben Amor, Riadh Abidi, Ezzeddine Srasra

Erschienen in: Surface Engineering and Applied Electrochemistry | Ausgabe 3/2023

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Abstract

The X-ray diffraction, infrared spectroscopy, chemical analysis, and cation exchange capacities are the most common techniques used for the physico-chemical study and characterization of clays. All of these used in the present study showed that the Tunisian clay samples collected from Zaghouan area (Zg1, Zg2, and Zg3) and Hawaria area (Ha1, Ha2, and Ha3) consisted of illite, kaolinite, and smectite associated with quartz, K-feldespar, calcite, and dolomite. The chemical analysis revealed that Al2O3 is relatively high in the Ha2 sample. The CaO rate was high (5.08 and 7.16 wt %) for Ha3 and Zg3 samples. To demonstrate the impact of clay mineralogical composition on the rheological properties, six samples were used to prepare the mixed clay aqueous suspension. Its effect depends on the proportion of the 2:1 phyllosilicate, especially smectite, as well as on the rheological properties of the blank clay suspensions and of Na2CO3 treated ones. Calcite forms large agglomerations with clays minerals, which prevents flocculation. The negative charges in the tetrahedral layers were generated by the substitution of Si4+ with Al3+, and they were compensated by the interlayer exchangeable cations. Therefore, the interlayer hydration leads to an increase of the dispersion of clay particles and rheological properties.

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Metadaten
Titel
The Effect of the Proportion and Clay Mineralogical Composition on the Rheological Properties of the Raw Clay and the Sodium Carbonate Treated Clay Suspensions
verfasst von
Abderazak Elhechi
Olfa Ben Amor
Riadh Abidi
Ezzeddine Srasra
Publikationsdatum
01.06.2023
Verlag
Pleiades Publishing
Erschienen in
Surface Engineering and Applied Electrochemistry / Ausgabe 3/2023
Print ISSN: 1068-3755
Elektronische ISSN: 1934-8002
DOI
https://doi.org/10.3103/S1068375523030067

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