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Journal of Materials Engineering and Performance
Erschienen in: Journal of Materials Engineering and Performance 11/2016

26.09.2016

The Passive Film Characteristics of Cold Deformed Pure Copper

verfasst von: Arash Fattah-Alhosseini, Majid Naseri, Omid Imantalab, Davood Gholami, Meysam Haghshenas

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 11/2016

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Abstract

In the present study, the effect of cold deformation on the electrochemical and passive behaviors of pure copper in 0.01 M NaOH solution was investigated. The dislocation density in cold deformation was calculated using a recently developed JAVA-based software, materials analysis using diffraction, based on Rietveld’s whole x-ray pattern fitting methodology. At the thickness reduction of 70%, the microhardness measured as 125.30 HV, which is 1.56 times than that in the annealed pure copper (80.25 HV). Potentiodynamic polarization plots and electrochemical impedance spectroscopy measurements showed that increasing the cold deformation offers better conditions for forming the passive films. In the Mott-Schottky analysis, no evidence for n-type behavior was obtained which indicates that the oxygen vacancies and the copper interstitials did not have any significant population density in the passive films. Also, this analysis revealed that with increasing cold deformation, the acceptor density of the passive films decreased.
Vorheriger Artikel Microstructure and Corrosion Resistance of Electrodeposited Ni-Cu-Mo Alloy Coatings
Nächster Artikel Development and Validation of Processing Maps for Ti-6Al-4V Alloy Using Various Flow Instability Criteria

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Metadaten
Titel
The Passive Film Characteristics of Cold Deformed Pure Copper
verfasst von
Arash Fattah-Alhosseini
Majid Naseri
Omid Imantalab
Davood Gholami
Meysam Haghshenas
Publikationsdatum
26.09.2016
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 11/2016
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-016-2352-5

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