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2017 | OriginalPaper | Buchkapitel

The Synthesis and the Catalytic Properties of Graphene-Based Composite Materials

verfasst von : Baojiang Jiang, Ph.D, Chaoyang Li

Erschienen in: Carbon-related Materials in Recognition of Nobel Lectures by Prof. Akira Suzuki in ICCE

Verlag: Springer International Publishing

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Abstract

Graphene is composed of a single layer of carbon atoms arranged in a sp2-bonded aromatic structure, which has become one of the most interesting research areas in the last 5 years. Graphene is also distinctly different from carbon nanotubes and fullerenes, exhibiting a range of unusual properties. It exhibits excellent serials of properties including magical optical, mechanical, electrical, thermal, and chemical performance. These features make graphene the go-to material for applications including photocatalysis, supercapacitors, photovoltaic devices, flexible displays, and nano-transistors.
In this chapter, we will introduce our research work focusing on the novel synthesis of high-quality graphene and graphene-based composites for renewable clean energy and environmental protection. The novel quenching process was developed to produce high-quality graphene on a large scale from cheap expanded graphite. Based on high-quality graphene sheets, Ag/graphene composite was synthesized as a promising antibacterial agent. In addition, we also developed small-size Pd@PdO clusters on nitrogen-doped graphene sheets by facile oxidation-reduction method, which was used in Suzuki-Miyaura reactions with high yields and good structural stability. The TiO2/graphene with excellent photocatalytic performance was also synthesized for environmental protection application.

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Nächstes Kapitel Optical Characterization of Graphene and Its Derivatives: An Experimentalist’s Perspective
Literatur
1.
K. Geim, K.S. Novoselov, The rise of graphene. Nat. Mater. 6, 183–191 (2007)CrossRef
2.
X. Li, X. Wang, L. Zhang, S. Lee, H. Dai, Chemically derived, Ultrasmooth graphene nanoribbon semiconductors. Science 319, 1229–1232 (2008)CrossRef
3.
S. Park, R.S. Ruoff, Chemical methods for the production of graphenes. Nat. Nanotechnol. 5, 217–224 (2009)CrossRef
4.
S. Patchkovskii, J.S. Tse, S.N. Yurchenko, L. Zhechkov, T. Heine, G. Seifert, Graphene nanostructures as tunable storage media for molecular hydrogen. PNAS 102, 10439–10444 (2005)CrossRef
5.
E. Hendry, P.J. Hale, J. Moger, A.K. Savchenko, S.A. Mikhailov, Coherent nonlinear optical response of graphene. Phys. Rev. Lett. 105, 212–217 (2010)CrossRef
6.
M. Allen, V.C. Tung, R.B. Kaner, Honeycomb carbon: A review of graphene. Chem. Rev. 110, 132–145 (2010)CrossRef
7.
Q.J. Xiang, Y. JG, M. Jaroniec, Graphene-based semiconductor photocatalysts. Chem. Soc. Rev. 41, 782–796 (2012)CrossRef
8.
L.M. Zhang, S. Diao, Y.F. Nie, K. Yan, N. Liu, B.Y. Dai, Q. Xie, A. Reina, J. Kong, Z.F. Liu, Photocatalytic patterning and modification of graphene. J. Am. Chem. Soc. 133, 2706–2713 (2011)CrossRef
9.
Y.H. Zhang, Z.R. Tang, F. XZ, X. YJ, TiO2-graphene nanocomposites for gas-phase photocatalytic degradation of volatile aromatic pollutant: is TiO2-graphene truly different from other TiO2-carbon composite materials? ACS Nano 4, 7303–7314 (2010)CrossRef
10.
X.S. Li, W.W. Cai, J.H. An, S. Kim, J. Nah, D.X. Yang, R. Piner, A. Velamakanni, I. Jung, E. Tutuc, Large-area synthesis of high-quality and uniform graphene films on copper foils. Science 324, 1312–1314 (2009)CrossRef
11.
M.Y. Han, B. Ozyilmaz, Y.B. Zhang, P. Kim, Energy band-gap engineering of graphene nanoribbons. Phys. Rev. Lett. 98, 206805 (2007)CrossRef
12.
K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva, A.A. Firsov, Electric field effect in atomically thin carbon films. Science 306, 666–669 (2004)CrossRef
13.
A. Reina, X. Jia, J. Ho, D. Nezich, H. Son, V. Bulovic, M.S. Dresselhaus, J. Kong, Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. Nano. Lett. 9, 30–35 (2008)CrossRef
14.
A. Ciesielski, P. Samorì, Graphene via sonication assisted liquid-phase exfoliation. Chem. Soc. Rev. 4, 381–398 (2014)CrossRef
15.
M. Choucairl, J.A. Stride, Gram-scale production of graphene based on solvothermal synthesis and sonication. Nature Nanotech 4, 30–33 (2009)CrossRef
16.
G. Eda, G. Fanchini, M. Chhowalla, Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material. Nature Nanotech 3, 270–274 (2008)CrossRef
17.
B. Jiang, C. Tian, Q. Pan, Z. Jiang, J. Wang, W. Yan, H. Fu, Enhanced photocatalytic activity and electron transfer mechanisms of graphene/TiO2 with exposed {001} facets. J. Phys. Chem. C 115, 23718–23725 (2011)CrossRef
18.
H. Zhang, X.J. Lv, Y.M. Li, Y. Wang, J.H. Li, P25-graphene composite as a high performance photocatalyst. ACS Nano 4, 380–386 (2010)CrossRef
19.
G. Williams, B. Seger, P.V. Kamat, TiO2-graphene nanocomposites. UV-assisted photocatalytic reduction of graphene oxide. ACS Nano 2, 1487–1491 (2008)CrossRef
20.
Y.Y. Liang, H.L. Wang, H.S. Casalongue, Z. Chen, H.J. Dai, TiO2 nanocrystals grown on graphene as advanced photocatalytic hybrid materials. Nano Res. 3, 701–705 (2010)CrossRef
21.
A.A. Polyakov, Quenching properties of parts having stress concentrators. Met. Sci. Heat Treat 37, 324–325 (1995)CrossRef
22.
B.J. Jiang, C.G. Tian, L. Wang, X. YX, R.H. Wang, Y.Q. Qiao, Y.G. Ma, F. HG, Facile fabrication of high quality graphene from expandable graphite: Simultaneous exfoliation and reduction. Chem. Commun. 46, 4920–4922 (2010)CrossRef
23.
Y.B. Tang, C.S. Lee, Z.H. Chen, G.D. Yuan, Z.H. Kang, S.T. Lee, High-quality graphenes via a facile quenching method for field-effect transistors. Nano Lett. 9, 1374–1377 (2009)CrossRef
24.
X. YX, H. Bai, L. GW, C. Li, G.Q. Shi, Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets. J. Am. Chem. Soc. 130, 5856–5857 (2008)CrossRef
25.
S. Stankovich, R.D. Piner, S.T. Nguyen, R.S. Ruoff, Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets. Carbon 44, 3342–3347 (2006)CrossRef
26.
Y.M. Li, L.H. Tang, J.H. Li, Preparation and electrochemical performance for methanol oxidation of pt/graphene nanocomposites. Electrochem. Commun. 11, 846–849 (2009)CrossRef
27.
J.F. Shen, M. Shi, B. Yan, H.W. Ma, N. Li, M.X. Ye, One-pot hydrothermal synthesis of ag-reduced graphene oxide composite with ionic liquid. J. Mater. Chem. 21, 7795–7801 (2011)CrossRef
28.
R. Muszynski, B. Seger, P.V. Kamat, Decorating graphene sheets with gold nanoparticles. J. Phys. Chem. C 112, 5263–5266 (2008)CrossRef
29.
J. Liu, S. Fu, B. Yuan, Y. Li, Z. Deng, Toward a universal “adhesive nanosheet” for the assembly of multiple nanoparticles based on a protein-induced reduction/decoration of graphene oxide. J. Am. Chem. Soc. 132, 7279–7281 (2010)CrossRef
30.
J. Liu, H. Bai, Y. Wang, Z. Liu, X. Zhang, D.D. Sun, Self-assembling TiO2 nanorods on large graphene oxide sheets at a two-phase interface and their anti-recombination in photocatalytic applications. Adv. Funct. Mater. 20, 4175–4181 (2010)CrossRef
31.
Z. Yin, S. Wu, X. Zhou, X. Huang, Q. Zhang, F. Boey, H. Zhang, Electrochemical deposition of zno nanorods on transparent reduced graphene oxide electrodes for hybrid solar cells. Small 6, 307–312 (2010)CrossRef
32.
M. Feng, R.Q. Sun, H.B. Zhan, Y. Chen, Lossless synthesis of graphene nanosheets decorated with tiny cadmium sulfide quantum dots with excellent nonlinear optical properties. Nanotechnol 21, 589–594 (2010)
33.
Y.T. Kim, J.H. Han, B.H. Hong, Y.U. Kwon, Electrochemical synthesis of CdSe quantum-dot arrays on a graphene basal plane using mesoporous silica thin-film templates. Adv. Mater. 22, 515–518 (2010)CrossRef
34.
A. Melaiye, Z. Sun, K. Hindi, A. Milsted, D. Ely, D.H. Reneker, C.A. Tessier, W.J. Youngs, Silver(I)−imidazole cyclophane gem-diol complexes encapsulated by electrospun tecophilic nanofibers: Formation of nanosilver particles and antimicrobial activity. J. Am. Chem. Soc. 127, 2285–2291 (2005)CrossRef
35.
B.J. Jiang, C.G. Tian, G. Song, W. Chang, G.F. Wang, W.Q.F. HG, A novel ag/graphene composite: Facile fabrication and enhanced antibacterial properties. J. Mater. Sci. 48, 1980–1985 (2013)CrossRef
36.
H. Zhang, G. Chen, Potent antibacterial activities of Ag/TiO2 nanocomposite powders synthesized by a one-pot sol-gel method. Environ. Sci. Technol. 43, 2905–2910 (2009)CrossRef
37.
C.G. Navarro, R.T. Weitz, A.M. Bittner, M. Scolari, A. Mews, M. Burghard, K. Kern, Electronic transport properties of individual chemically reduced graphene oxide sheets. Nano Lett. 7, 3499–3503 (2007)CrossRef
38.
A. Mukhopadhyay, S. Basak, J.K. Das, S.K. Medda, K. Chattopadhyay, G. De, Ag-TiO2 nanoparticle Codoped SiO2 films on ZrO2 barrier-coated glass substrates with antibacterial activity in ambient condition. ACS Appl. Mater. Interfaces 2, 2540–2546 (2010)CrossRef
39.
N. Hoshiya, M. Shimoda, H. Yioshikawa, Y. Yamashita, S. Shuto, M. Arisawa, Sulfur modification of au via treatment with piranha solution provides low-Pd releasing and recyclable Pd material, SAPd. J. Am. Chem. Soc. 132, 7270–7272 (2010)CrossRef
40.
S. Pylypenko, A. Queen, T.S. Olson, A. Dameron, K. O’Neill, K.C. Neyerlin, B. Pivovar, H.N. Dinh, D.S. Ginley, T. Gennett, Tuning carbon-based fuel cell catalyst support structures via nitrogen functionalization. I. Investigation of structural and compositional modification of highly oriented pyrolytic graphite model catalyst supports as a function of nitrogen implantation dose. J. Phys. Chem. C 115, 13667–13675 (2011)CrossRef
41.
B.J. Jiang, S.Z. Song, G.Q. Wang, W. Chu, H.F. Li, H. Xu, C.G. Tian, F. HG, Nitrogen-doped graphene supported Pd@PdO core– shell clusters for C─C coupling reactions. Nano Res. 7(9), 1280–1290 (2014)CrossRef
42.
S. Pylypenko, A. Borisevich, K.L. More, A.R. Corpuz, T. Holme, A.A. Dameron, T.S. Olson, H.N. Dinh, T. Gennette, R. O’Hayre, Nitrogen: unraveling the secret to stable carbon-supported Pt-alloy electrocatalysts. Energy Environ. Sci. 6, 2957–2965 (2013)CrossRef
43.
X.M. Chen, W. GH, J.M. Chen, X. Chen, Z.X. Xie, X.R. Wang, Synthesis of “clean” and well-dispersive Pd nanoparticles with excellent electrocatalytic property on graphene oxide. J. Am. Chem. Soc. 133, 3693–3695 (2011)CrossRef
44.
G. Riegel, J.R. Bolton, Photocatalytic efficiency variability in TiO2 particles. J. R. J. Phys. Chem 99, 4215–4224 (1995)CrossRef
45.
O. Carp, C.L. Huisman, A. Reller, Photoinduced reactivity of titanium dioxide. Sol. State Chem. 32, 33–177 (2004)CrossRef
46.
C.N.R. Rao, K. Biswas, K.S. Subrahmanyam, A. Govindaraj, Graphene, the new nanocarbon. J. Mater. Chem. 19, 2457–2469 (2009)CrossRef
47.
X. Gong, A. Selloni, Reactivity of anatase TiO2 nanoparticles: The role of the minority (001) surface. J. Phys. Chem. B 109, 19560–19562 (2005)CrossRef
48.
H.G. Yang, C.H. Sun, S.Z. Qiao, J. Zou, G. Liu, S.C. Smith, H.M. Cheng, L. GQ, Anatase TiO2 single crystals with a large percentage of reactive facets. Nature 453, 638–641 (2008)CrossRef
49.
X.G. Han, Q. Kuang, M.S. Jin, Z.X. Xie, L.S. Zheng, Synthesis of Titania nanosheets with a high percentage of exposed (001) facets and related photocatalytic properties. J. Am. Chem. Soc. 131, 3152–3153 (2009)CrossRef
50.
J. Li, S.B. Tang, L. Lu, H.C. Zeng, Preparation of nanocomposites of metals, metal oxides, and carbon nanotubes via self-assembly. J. Am. Chem. Soc. 129, 9401–9409 (2007)CrossRef
51.
H.B. Zhang, X.L. Pan, J. Liu, W.Z. Qian, F. Wei, Y.Y. Huang, X.H. Bao, Enhanced catalytic activity of sub-nanometer titania clusters confined inside double-wall carbon nanotubes. Chem. Sus. Chem. 4, 975–980 (2011)CrossRef
52.
F.M.F. De De Groot, M. Gnoni, J.C. Fuggle, J. Ghljsen, G.A. Sawatzky, H. Peterson, Oxygen 1s X-ray absorption edges of transition metal oxides. Phys. Rev. B 40, 5715–5723 (1989)CrossRef
Metadaten
Titel
The Synthesis and the Catalytic Properties of Graphene-Based Composite Materials
verfasst von
Baojiang Jiang, Ph.D
Chaoyang Li
Copyright-Jahr
2017
Buch
Carbon-related Materials in Recognition of Nobel Lectures by Prof. Akira Suzuki in ICCE

Print ISBN: 978-3-319-61650-6

Electronic ISBN: 978-3-319-61651-3

Copyright-Jahr: 2017

DOI
https://doi.org/10.1007/978-3-319-61651-3_1

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