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Erschienen in: Colloid and Polymer Science 1/2016

01.01.2016 | Original Contribution

The vesicle formation of β-CD and AD self-assembly of dumbbell-shaped amphiphilic triblock copolymer

verfasst von: Lujuan Xu, Xinyi Liang, Lin Zhang, Jinbi Wu, Zhanxian Li, Mingming Yu, Liuhe Wei

Erschienen in: Colloid and Polymer Science | Ausgabe 1/2016

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Abstract

Vesicles of a noncovalent dumbbell-shaped amphiphilic triblock copolymer were formed by self-assembly of host-guest inclusion between β-cyclodextrin containing poly(ethylene oxide) (β-CD-PEO) and adamantyl group containing polystyrene (AD-PS-AD) in solution. Addition of water into the copolymer resulted in the formation of new bowl-shaped and vesicle morphologies by adjusting not only ratio of solvents (THF dioxane or DMF) but also the length of the PS middle block in the guest polymer, which was ascribed to the large compound micelles (LCMs). The continuous phase of PS was composed of an assembly of reversed micelles (PEO core and PS corona) with hydrophilic PEO chains surrounding the structure at the polymer/aqueous solution interface in the larger compound micelles.

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Metadaten
Titel
The vesicle formation of β-CD and AD self-assembly of dumbbell-shaped amphiphilic triblock copolymer
verfasst von
Lujuan Xu
Xinyi Liang
Lin Zhang
Jinbi Wu
Zhanxian Li
Mingming Yu
Liuhe Wei
Publikationsdatum
01.01.2016
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 1/2016
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-015-3758-6

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