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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 9/2020

30.06.2020 | Original Contribution

Thermo-responsiveness of giant vesicles supporting hindered amines as reactive sites

verfasst von: Eri Yoshida

Erschienen in: Colloid and Polymer Science | Ausgabe 9/2020

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Abstract

The thermo-responsiveness of giant vesicles supporting 2,2,6,6-tetramethylpiperidine (TP), the hindered amine, and its reactivity on the vesicle surface were evaluated with the aim of creating a new artificial biomembrane model using the polymer vesicles having reactive sites on the surface. A light-scattering study demonstrated that the TP-supporting spherical vesicles reversibly self-assembled by responding to temperature changes. The vesicles underwent a two-step disruption by heating, the first, transformation into much smaller and deformed vesicles, and the second, transformation into micelles through the budding separation from the granulated vesicle surface. The vesicles were rapidly restored by cooling due to the aggregation of the micelles. The TP supported on the vesicle surface underwent oxidation by H2O2 to convert into 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO), accompanied by transformation from the spherical shape into a sheet. The TEMPO underwent a further reduction by L(+)-ascorbic acid into the hydroxylamine.
Vorheriger Artikel Surface tension of the oppositely charged sodium poly(styrene sulfonate) /benzyldimethylhexadecylammonium chloride and sodium poly(styrene sulfonate)/polyallylamine hydrochloride mixtures
Nächster Artikel Study on the surface properties and thermal stability of polysiloxane-based polyurethane elastomers with aliphatic and aromatic diisocyanate structures

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Metadaten
Titel
Thermo-responsiveness of giant vesicles supporting hindered amines as reactive sites
verfasst von
Eri Yoshida
Publikationsdatum
30.06.2020
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 9/2020
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-020-04697-2

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