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Erschienen in: Metallurgical and Materials Transactions A 13/2010

01.12.2010

Thermodynamic Modeling of the ZrO2-YO1.5-TiO2 System

verfasst von: Kun Wang, Chonghe Li, Hequan Dong, Xiaosu Ye, Xionggang Lu, Weizhong Ding

Erschienen in: Metallurgical and Materials Transactions A | Ausgabe 13/2010

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Abstract

The binary systems ZrO2-YO1.5, ZrO2-TiO2, and YO1.5-TiO2 are reassessed, and a set of self-consistent thermodynamic parameters, which can be reliably extrapolated into the ZrO2-YO1.5-TiO2 ternary system, are obtained. The substitutional solution model and the stoichiometric compound model are applied to the phase description in the ternary system, and the thermodynamic database of this ternary system is derived by the CALPHAD approach. It is noted that, except for the liquid phase, no ternary interaction parameters are introduced. The present evaluation can better describe the experimental phase diagrams reported recently at 1573 K, 1773 K, and 1873 K (1300 °C, 1500 °C, and 1600 °C). Thus, the optimized thermodynamic parameters may be authentic and can be applied to optimizing the compositions of the novel materials based on this ternary system.

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Metadaten
Titel
Thermodynamic Modeling of the ZrO2-YO1.5-TiO2 System
verfasst von
Kun Wang
Chonghe Li
Hequan Dong
Xiaosu Ye
Xionggang Lu
Weizhong Ding
Publikationsdatum
01.12.2010
Verlag
Springer US
Erschienen in
Metallurgical and Materials Transactions A / Ausgabe 13/2010
Print ISSN: 1073-5623
Elektronische ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-010-0405-1

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