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Journal of Materials Science: Materials in Electronics

Erschienen in:

11.06.2019

Tunable luminescence and energy transfer properties based on La₂O₃-P₂O₅:Dy³⁺/Tm³⁺ glasses

verfasst von: Tao Zhang, Jingxuan Wang, Yifan Xin, Xin Wang, Libo Yuan

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 13/2019

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Abstract

The white-LED material Dy³⁺/Tm³⁺ co-doped phosphate glass was prepared by a conventional melting method. The energy transfer in the two rare earth ions was supposed by changing the concentration of one doping ion and was further demonstrated by the fluorescence lifetime. The energy level transition mechanism between the rare earth ions was analyzed using the Inokuti–Hirayama theory. There were two kinds of energy transfer mechanisms from the dipole–quadrupole interaction (Dy³⁺ → Tm³⁺) and the quadrupole–quadrupole interaction (Tm³⁺→Dy³⁺). The luminescence color was tuned from a blue to a near standard white light emission using 350 nm excitation and adjusting the rare earth ion doping ratio. The results show that 15La₂O₃-85P₂O₅:xDy₂O₃-yTm₂O₃ glass is a promising UV-excited white photodiode material.

Vorheriger Artikel Effects of substrate annealing on wettability and intermetallic compound formation in Sn–3.0Cu/Cu systems

Nächster Artikel Preparation and electro responsive properties of Mg-doped BaTiO3 with novel morphologies

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Titel: Tunable luminescence and energy transfer properties based on La2O3-P2O5:Dy3+/Tm3+ glasses
verfasst von: Tao Zhang
Jingxuan Wang
Yifan Xin
Xin Wang
Libo Yuan
Publikationsdatum: 11.06.2019
Verlag: Springer US
Erschienen in: Journal of Materials Science: Materials in Electronics / Ausgabe 13/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-019-01567-8

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