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Journal of Materials Science
Erschienen in: Journal of Materials Science 12/2023

10.03.2023 | Chemical routes to materials

Unveiling the role of trace metal doping in transition metal oxides for boosting oxygen evolution reaction

verfasst von: Yifan Yang, Lixiong Xu, Wei Wang, Rong Han, Jun Ma, Mengqin Yao, Shuo Geng, Fei Liu

Erschienen in: Journal of Materials Science | Ausgabe 12/2023

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Abstract

Introducing oxygen vacancies in electrocatalysts through heteroatom doping has been deemed to be a promising strategy to modulate the electronic structure of electrocatalysts for improving electrocatalytic activity. However, there is a bewilderment for understanding the relationship between the oxygen vacancies and electrocatalytic activity of electrocatalysts because heteroatom doping can also modulate the electronic structure of electrocatalysts by heteroatom. In this work, trace metal-doped Co3O4 was synthesized to understand the relationship between the oxygen vacancies and OER activity of electrocatalysts without considering the influence of heteroatom. Trace metal doping has no influence on electronic structure but increases the content of oxygen vacancies of Co3O4. Among these trace metal-doped Co3O4, Zn-doped Co3O4 shows the superior OER performance owing to the most oxygen vacancies. Compared to the pristine Co3O4 nanorods, the overpotential of Zn-doped Co3O4 for the current density of 10 mA cm−2 was decreased 70 mV, indicating that only oxygen vacancies formation can enhance the OER activity of Co3O4. This work is helpful to understanding the relationship between catalytic activity and oxygen vacancies.

Graphical Abstract

Vorheriger Artikel Microfluidics-assisted, time-effective and continuous synthesis of bimetallic ZIF-8/67 under different synthesis conditions
Nächster Artikel Uniformly embedded PtCu alloy nanoparticles on mesoporous carbon nanospheres: a high-efficiency nanozyme for glucose detection

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Metadaten
Titel
Unveiling the role of trace metal doping in transition metal oxides for boosting oxygen evolution reaction
verfasst von
Yifan Yang
Lixiong Xu
Wei Wang
Rong Han
Jun Ma
Mengqin Yao
Shuo Geng
Fei Liu
Publikationsdatum
10.03.2023
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 12/2023
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-023-08345-2

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