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16.09.2020 | Original Research

Use of a novel bio-magnetic nanocomposite synthesized from industrial tomato processing waste for methylene blue removal: sorption optimization, kinetic and isotherm studies

verfasst von: Yekbun Avşar Teymur, Fuat Güzel, Filiz Koyuncu, Gülbahar Akkaya Sayğılı

Erschienen in: Cellulose | Ausgabe 16/2020

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Abstract

In the current study, the methylene blue (MB) dye sorption performance of a new biomagnetic composite (MTNC) synthesized by modification with Fe₃O₄ nanoparticles of industrial tomato processing (Lycopersicon esculentum Mill.) processing solid waste (TW) was investigated. The XRD, BET, SEM, FT-IR and VSM analysis techniques were used in the characterization of MTNC. The specific surface area, total pore volume, micropore volume, mesopore volume, and mean pore diameter values of MTNC are 28.21 m²/g, 0.082 cm³/g, 0.003 cm³/g, 0.079 and 11.06 nm, respectively. Also, its saturation magnetization value was determined to be 24.80 emu/g. The maximum MB sorption capacity of the MTNC determined to be 90.09 mg/g under optimized conditions of the solution pH of 7.0, WPC dosage of 50 mg, contact time of 180 min, and solution temperature of 50 °C. The kinetics and isotherm data were well fitted to the pseudo-second order kinetic and Langmuir isotherm models, respectively. The thermodynamic parameters calculated for the MTNC-MB sorption system proved that the process was spontaneous and endothermic in nature.

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Abbaszadeh S, Nodeh HR, Alwi SRW (2018) Bio-adsorbent derived from papaya peel waste and magnetic nanoparticles fabricated for lead determination. Pure Appl Chem 90(1):79–92. https://doi.org/10.1515/pac-2017-0503CrossRef

Agriculture and Livestock-Tomato, TR (2018) T.R. Ministry of Food reports, Item No: 20. https://arastirma.tarim.gov.tr/tepge

Ahmed MJ, Theydan SK (2012) Adsorption of cephalexin onto activated carbons from Albizia lebbeck seed pods by microwave-induced KOH and K₂CO₃ activations. Chem Eng J 211:200–207. https://doi.org/10.1016/j.cej.2012.09.089CrossRef

Ahmed MJ, Theydan SK (2013) Microwave assisted preparation of microporous activated carbon from Siris seed pods for adsorption of metronidazole antibiotic. Chem Eng J 214:310–318. https://doi.org/10.1016/j.cej.2012.10.101CrossRef

Ai L, Zhang C, Chen Z (2011a) Removal of methylene blue from aqueous solution by a solvothermal-synthesized graphene/magnetite composite. J Hazard Mater 192(3):1515–1524. https://doi.org/10.1016/j.jhazmat.2011.06.068CrossRefPubMed

Ai L, Zhou Y, Jiang J (2011b) Removal of methylene blue from aqueous solution by montmorillonite/CoFe₂O₄ composite with magnetic separation performance. Desalination 266(1–3):72–77. https://doi.org/10.1016/j.desal.2010.08.004CrossRef

Babic BM, Milonjic SK, Polovina MJ et al (1999) Point of zero charge and intrinsic equilibrium constants of activated carbon cloth. Carbon 37(3):477–481. https://doi.org/10.1016/S0008-6223(98)00216-4CrossRef

Boehm HP (1994) Some aspects of the surface chemistry of carbon blacks and other carbons. Carbon 32(5):759–769. https://doi.org/10.1016/0008-6223(94)90031-0CrossRef

Cao JS, Lin JX, Fang F et al (2014) A new absorbent by modifying walnut shell for the removal of anionic dye: kinetic and thermodynamic studies. Bioresour Technol 163:199–205. https://doi.org/10.1016/j.biortech.2014.04.046CrossRefPubMed

Chen Y, Zhai SR, Liu N et al (2013) Dye removal of activated carbons prepared from NaOH-pretreated rice husks by low-temperature solution-processed carbonization and H₃PO₄ activation. Bioresour Technol 144:401–409. https://doi.org/10.1016/j.biortech.2013.07.002CrossRefPubMed

Danish M, Ahmad T, Nadhari WNAW et al (2018) Optimization of banana trunk-activated carbon production for methylene blue-contaminated water treatment. Appl Water Sci 8(1):9. https://doi.org/10.1007/s13201-018-0644-7CrossRef

Deniz F, Karaman S (2011) Removal of Basic Red 46 dye from aqueous solution by pine tree leaves. Chem Eng J 170(1):67–74. https://doi.org/10.1016/j.cej.2011.03.029CrossRef

Doğan M, Özdemir Y, Alkan M (2007) Adsorption kinetics and mechanism of cationic methyl violet and methylene blue dyes onto sepiolite. Dyes Pigments 75(3):701–713. https://doi.org/10.1016/j.dyepig.2006.07.023CrossRef

Ghaedi M, Ansari A, Habibi MH et al (2014) Removal of malachite green from aqueous solution by zinc oxide nanoparticle loaded on activated carbon: kinetics and isotherm study. J Ind Eng Chem 20(1):17–28. https://doi.org/10.1016/j.jiec.2013.04.031CrossRef

Gregg SJ, Sing KSW (1982) Adsorption, surface area and porosity, 2nd edn. Academic Press, London

Güzel F, Sayğılı H, Sayğılı GA et al (2014) Elimination of anionic dye by using nanoporous carbon prepared from an industrial biowaste. J Mol Liq 194:130–140. https://doi.org/10.1016/j.molliq.2014.01.018CrossRef

Han S, Zhao F, Sun J et al (2013) Removal of p-nitrophenol from aqueous solution by magnetically modified activated carbon. J Magn Magn Mater 341:133–137. https://doi.org/10.1016/j.jmmm.2013.04.018CrossRef

Huang L, Sun Y, Wang W et al (2011) Comparative study on characterization of activated carbons prepared by microwave and conventional heating methods and application in removal of oxytetracycline (OTC). Chem Eng J 171(3):1446–1453. https://doi.org/10.1016/j.cej.2011.05.041CrossRef

Isa MH, Lang LS, Asaari FA et al (2007) Low cost removal of disperse dyes from aqueous solution using palm ash. Dyes Pigments 74(2):446–453. https://doi.org/10.1016/j.dyepig.2006.02.025CrossRef

Jang J, Miran W, Divine SD et al (2017) Rice straw-based biochar beads for the removal of radioactive strontium from aqueous solution. Sci Total Environ 615:698–707. https://doi.org/10.1016/j.scitotenv.2017.10.023CrossRefPubMed

Ji B, Wang J, Song H et al (2019) Removal of methylene blue from aqueous solutions using biochar derived from a fallen leaf by slow pyrolysis: behavior and mechanism. J Environ Chem Eng 7(3):103036. https://doi.org/10.1016/j.jece.2019.103036CrossRef

Jiang R, Tian J, Zheng H et al (2015) A novel magnetic adsorbent based on waste litchi peels for removing Pb(II) from aqueous solution. J Environ Manage 155:24–30. https://doi.org/10.1016/j.jenvman.2015.03.009CrossRefPubMed

Kavitha D, Namasivayam C (2007) Experimental and kinetic studies on methylene blue adsorption by coir pith carbon. Bioresour Technol 98(1):14–21. https://doi.org/10.1016/j.biortech.2005.12.008CrossRefPubMed

Khaled A, El Nemr A, El-Sikaily A et al (2009) Removal of Direct N Blue-106 from artificial textile dye effluent using activated carbon from orange peel: adsorption isotherm and kinetic studies. J Hazard Mater 165(1–3):100–110. https://doi.org/10.1016/j.jhazmat.2008.09.122CrossRefPubMed

Khorasani AC, Shojaosadati SA (2019) Magnetic pectin-Chlorella vulgaris biosorbent for the adsorption of dyes. J Environ Chem Eng 7(3):103062. https://doi.org/10.1016/j.jece.2019.103062CrossRef

Köseoğlu E, Akmil-Başar C (2015) Preparation, structural evaluation and adsorptive properties of activated carbon from agricultural waste biomass. Adv Powder Technol 26:811–818. https://doi.org/10.1016/j.apt.2015.02.006CrossRef

Koyuncu F, Güzel F, Sayğılı H (2018) Role of optimization parameters in the production of nanoporous carbon from mandarin shells by microwave-assisted chemical activation and utilization as dye adsorbent. Adv Powder Technol 29(9):2108–2118. https://doi.org/10.1016/j.apt.2018.05.019CrossRef

Kumar PS, Ramalingam S, Senthamarai C et al (2010) Adsorption of dye from aqueous solution by cashew nut shell: studies on equilibrium isotherm, kinetics and thermodynamics of interactions. Desalination 261:52–60. https://doi.org/10.1016/j.desal.2010.05.032CrossRef

Kyzas GZ, Deliyanni EA, Lazaridis NK (2014) Magnetic modification of microporous carbon for dye adsorption. J Colloid Interface Sci 430:166–173. https://doi.org/10.1016/j.jcis.2014.05.049CrossRefPubMed

Lee LY, Chin DZB, Lee XJ et al (2015) Evaluation of Abelmoschus esculentus (lady’s finger) seed as a novel biosorbent for the removal of Acid Blue 113 dye from aqueous solutions. Process Saf Environ 94:329–338. https://doi.org/10.1016/j.psep.2014.08.004CrossRef

Li GY, Jiang YR, Huang KL et al (2008) Kinetics of adsorption of Saccharomyces cerevisiae mandelated dehydrogenase on magnetic Fe₃O₄-chitosan nanoparticle. Colloids Surf A 20(3):11–18. https://doi.org/10.1016/j.colsurfa.2008.01.017CrossRef

Madrakian T, Afkhami A, Ahmadi M (2012) Adsorption and Kinetic Studies of seven different organic dyes onto magnetite nanoparticles loaded tea waste and removal of them from wastewater samples. Spectrochım Acta A 99:102–109. https://doi.org/10.1016/j.saa.2012.09.025CrossRef

Mashkoor F, Nasar A (2020) Magnetized Tectona grandis sawdust as a novel adsorbent: preparation, characterization, and utilization for the removal of methylene blue from aqueous solution. Cellulose 27(5):2613–2635. https://doi.org/10.1007/s10570-019-02918-8CrossRef

Nata IF, Salim GW, Lee CK (2010) Facile preparation of magnetic carbonaceous nanoparticles for Pb²⁺ ions removal. J Hazard Mater 183(1–3):853–858. https://doi.org/10.1016/j.jhazmat.2010.07.105CrossRefPubMed

Qian WC, Luo XP, Wang X et al (2018) Removal of methylene blue from aqueous solution by modified bamboo hydrochar. Ecotoxicol Environ Saf 157:300–306. https://doi.org/10.1016/j.ecoenv.2018.03.088CrossRefPubMed

Sayğılı H, Güzel F (2015) Performance of new mesoporous carbon sorbent prepared from grape industrial processing wastes for malachite green and congo red removal. Chem Eng Res Des 100:27–38. https://doi.org/10.1016/j.cherd.2015.05.014CrossRef

Sayğılı H, Güzel F (2016) High surface area mesoporous activated carbon from tomato processing solid waste by zinc chloride activation: process optimization, characterization and dyes adsorption. J Clean Prod 113:995–1004. https://doi.org/10.1016/j.jclepro.2015.12.055CrossRef

Sayğılı H, Güzel F, Önal Y (2015) Conversion of grape industrial processing waste to activated carbon sorbent and its performance in cationic and anionic dyes adsorption. J Clean Prod 93:84–93. https://doi.org/10.1016/j.jclepro.2015.01.009CrossRef

Schwanninger M, Rodrigues JC, Pereira H et al (2004) Effects of short-time vibratory ball milling on the shape of FT-IR spectra of wood and cellulose. Vib Spectrosc 36(1):23–40. https://doi.org/10.1016/j.vibspec.2004.02.003CrossRef

Shakoor S, Nasar A (2016) Removal of methylene blue dye from artificially contaminated water using citrus limetta peel waste as a very low cost adsorbent. J Taiwan Inst Chem Eng 66:154–163. https://doi.org/10.1016/j.jtice.2016.06.009CrossRef

Shakoor S, Nasar A (2017) Adsorptive treatment of hazardous methylene blue dye from artificially contaminated water using cucumis sativus peel waste as a low-cost adsorbent. Groundw Sustain Dev 5:152–159CrossRef

Sharifpour E, Haddadi H, Ghaedi M (2016) Simultaneous and rapid dye removal in the presence of ultrasound waves and a nano-structured material: experimental design methodology, equilibrium and kinetics. RSC Adv 6(70):66311–66319. https://doi.org/10.1039/c6ra13286cCrossRef

Sing KSW, Everett DH, Haul RAW et al (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl Chem 57(4):603–619. https://doi.org/10.1351/pac198557040603CrossRef

Soleimani K, Tehrani AD, Adeli M (2018) Bioconjugated graphene oxide hydrogel as an effective adsorbent for cationic dyes removal. Ecotoxicol Environ Saf 147:34–42. https://doi.org/10.1016/j.ecoenv.2017.08.021CrossRefPubMed

Sun L, Wan S, Luo W (2013) Biochars prepared from anaerobic digestion residue, palm bark, and eucalyptus for adsorption of cationic methylene blue dye: characterization, equilibrium, and kinetic studies. Bioresour Technol 140:406–413. https://doi.org/10.1016/j.biortech.2013.04.116CrossRefPubMed

Tan KL, Hameed BH (2017) Insight into the adsorption kinetics models for the removal of contaminants from aqueous solutions. J Taiwan Inst Chem Eng 74:25–48. https://doi.org/10.1016/j.jtice.2017.01.024CrossRef

Tan IAW, Ahmad AL, Hameed BH (2009) Adsorption isotherms, kinetics, thermodynamics and desorption studies of 2,4,6-trichlorophenol on oil palm empty fruit bunch-based activated carbon. J Hazard Mater 164:473–482. https://doi.org/10.1016/j.jhazmat.2008.08.025CrossRefPubMed

Torkian L, Ashtiani BG, Amereh E et al (2012) Adsorption of Congo red onto mesoporous carbon material: equilibrium and kinetic studies. Desal Water Treat 44(1–3):118–127. https://doi.org/10.1080/19443994.2012.691789CrossRef

Tuzen M, Sarı A, Saleh TA (2018) Response surface optimization, kinetic and thermodynamic studies for effective removal of rhodamine B by magnetic AC/CeO₂ nanocomposite. J Environ Manage 206:170–177. https://doi.org/10.1016/j.jenvman.2017.10.016CrossRefPubMed

Uddin MK, Nasar A (2020) Decolorization of basic dyes solution by utilizing fruit seed powder. KSCE J Civ Eng 24(2):345–355. https://doi.org/10.1007/s12205-020-0523-2CrossRef

Üner O, Bayrak Y (2018) The effect of carbonization temperature, carbonization time and impregnation ratio on the properties of activated carbon produced from Arundo donax. Microporous Mesoporous Mater 268:225–234. https://doi.org/10.1016/j.micromeso.2018.04.037CrossRef

Wang F (2017) Effect of oxygen-containing functional groups on the adsorption of cationic dye by magneticgraphene nanosheets. Chem Eng Res Des 128:155–161. https://doi.org/10.1016/j.cherd.2017.10.007CrossRef

Wang S, Boyjoo Y, Choueib A (2005) A comparative study of dye removal using fly ash treated by different methods. Chemosphere 60:1401–1407. https://doi.org/10.1016/j.chemosphere.2005.01.091CrossRefPubMed

Xiao H, Peng H, Deng S et al (2012) Preparation of activated carbon from edible fungi residue by microwave assisted K₂CO₃ activation-application in reactive black 5 adsorption from aqueous solution. Bioresour Technol 111:127–133. https://doi.org/10.1016/j.biortech.2012.02.054CrossRefPubMed

Xu Q, Zhou Q, Pan M et al (2020) Interaction between chlortetracycline and calcium-rich biochar: enhanced removal by adsorption coupled with flocculation. Chem Eng J 382:122705. https://doi.org/10.1016/j.cej.2019.122705CrossRef

Yao Y, Xu F, Chen M (2010) Adsorption behavior of methylene blue on carbon nanotubes. Bioresour Technol 101(9):3040–3046. https://doi.org/10.1016/j.biortech.2009.12.042CrossRefPubMed

Zhang W, Li H, Kan X et al (2012) Adsorption of anionic dyes from aqueous solutions using chemically modified straw. Bioresour Technol 117:40–47. https://doi.org/10.1016/j.biortech.2012.04.064CrossRefPubMed

Titel: Use of a novel bio-magnetic nanocomposite synthesized from industrial tomato processing waste for methylene blue removal: sorption optimization, kinetic and isotherm studies
verfasst von: Yekbun Avşar Teymur
Fuat Güzel
Filiz Koyuncu
Gülbahar Akkaya Sayğılı
Publikationsdatum: 16.09.2020
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 16/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03442-w

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