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17.06.2022 | Original Article

Valorization of bagasse alkali lignin to water-soluble derivatives through chemical modification

verfasst von: Ali Abdulkhani, Zeinab Khorasani, Yahya Hamzeh, Fariborz Momenbeik, Zahra Echresh zadeh, Fubao Sun, Meysam Madadi, XueMing Zhang

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 7/2024

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Abstract

Black liquor is the by-product of the pulping process where the lignin, hemicellulose, and extractive materials are separated from wood to produce paper pulp. As one of the primary lignin sources, black liquor is considered an important energy source from biomass to produce biofuels and value-added chemicals. However, soda alkaline lignin has limited industrial applications due to its insolubility in water and lack of reactivity. Therefore, chemical modification is essential to enhance its industrial applications. In this study, alkali lignin from bagasse was modified through sulfonation, sulfomethylation, and amination processes using different reaction conditions. The structural analysis of obtained products was investigated by FTIR and ¹H-NMR. The molecular weight distribution and thermal stability of the water-soluble products were analyzed using gel permeation chromatography (GPC) and thermogravimetric analysis (TGA), respectively. The elemental analysis was used to measure the elements (CHNSO) of the obtained water-soluble derivatives. The chemical structure analysis of the samples with FTIR and ¹HNMR confirmed the modification processes. The results indicate that modification led to increased water solubility and a decrease in the precipitation pH of lignin samples, due to the introduction of sulfonate and amin functunal groups on lignin. In addition, the molecular weight and thermal stability of modified lignins were increased due to the presence of sulfonate and amine groups compared to unmodified lignin.

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Vorheriger Artikel A comparative study on pyrolysis behaviors, product distribution, and kinetics of waste cotton stalk under different organic acidic solutions pretreatment

Nächster Artikel Theoretical analysis of the thermal characteristics of Ree–Eyring nanofluid flowing past a stretching sheet due to bioconvection

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Titel: Valorization of bagasse alkali lignin to water-soluble derivatives through chemical modification
verfasst von: Ali Abdulkhani
Zeinab Khorasani
Yahya Hamzeh
Fariborz Momenbeik
Zahra Echresh zadeh
Fubao Sun
Meysam Madadi
XueMing Zhang
Publikationsdatum: 17.06.2022
Verlag: Springer Berlin Heidelberg
Erschienen in: Biomass Conversion and Biorefinery / Ausgabe 7/2024
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI: https://doi.org/10.1007/s13399-022-02935-x

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