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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 15/2020

19.06.2020

Vertical phase segregation suppression for efficient FA-based quasi-2D perovskite solar cells via HCl additive

verfasst von: Yuepeng Li, Haijin Li, Liuwen Tian, Qiyun Wang, Fengkai Wu, Fu Zhang, Lin Du, Yuelong Huang

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 15/2020

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Abstract

Ruddlesden–Popper (RP) layered perovskites (with general formula of (RNH3)2An−1MnX3n+1) have drawn tremendous attention due to their excellent ambient stability while retaining promising device performance. However, quasi-2D perovskites with mixed-cation often suffer from severe phase segregation and vertically aligned multiple perovskite phases (with small n phases concentrated on the bottom and large n phases on the top) are usually formed. Here, we report a strategy to suppress vertical phase segregation by using hydrochloric acid (HCl) additive. As a result, homogenous quasi-2D perovskite films with uniform phase distribution and enhanced film quality are successfully obtained via this additive strategy, which is confirmed by PL measurements. With uniform distribution of different n value phases and high-quality film, FA-based quasi-2D perovskite solar cells with an efficiency of 13.16% and excellent stability was fabricated. This strategy paves a way to develop stable and efficient quasi-2D perovskite solar cells by suppressing phase segregation.
Vorheriger Artikel Improve piezoelectricity in BaTiO3-based ceramics with large electrostriction coefficient
Nächster Artikel Metal–organic framework-derived cobalt diselenide as an efficient electrocatalyst for dye-sensitized solar cells

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Metadaten
Titel
Vertical phase segregation suppression for efficient FA-based quasi-2D perovskite solar cells via HCl additive
verfasst von
Yuepeng Li
Haijin Li
Liuwen Tian
Qiyun Wang
Fengkai Wu
Fu Zhang
Lin Du
Yuelong Huang
Publikationsdatum
19.06.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 15/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-03775-z

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