Skip to main content
Erschienen in: Journal of Materials Science 11/2014

01.06.2014 | Interfaces and Intergranular Boundaries

Visualization of deuterium flux and grain boundary diffusion in duplex stainless steel and Fe–30 % Ni alloy, using secondary ion mass spectrometry equipped with a Ga focused ion beam

verfasst von: Tomohito Tanaka, Kazuto Kawakami, Shun-ichi Hayashi

Erschienen in: Journal of Materials Science | Ausgabe 11/2014

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Time of flight secondary ion mass spectrometry (TOF-SIMS) equipped with a high spatial resolution Ga focused ion beam (Ga-FIB) was applied to understand hydrogen diffusion and desorption behavior in duplex stainless steel and Fe–30 % Ni alloys. Deuterium was used as a tracer of hydrogen. Results showed that the secondary ion intensity from body-centered cubic (bcc) and face-centered cubic (fcc) Fe represents the flux of deuterium from the surface and the concentration of deuterium, respectively. The deuterium-depleted zone can be visualized from the interface between bcc and fcc phase to fcc Fe on the surface. Furthermore, direct visualization of the grain boundary diffusion of deuterium is also possible in fcc Fe–30 % Ni alloys, using Ga-FIB-TOF-SIMS.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat da Silva JRG, Stafford SW, McLellan RE (1976) The thermodynamics of the hydrogen-iron system. J Less Common Metals 49:407–420CrossRef da Silva JRG, Stafford SW, McLellan RE (1976) The thermodynamics of the hydrogen-iron system. J Less Common Metals 49:407–420CrossRef
2.
Zurück zum Zitat Hagi H (1994) Diffusion coefficient of hydrogen in iron without trapping by dislocations and impurities. Mater Trans JIM 35:112–117 Hagi H (1994) Diffusion coefficient of hydrogen in iron without trapping by dislocations and impurities. Mater Trans JIM 35:112–117
3.
Zurück zum Zitat Sakamoto Y, Katayama H (1982) The electrochemical determination of diffusivity and solubility of hydrogen in an austenitic type 304 steel. J Japan Inst Metals 46:805–814 Sakamoto Y, Katayama H (1982) The electrochemical determination of diffusivity and solubility of hydrogen in an austenitic type 304 steel. J Japan Inst Metals 46:805–814
4.
Zurück zum Zitat Park YD, Maroef IS, Landau A, Olson DL (2002) Retained austenite as a hydrogen trap in steel welds. Weld J 81(2):27–35 Park YD, Maroef IS, Landau A, Olson DL (2002) Retained austenite as a hydrogen trap in steel welds. Weld J 81(2):27–35
5.
Zurück zum Zitat Turnbull A, Hutchings RB (1994) Analysis of hydrogen atom transport in a two-phase alloy. Mater Sci Eng A177:161–171CrossRef Turnbull A, Hutchings RB (1994) Analysis of hydrogen atom transport in a two-phase alloy. Mater Sci Eng A177:161–171CrossRef
6.
Zurück zum Zitat Chan SLI, Lee HL, Yang JR (1991) Effect of retained austenite of the hydrogen content and effective diffusivity of martensitic structure. Metall Trans A 22A:2579–2586CrossRef Chan SLI, Lee HL, Yang JR (1991) Effect of retained austenite of the hydrogen content and effective diffusivity of martensitic structure. Metall Trans A 22A:2579–2586CrossRef
7.
Zurück zum Zitat Escobar DP, Depover T, Duprez L, Verbeken K, Verhaege M (2012) Combined thermal desorption spectroscopy, differential scanning calorimetry, scanning electron microscopy and X-ray diffraction study of hydrogen trapping in cold deformed TRIP steel. Acta Mater 60:2593–2605CrossRef Escobar DP, Depover T, Duprez L, Verbeken K, Verhaege M (2012) Combined thermal desorption spectroscopy, differential scanning calorimetry, scanning electron microscopy and X-ray diffraction study of hydrogen trapping in cold deformed TRIP steel. Acta Mater 60:2593–2605CrossRef
8.
Zurück zum Zitat Asaoka A, Lapasset G, Aucouturier M, Lacomb (1978) Observation of hydrogen trapping in Fe–0.15 wt% Ti alloy by high resolution autoradiography. Corrosion 34:39–47CrossRef Asaoka A, Lapasset G, Aucouturier M, Lacomb (1978) Observation of hydrogen trapping in Fe–0.15 wt% Ti alloy by high resolution autoradiography. Corrosion 34:39–47CrossRef
9.
Zurück zum Zitat Wei FG, Tsuzaki K (2006) Quantitative analysis on hydrogen trapping of TiC particles in steel. Metall Mater Trans A 37A:331–353CrossRef Wei FG, Tsuzaki K (2006) Quantitative analysis on hydrogen trapping of TiC particles in steel. Metall Mater Trans A 37A:331–353CrossRef
10.
Zurück zum Zitat Asahi H, Hirakami D, Yamasaki S (2003) Hydrogen trapping behavior in vanadium-added steel. ISIJ Int 43:527–533CrossRef Asahi H, Hirakami D, Yamasaki S (2003) Hydrogen trapping behavior in vanadium-added steel. ISIJ Int 43:527–533CrossRef
11.
Zurück zum Zitat Kawakami K, Matsumiya T (2012) Numerical analysis of hydrogen trap state by TiC and V4C3 in bcc-Fe. ISIJ Int 52:1693–1697CrossRef Kawakami K, Matsumiya T (2012) Numerical analysis of hydrogen trap state by TiC and V4C3 in bcc-Fe. ISIJ Int 52:1693–1697CrossRef
12.
Zurück zum Zitat Frank RC, Baker JE, Altstetter CJ (1982) A SIMS study of the diffusion and trapping of deuterium in 302 stainless steel. Metall Trans A 13A:581–584CrossRef Frank RC, Baker JE, Altstetter CJ (1982) A SIMS study of the diffusion and trapping of deuterium in 302 stainless steel. Metall Trans A 13A:581–584CrossRef
13.
Zurück zum Zitat Ladna B, Birnbaum HK (1987) A study of hydrogen transport during plastic deformation. Acta Metall Mater 35:1775–1778CrossRef Ladna B, Birnbaum HK (1987) A study of hydrogen transport during plastic deformation. Acta Metall Mater 35:1775–1778CrossRef
14.
Zurück zum Zitat Dieudonné T, Marchetti L, Jomard F, Wery M, Chéne J, Allely C, Cugy P, Scott CP (2012) SIMS analysis of deuterium absorption and diffusion in austenitic Fe–Mn–C steels. Def Diff Forum 323–325:477–483CrossRef Dieudonné T, Marchetti L, Jomard F, Wery M, Chéne J, Allely C, Cugy P, Scott CP (2012) SIMS analysis of deuterium absorption and diffusion in austenitic Fe–Mn–C steels. Def Diff Forum 323–325:477–483CrossRef
15.
Zurück zum Zitat Takai K, Seki J, Homma Y (1995) Observation of trapping sites of hydrogen and deuterium in high-strength steels by using secondary ion mass spectrometry. Mater Trans JIM 36:1134–1139 Takai K, Seki J, Homma Y (1995) Observation of trapping sites of hydrogen and deuterium in high-strength steels by using secondary ion mass spectrometry. Mater Trans JIM 36:1134–1139
16.
Zurück zum Zitat Takai K, Chiba Y, Noguchi K, Nozue A (2002) Visualization of the hydrogen desorption process from ferrite, pearlite, and graphite by secondary ion mass spectrometry. Metall Mater Trans A 33A:2659–2665CrossRef Takai K, Chiba Y, Noguchi K, Nozue A (2002) Visualization of the hydrogen desorption process from ferrite, pearlite, and graphite by secondary ion mass spectrometry. Metall Mater Trans A 33A:2659–2665CrossRef
17.
Zurück zum Zitat Saintier N, Awane T, Olive JM, Matsuoka S, Murakami Y (2011) Analyses of hydrogen distribution around fatigue crack on type 304 stainless steel using secondary ion mass spectrometry. Int J Hydrogen Energ 36:8630–8640CrossRef Saintier N, Awane T, Olive JM, Matsuoka S, Murakami Y (2011) Analyses of hydrogen distribution around fatigue crack on type 304 stainless steel using secondary ion mass spectrometry. Int J Hydrogen Energ 36:8630–8640CrossRef
18.
Zurück zum Zitat Pérez TE, Garícia JO (1982) Direct observation of hydrogen evolution in the electron microscope scale. Scripta Metall 16:161–164CrossRef Pérez TE, Garícia JO (1982) Direct observation of hydrogen evolution in the electron microscope scale. Scripta Metall 16:161–164CrossRef
19.
Zurück zum Zitat Ichitani K, Kanno M (2003) Visualization of hydrogen diffusion in steels by high sensitivity hydrogen microprint technique. Sci Tech Adv Mater 4:545–551CrossRef Ichitani K, Kanno M (2003) Visualization of hydrogen diffusion in steels by high sensitivity hydrogen microprint technique. Sci Tech Adv Mater 4:545–551CrossRef
20.
Zurück zum Zitat Yalçì HK, Edmonds DV (1995) Application of the hydrogen microprint and the microautoradiography techniques to a duplex stainless steel. Mater Charact 34:97–104CrossRef Yalçì HK, Edmonds DV (1995) Application of the hydrogen microprint and the microautoradiography techniques to a duplex stainless steel. Mater Charact 34:97–104CrossRef
21.
Zurück zum Zitat Takahashi J, Kawakami K, Kobayashi Y, Tarui T (2010) The first direct observation of hydrogen trapping sites in TiC precipitation-hardening steel through atom probe tomography. Scripta Mater 63:261–264CrossRef Takahashi J, Kawakami K, Kobayashi Y, Tarui T (2010) The first direct observation of hydrogen trapping sites in TiC precipitation-hardening steel through atom probe tomography. Scripta Mater 63:261–264CrossRef
22.
Zurück zum Zitat Sekiba D, Yonemura H, Ogura S, Matsumoto M, Kitaoka Y, Yokoyama Y, Matsuzaki H, Narusawa T, Fukutani K (2011) Development of micro-beam NRA for hydrogen mapping: observation of fatigue-fractured surface of glassy alloys. Nucl Instrum Meth Phys Res B 269:627–631CrossRef Sekiba D, Yonemura H, Ogura S, Matsumoto M, Kitaoka Y, Yokoyama Y, Matsuzaki H, Narusawa T, Fukutani K (2011) Development of micro-beam NRA for hydrogen mapping: observation of fatigue-fractured surface of glassy alloys. Nucl Instrum Meth Phys Res B 269:627–631CrossRef
23.
Zurück zum Zitat Ueda K, Ishikawa K, Yoshimura M (1997) Two-dimensional hydrogen analysis by time-of-flight-type electron-stimulated desorption spectroscopy. Jpn J Appl Phys 36:L1254–L1256CrossRef Ueda K, Ishikawa K, Yoshimura M (1997) Two-dimensional hydrogen analysis by time-of-flight-type electron-stimulated desorption spectroscopy. Jpn J Appl Phys 36:L1254–L1256CrossRef
24.
Zurück zum Zitat Sakamoto T, Koizumi M, Kawasaki J, Yamaguchi J (2008) Development of a high lateral resolution TOF-SIMS apparatus for single particle analysis. Appl Surf Sci 255:1617–1620CrossRef Sakamoto T, Koizumi M, Kawasaki J, Yamaguchi J (2008) Development of a high lateral resolution TOF-SIMS apparatus for single particle analysis. Appl Surf Sci 255:1617–1620CrossRef
25.
Zurück zum Zitat Hayashi S, Takahashi T, Kanehashi K, Kubota N, Mizuno K, Kashiwakura S, Sakamoto T, Nagasaka T (2010) Chemical state of boron in coal fly ash investigated by focused-ion-beam time-of-flight secondary ion mass spectrometry (FIB-TOF-SIMS) and satellite-transition magic angle spinning nuclear magnetic resonance (STMAS NMR). Chemosphere 80:881–887CrossRef Hayashi S, Takahashi T, Kanehashi K, Kubota N, Mizuno K, Kashiwakura S, Sakamoto T, Nagasaka T (2010) Chemical state of boron in coal fly ash investigated by focused-ion-beam time-of-flight secondary ion mass spectrometry (FIB-TOF-SIMS) and satellite-transition magic angle spinning nuclear magnetic resonance (STMAS NMR). Chemosphere 80:881–887CrossRef
26.
Zurück zum Zitat Tanaka T, Fujishiro T, Shigesato G, Hayashi S (2013) Ga-FIB-TOF-SIMS analysis on grain boundary segregation/precipitation of boron in steels (under review) Tanaka T, Fujishiro T, Shigesato G, Hayashi S (2013) Ga-FIB-TOF-SIMS analysis on grain boundary segregation/precipitation of boron in steels (under review)
27.
Zurück zum Zitat Du YA, Ismer L, Rogal J, Hickel T, Neugebauer J, Drautz R (2011) First-principles study on the interaction of H interstitials with grain boundaries in α- and γ-Fe. Phys Rev B 84:144121–1–144121–13CrossRef Du YA, Ismer L, Rogal J, Hickel T, Neugebauer J, Drautz R (2011) First-principles study on the interaction of H interstitials with grain boundaries in α- and γ-Fe. Phys Rev B 84:144121–1–144121–13CrossRef
28.
Zurück zum Zitat Moreno I, Almagro JF, Llovet X (2002) Determination of nitrogen in duplex stainless steels by EPMA. Microchim Acta 139:105–110CrossRef Moreno I, Almagro JF, Llovet X (2002) Determination of nitrogen in duplex stainless steels by EPMA. Microchim Acta 139:105–110CrossRef
29.
Zurück zum Zitat Herrera C, Lima NB, Kliauga AM, Padilha AF (2008) Microstructure and texture of duplex stainless steel after melt-spinning processing. Mater Charact 59:79–83CrossRef Herrera C, Lima NB, Kliauga AM, Padilha AF (2008) Microstructure and texture of duplex stainless steel after melt-spinning processing. Mater Charact 59:79–83CrossRef
30.
Zurück zum Zitat De Laeter JR, Böhlke JK, De Bièvre P, Hidaka H, Peiser HS, Rosman KJR, Taylor PDP (2003) Atomic weights of the elements: review 2000. Pure Appl Chem 75:683–800CrossRef De Laeter JR, Böhlke JK, De Bièvre P, Hidaka H, Peiser HS, Rosman KJR, Taylor PDP (2003) Atomic weights of the elements: review 2000. Pure Appl Chem 75:683–800CrossRef
31.
32.
Zurück zum Zitat Benamati G, Donato A, Solina A, Valentini R, Lanza S (1994) Experimental studies on hydrogen diffusion and trapping in martensitic and austenitic stainless steels for fusion application. J Nucl Mater 212–215:1401–1405CrossRef Benamati G, Donato A, Solina A, Valentini R, Lanza S (1994) Experimental studies on hydrogen diffusion and trapping in martensitic and austenitic stainless steels for fusion application. J Nucl Mater 212–215:1401–1405CrossRef
33.
Zurück zum Zitat Shewmon PG (1989) Diffusion in Solids. Wiley, New York Shewmon PG (1989) Diffusion in Solids. Wiley, New York
34.
Zurück zum Zitat Tsuru T, Latanision RM (1982) Grain boundary transport of hydrogen in nickel. Scripta Metall Mater 16:575–578CrossRef Tsuru T, Latanision RM (1982) Grain boundary transport of hydrogen in nickel. Scripta Metall Mater 16:575–578CrossRef
35.
Zurück zum Zitat Schober T, Dieker C (1983) Observation of local hydrogen on nickel surface. Metall Trans A 14A:2440–2442CrossRef Schober T, Dieker C (1983) Observation of local hydrogen on nickel surface. Metall Trans A 14A:2440–2442CrossRef
36.
Zurück zum Zitat Harrison LG (1961) Influence of dislocations on diffusion kinetics in solids with particular reference to the alkali halides. Trans Farad Soc 57:1191–1199CrossRef Harrison LG (1961) Influence of dislocations on diffusion kinetics in solids with particular reference to the alkali halides. Trans Farad Soc 57:1191–1199CrossRef
Metadaten
Titel
Visualization of deuterium flux and grain boundary diffusion in duplex stainless steel and Fe–30 % Ni alloy, using secondary ion mass spectrometry equipped with a Ga focused ion beam
verfasst von
Tomohito Tanaka
Kazuto Kawakami
Shun-ichi Hayashi
Publikationsdatum
01.06.2014
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 11/2014
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-013-7956-7

Weitere Artikel der Ausgabe 11/2014

Journal of Materials Science 11/2014 Zur Ausgabe

Interfaces and Intergranular Boundaries

Ni–YSZ(111) solid–solid interfacial energy

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.