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Polymer Bulletin
Erschienen in: Polymer Bulletin 6/2020

27.07.2019 | Original Paper

A comparative analysis of the preparation of cellulose acetate butyrate and the characteristics of applying in pearlescent coating film

verfasst von: Aimin Huang, Liping Wei, Zengyan Zhao, Guodong Wei, Yanjuan Zhang, Zuqiang Huang, Xuanhai Li, Huayu Hu, Xingzhen Qin, Mei Yang

Erschienen in: Polymer Bulletin | Ausgabe 6/2020

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Abstract

A simple, green, and efficient mechanical activation-assisted esterification (MAE) technology was developed for the preparation of cellulose acetate butyrate (CAB), which was used as film-former for pearlescent coating. In addition, CAB was also prepared by a traditional liquid phase esterification (LPE) method for comparing the structures and characteristics of the CABs prepared by these two technologies. 1H and 13C NMR confirmed that CAB was successfully produced, and the degree of substitution of acetyl and butyryl groups was also calculated. The crystal structure and molar mass of the CABs prepared by MAE and LPE methods were dissimilar, ascribing to different reaction systems and characteristics. FTIR, SEM, and transparency analyses were used to investigate the chemical structure and surface characteristics of CAB films, and appearance, glossiness, rub resistance, and ethanol resistance measurements were carried out to investigate the surface and wear characteristics of CAB/pearlescent coating films. The results indicated that the surface and wear characteristics of the films based on MAE- and LPE-prepared CABs were similar to the same reaction time, and the interfacial adhesion and compatibility among components significantly affected the characteristics of the films.
Vorheriger Artikel Reaction of “unreactive” silicone: synthesis of long-chain alkyl fluorosilicone via a simple siloxane equilibration process
Nächster Artikel Composites based on high-density polyethylene, polylactide and calcium carbonate: effect of calcium carbonate nanoparticles as co-compatibilizers

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Metadaten
Titel
A comparative analysis of the preparation of cellulose acetate butyrate and the characteristics of applying in pearlescent coating film
verfasst von
Aimin Huang
Liping Wei
Zengyan Zhao
Guodong Wei
Yanjuan Zhang
Zuqiang Huang
Xuanhai Li
Huayu Hu
Xingzhen Qin
Mei Yang
Publikationsdatum
27.07.2019
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 6/2020
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-019-02886-w

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