Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
ATZ-Fachkongress

Chassis.tech plus 2024


4 Kongresse in einer Veranstaltung

Treffen Sie in München die Fachleute von Chassis, Lenkung, Bremsen sowie Reifen/Räder.
Erweiterte Suche
Anmelden
nach oben
Polymer Bulletin
Erschienen in: Polymer Bulletin 6/2020

29.07.2019 | Original Paper

Poly(N-vinylpyrrolidone)-stabilized colloidal graphene-reinforced poly(ethylene-co-methyl acrylate) to mitigate electromagnetic radiation pollution

verfasst von: Sayan Ganguly, Sabyasachi Ghosh, Poushali Das, Tushar Kanti Das, Suman Kumar Ghosh, Narayan Chandra Das

Erschienen in: Polymer Bulletin | Ausgabe 6/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Electrically conducting flexible polymeric nanocomposite has been fabricated through wet mixing method where conducting inclusion was acoustically exfoliated pristine graphene nanosheets. Colloidal graphene is the key component here which has been prepared by acoustic cavitation in the presence of macromolecular dispersion. The significance of the method is their green preparation strategy without using any chemical reducing agents and long self-life without drastic sedimentation rate. Thermoplastic poly(ethylene-co-methyl acrylate) was chosen as flexible phase where graphene sheets were distributed to make spatial conducting network architecture. The prepared nanocomposites showed 0.259 S/cm DC electrical conductivity and frequency-independent electroconducting character in higher concentration. The electromagnetic interference shielding effectiveness of the nanocomposites was around 30 dB in ~ 1.0 mm thickness in X-band (8.2–12.4 GHz) frequency range without affecting its mechanical toughness and flexibility. Thus, such pristine graphene-based thermoplastic matrix could be a desirable replacement of metallic shielding materials on the ground of flexible, conducting, lightweight characteristics.

Graphic abstract

Vorheriger Artikel Influence of vanillin acrylate and 4-acetylphenyl acrylate hydrophobic functional monomers on phase separation of N-isopropylacrylamide environmental terpolymer: fabrication and characterization
Nächster Artikel Wound dressing application of castor oil- and CAPA-based polyurethane membranes

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Chen Z, Xu C, Ma C, Ren W, Cheng HM (2013) Lightweight and flexible graphene foam composites for high-performance electromagnetic interference shielding. Adv Mater 25(9):1296–1300PubMed
2.
Yu M, Liu P, Zhang S, Liu J, An J, Li S (2012) Preparation of graphene–Ag composites and their application for electrochemical detection of chloride. Mater Res Bull 47(11):3206–3210
3.
Ganguly S, Bhawal P, Ravindren R, Das NC (2018) Polymer nanocomposites for electromagnetic interference shielding: a review. J Nanosci Nanotechnol 18(11):7641–7669
4.
Liang J, Wang Y, Huang Y, Ma Y, Liu Z, Cai J, Zhang C, Gao H, Chen Y (2009) Electromagnetic interference shielding of graphene/epoxy composites. Carbon 47(3):922–925
5.
Kim H, Kim K, Lee S, Joo J, Yoon H, Cho S, Lyu S, Lee CJ (2004) Charge transport properties of composites of multiwalled carbon nanotube with metal catalyst and polymer: application to electromagnetic interference shielding. Curr Appl Phys 4(6):577–580
6.
Liu P, Huang Y, Zhang X (2015) Synthesis, characterization and excellent electromagnetic wave absorption properties of graphene@ CoFe2O4@ polyaniline nanocomposites. Synth Met 201:76–81
7.
Wang Y, Huang Y, Ding J (2014) Synthesis and enhanced electromagnetic absorption properties of polypyrrole–BaFe12O19/Ni0.8Zn0.2Fe2O4 on graphene nanosheet. Synth Met 196:125–130
8.
Cao W-Q, Wang X-X, Yuan J, Wang W-Z, Cao M-S (2015) Temperature dependent microwave absorption of ultrathin graphene composites. J Mater Chem C 3(38):10017–10022
9.
Lu M, Wang X, Cao W, Yuan J, Cao M (2015) Carbon nanotube-CdS core–shell nanowires with tunable and high-efficiency microwave absorption at elevated temperature. Nanotechnology 27(6):065702PubMed
10.
Ganguly S, Das NC (2019) Rheological Properties of Polymer-Carbon Composites. Carbon-Containing Polymer Composites. Springer, Singapore, pp 271–294
11.
Ganguly S, Das P, Banerjee S, Das NC (2019) Advancement in science and technology of carbon dot-polymer hybrid composites: a review. Funct Compos Struct 1(2):022001
12.
Das P, Ganguly S, Banerjee S, Das NC (2019) Graphene based emergent nanolights: a short review on the synthesis, properties and application. Res Chem Intermed 45(7):3823–3853
13.
Li P, Du D, Guo L, Guo Y, Ouyang J (2016) Stretchable and conductive polymer films for high-performance electromagnetic interference shielding. J Mater Chem C 4(27):6525–6532
14.
Ganguly S, Das NC (2016) Chlorosulphonated polyethylene and its composites for electronic applications. Flexible and Stretchable Electronic Composites. Springer, Cham, pp 229–259
15.
Ghosh S, Mondal S, Ganguly S, Remanan S, Singha N, Das NC (2018) Carbon nanostructures based mechanically robust conducting cotton fabric for improved electromagnetic interference shielding. Fibers Polym 19(5):1064–1073
16.
Ghosh S, Ganguly S, Remanan S, Mondal S, Jana S, Maji PK, Singha N, Das NC (2018) Ultra-light weight, water durable and flexible highly electrical conductive polyurethane foam for superior electromagnetic interference shielding materials. J Mater Sci: Mater Electron 29:10177–10189
17.
Yuping D, Shunhua L, Hongtao G (2005) Investigation of electrical conductivity and electromagnetic shielding effectiveness of polyaniline composite. Sci Technol Adv Mater 6(5):513–518
18.
Geetha S, Kumar KKS, Trivedi DC (2005) Conducting fabric-reinforced polyaniline film using p-chlorophenol as secondary dopant for the control of electromagnetic radiations. J Compos Mater 39(7):647–658
19.
Niu Y (2006) Preparation of polyaniline/polyacrylate composites and their application for electromagnetic interference shielding. Polym Compos 27(6):627–632
20.
Thomassin J-M, Jérôme C, Pardoen T, Bailly C, Huynen I, Detrembleur C (2013) Polymer/carbon based composites as electromagnetic interference (EMI) shielding materials. Mater Sci Eng R: Rep 74(7):211–232
21.
Kim HK, Kim MS, Chun SY, Park YH, Jeon BS, Lee JY, Hong YK, Joo J, Kim SH (2003) Characteristics of electrically conducting polymer-coated textiles. Mol Cryst Liq Cryst 405(1):161–169
22.
Kim M, Kim H, Byun S, Jeong S, Hong Y, Joo J, Song K, Kim J, Lee C, Lee J (2002) PET fabric/polypyrrole composite with high electrical conductivity for EMI shielding. Synth Met 126(2):233–239
23.
Taka T (1991) EMI shielding measurements on poly (3-octyl thiophene) blends. Synth Met 41(3):1177–1180
24.
Courric S, Tran V (2000) The electromagnetic properties of blends of poly (p-phenylene-vinylene) derivatives. Polym Adv Technol 11(6):273–279
25.
Yang Y, Gupta MC, Dudley KL, Lawrence RW (2005) Novel carbon nanotube-polystyrene foam composites for electromagnetic interference shielding. Nano Lett 5(11):2131–2134PubMed
26.
Saini P, Choudhary V, Singh B, Mathur R, Dhawan S (2009) Polyaniline–MWCNT nanocomposites for microwave absorption and EMI shielding. Mater Chem Phys 113(2):919–926
27.
Huang H-D, Liu C-Y, Zhou D, Jiang X, Zhong G-J, Yan D-X, Li Z-M (2015) Cellulose composite aerogel for highly efficient electromagnetic interference shielding. J Mater Chem A 3(9):4983–4991
28.
Chen YC, Prokleška J, Xu WJ, Liu JL, Liu J, Zhang WX, Tong ML (2015) A brilliant cryogenic magnetic coolant: magnetic and magnetocaloric study of ferromagnetically coupled GdF 3. J Mater Chem C 3(47):12206–12211
29.
Hsiao S-T, Ma C-CM, Tien H-W, Liao W-H, Wang Y-S, Li S-M, Huang Y-C (2013) Using a non-covalent modification to prepare a high electromagnetic interference shielding performance graphene nanosheet/water-borne polyurethane composite. Carbon 60:57–66
30.
Bhawal P, Das TK, Ganguly S, Mondal S, Das NC (2019) Selective cross-linking of carboxylated acrylonitrile butadiene rubber and study of their technological compatibility with poly (ethylene-co-methyl acrlylate) by means of mechanical, thermal, and chemical analysis. Polym Bull 76(4):1877–1897
31.
Bhawal P, Ganguly S, Das TK, Mondal S, Nayak L, Das NC (2019) A comparative study of physico-mechanical and electrical properties of polymer-carbon nanofiber in wet and melt mixing methods. Mater Sci Eng, B 245:95–106
32.
Neto AC, Guinea F, Peres NM, Novoselov KS, Geim AK (2009) The electronic properties of graphene. Rev Mod Phys 81(1):109
33.
CeNeR Rao, AeK Sood, KeS Subrahmanyam, Govindaraj A (2009) Graphene: the new two-dimensional nanomaterial. Angew Chem Int Ed 48(42):7752–7777
34.
Zhou M, Zhai Y, Dong S (2009) Electrochemical sensing and biosensing platform based on chemically reduced graphene oxide. Anal Chem 81(14):5603–5613PubMed
35.
Yan J, Fan Z, Wei T, Qian W, Zhang M, Wei F (2010) Fast and reversible surface redox reaction of graphene–MnO2 composites as supercapacitor electrodes. Carbon 48(13):3825–3833
36.
Verma M, Singh AP, Sambyal P, Singh BP, Dhawan S, Choudhary V (2015) Barium ferrite decorated reduced graphene oxide nanocomposite for effective electromagnetic interference shielding. Phys Chem Chem Phys 17(3):1610–1618PubMed
37.
Liu W, Li H, Zeng Q, Duan H, Guo Y, Liu X, Sun C, Liu H (2015) Fabrication of ultralight three-dimensional graphene networks with strong electromagnetic wave absorption properties. J Mater Chem A 3(7):3739–3747
38.
Gupta TK, Singh BP, Singh VN, Teotia S, Singh AP, Elizabeth I, Dhakate SR, Dhawan S, Mathur R (2014) MnO2 decorated graphene nanoribbons with superior permittivity and excellent microwave shielding properties. J Mater Chem A 2(12):4256–4263
39.
Arjmand M, Moud AA, Li Y, Sundararaj U (2015) Outstanding electromagnetic interference shielding of silver nanowires: comparison with carbon nanotubes. RSC Adv 5(70):56590–56598
40.
Yu Y-H, Ma C-CM, Teng C-C, Huang Y-L, Lee S-H, Wang I, Wei M-H (2012) Electrical, morphological, and electromagnetic interference shielding properties of silver nanowires and nanoparticles conductive composites. Mater Chem Phys 136(2):334–340
41.
Yang Y, Gupta M, Dudley K (2007) Studies on electromagnetic interference shielding characteristics of metal nanoparticle-and carbon nanostructure-filled polymer composites in the Ku-band frequency. IET Micro Nano Lett 2(4):85–89
42.
Aji M, Bijaksana S, Abdullah M (2012) Electrical and magnetic properties of polymer electrolyte (PVA: LiOH) containing in situ dispersed Fe3O4 nanoparticles. ISRN Mater Sci 2012:1–7
43.
Guo Z, Zhang D, Wei S, Wang Z, Karki AB, Li Y, Bernazzani P, Young DP, Gomes J, Cocke DL (2010) Effects of iron oxide nanoparticles on polyvinyl alcohol: interfacial layer and bulk nanocomposites thin film. J Nanopart Res 12(7):2415–2426
44.
Das TK, Bhawal P, Ganguly S, Mondal S, Das NC (2018) A facile green synthesis of amino acid boosted Ag decorated reduced graphene oxide nanocomposites and its catalytic activity towards 4-nitrophenol reduction. Surf Interfaces 13:79–91
45.
Ashori A, Ghiyasi M, Fallah A (2019) Glass fiber-reinforced epoxy composite with surface-modified graphene oxide: enhancement of interlaminar fracture toughness and thermo-mechanical performance. Polym Bull 76(1):259–270
46.
Moniruzzaman M, Winey KI (2006) Polymer nanocomposites containing carbon nanotubes. Macromolecules 39(16):5194–5205
47.
Bourlinos AB, Georgakilas V, Zboril R, Steriotis TA, Stubos AK, Trapalis C (2009) Aqueous-phase exfoliation of graphite in the presence of polyvinylpyrrolidone for the production of water-soluble graphenes. Solid State Commun 149(47):2172–2176
48.
Wei W, Lu W, Yang Q-h (2011) High-concentration graphene aqueous suspension and a membrane self-assembled at the liquid–air interface. Carbon 49(8):2879
49.
Sun Z, Nicolosi V, Rickard D, Bergin SD, Aherne D, Coleman JN (2008) Quantitative evaluation of surfactant-stabilized single-walled carbon nanotubes: dispersion quality and its correlation with zeta potential. J Phys Chem C 112(29):10692–10699
50.
Wajid AS, Das S, Irin F, Ahmed HT, Shelburne JL, Parviz D, Fullerton RJ, Jankowski AF, Hedden RC, Green MJ (2012) Polymer-stabilized graphene dispersions at high concentrations in organic solvents for composite production. Carbon 50(2):526–534
51.
Bhawal P, Ganguly S, Chaki T, Das N (2016) Synthesis and characterization of graphene oxide filled ethylene methyl acrylate hybrid nanocomposites. RSC Adv 6(25):20781–20790
52.
Behabtu N, Lomeda JR, Green MJ, Higginbotham AL, Sinitskii A, Kosynkin DV, Tsentalovich D, Parra-Vasquez ANG, Schmidt J, Kesselman E, Cohen Y, Talmon Y, Tour JM, Pasquali M (2010) Spontaneous high-concentration dispersions and liquid crystals of graphene. Nat Nano 5:406–411
53.
Ferrari A, Meyer J, Scardaci V, Casiraghi C, Lazzeri M, Mauri F, Piscanec S, Jiang D, Novoselov K, Roth S (2006) Raman spectrum of graphene and graphene layers. Phys Rev Lett 97(18):187401PubMed
54.
Ganguly S, Mondal S, Das P, Bhawal P, Das TK, Ghosh S, Remanan S, Das NC (2018) An insight into the physico-mechanical signatures of silylated graphene oxide in poly (ethylene methyl acrylate) copolymeric thermoplastic matrix. Macromol Res 27(3):268–281
55.
Simon RM (1981) EMI shielding through conductive plastics. Polym Plast Technol Eng 17(1):1–10
56.
Ganguly S, Das P, Maity PP, Mondal S, Ghosh S, Dhara S, Das NC (2018) Green reduced graphene oxide toughened semi-IPN monolith hydrogel as dual responsive drug release system: rheological, physicomechanical, and electrical evaluations. J Phys Chem B 122(29):7201–7218PubMed
57.
Polley M, Boonstra B (1957) Carbon blacks for highly conductive rubber. Rubber Chem Technol 30(1):170–179
58.
Das TK, Bhawal P, Ganguly S, Mondal S, Remanan S, Ghosh S, Das NC (2018) Synthesis of hydroxyapatite nanorods and its use as a nanoreinforcement block for ethylene methacrylate copolymer matrix. Polym Bull 76(7):3621–3642
59.
Ryvkina N, Tchmutin I, Vilčáková J, Pelíšková M, Sáha P (2005) The deformation behavior of conductivity in composites where charge carrier transport is by tunneling: theoretical modeling and experimental results. Synth Met 148(2):141–146
60.
Ghosh S, Ganguly S, Remanan S, Das NC (2019) Fabrication and investigation of 3D tuned PEG/PEDOT: PSS treated conductive and durable cotton fabric for superior electrical conductivity and flexible electromagnetic interference shielding. Compos Sci Technol 181:107682
61.
Ghosh S, Ganguly S, Das P, Das TK, Bose M, Singha NK, Das AK, Das NC (2019) Fabrication of reduced graphene oxide/silver nanoparticles decorated conductive cotton fabric for high performing electromagnetic interference shielding and antibacterial application. Fibers Polym 20(6):1161–1171
62.
Yang Y, Gupta MC, Dudley KL (2007) Towards cost-efficient EMI shielding materials using carbon nanostructure-based nanocomposites. Nanotechnology 18(34):345701
63.
Afanasov I, Morozov V, Kepman A, Ionov S, Seleznev A, Van Tendeloo G, Avdeev V (2009) Preparation, electrical and thermal properties of new exfoliated graphite-based composites. Carbon 47(1):263–270
64.
Goyal R (2013) Cost-efficient high performance polyetheretherketone/expanded graphite nanocomposites with high conductivity for EMI shielding application. Mater Chem Phys 142(1):195–198
65.
Al-Saleh MH (2016) Electrical and electromagnetic interference shielding characteristics of GNP/UHMWPE composites. J Phys D Appl Phys 49(19):195302
66.
Nimbalkar P, Korde A, Goyal R (2018) Electromagnetic interference shielding of polycarbonate/GNP nanocomposites in X-band. Mater Chem Phys 206:251–258
67.
Bansala T, Joshi M, Mukhopadhyay S, Doong R-a, Chaudhary M (2017) Electrically conducting graphene-based polyurethane nanocomposites for microwave shielding applications in the Ku band. J Mater Sci 52(3):1546–1560
Metadaten
Titel
Poly(N-vinylpyrrolidone)-stabilized colloidal graphene-reinforced poly(ethylene-co-methyl acrylate) to mitigate electromagnetic radiation pollution
verfasst von
Sayan Ganguly
Sabyasachi Ghosh
Poushali Das
Tushar Kanti Das
Suman Kumar Ghosh
Narayan Chandra Das
Publikationsdatum
29.07.2019
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 6/2020
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-019-02892-y

Weitere Artikel der Ausgabe 6/2020

Polymer Bulletin 6/2020 Zur Ausgabe

Original Paper

Influence of vanillin acrylate and 4-acetylphenyl acrylate hydrophobic functional monomers on phase separation of N-isopropylacrylamide environmental terpolymer: fabrication and characterization

Original Paper

Electrosynthesized conducting poly(1,5-diaminonaphthalene) as a corrosion inhibitor for copper

Original Paper

Preparation and characterization of polymethyl methacrylate light-scattering material

Original Paper

A comparative analysis of the preparation of cellulose acetate butyrate and the characteristics of applying in pearlescent coating film

Original Paper

Multicomponent polyurethane–carbon black composite as piezoresistive sensor

Original Paper

Curing characteristics and cellular morphology of natural rubber/silica composite foams

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise