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Erschienen in: Mechanics of Composite Materials 5/2014

01.11.2014

A Study on the Structure and Adhesive Properties of Epoxy-Silicate Composites

verfasst von: T. V. Brantseva, S. O. Ilyin, I. Yu. Gorbunova, S. V. Antonov, M. L. Kerber

Erschienen in: Mechanics of Composite Materials | Ausgabe 5/2014

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Abstract

Compositions based on an ED-20 resin with three types of modifiers: natural montmorillonite (MMT) Cloisite Na +, organomodified MMT Cloisite 30B, and halloysite, were investigated. An optimum regime was chosen for preparation of the epoxy/modifier systems by employing the ultrasonic mixing. The rheological characteristics of suspensions were used to estimate the distribution of modifier in the epoxy oligomer. According to rheological data, the best dispersion of MMT in the epoxy oligomer after ultrasonic stirring was observed for the organomodified MMT Cloisite 30B. The maximum shear adhesion strength was also observed for the epoxy resin+Cloisite 30B systems. For the systems with 2 wt. % of Cloisite 30B, the increase in the adhesion strength was up to 65% as compared with that of the pristine epoxy oligomer.

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Literatur
1.
Zurück zum Zitat W. G. Potter, Epoxide Resins, Springer, New York (1970). W. G. Potter, Epoxide Resins, Springer, New York (1970).
2.
Zurück zum Zitat A. J. Kinloch, S. J. Shaw, et al., “Deformation and fracture behavior of a rubber-toughened epoxy: microstructure and fracture studies,” Polymer, 24, Iss. 10, 1341–1354 (1983).CrossRef A. J. Kinloch, S. J. Shaw, et al., “Deformation and fracture behavior of a rubber-toughened epoxy: microstructure and fracture studies,” Polymer, 24, Iss. 10, 1341–1354 (1983).CrossRef
3.
Zurück zum Zitat T. V. Brantseva, Yu. A. Gorbatkina, V. Dutschk, K. Schneider, and R. Häßler, “Modification of epoxy resin by polysulfone to improve the interfacial and mechanical properties in glass fibre composites. III. Properties of the cured blends and their structures in the polymer/fibre interphase,” J. Adhes. Sci. Technol., 18, Iss. 11, 1309–1323 (2004).CrossRef T. V. Brantseva, Yu. A. Gorbatkina, V. Dutschk, K. Schneider, and R. Häßler, “Modification of epoxy resin by polysulfone to improve the interfacial and mechanical properties in glass fibre composites. III. Properties of the cured blends and their structures in the polymer/fibre interphase,” J. Adhes. Sci. Technol., 18, Iss. 11, 1309–1323 (2004).CrossRef
4.
Zurück zum Zitat M. C. Richardson, J. Kim, D. Ho, C. R. Snyder, G. A. Holmes, and N. A. D’Souza, “Organofunctionalized montmorillonite/epoxy nanocomposites: the effect of interlayer distribution on mechanical properties,” Polym. Compos., 32, Iss. 1, 67–78 (2011).CrossRef M. C. Richardson, J. Kim, D. Ho, C. R. Snyder, G. A. Holmes, and N. A. D’Souza, “Organofunctionalized montmorillonite/epoxy nanocomposites: the effect of interlayer distribution on mechanical properties,” Polym. Compos., 32, Iss. 1, 67–78 (2011).CrossRef
5.
Zurück zum Zitat M. S. Lakshmi, B. Narmadha, and B. S. R. Reddy, “Enhanced thermal stability and structural characteristics of different MMT-Clay/epoxy-nanocomposite material,” Polym. Degrad. Stabil., 93, Iss. 1, 201–213 (2008).CrossRef M. S. Lakshmi, B. Narmadha, and B. S. R. Reddy, “Enhanced thermal stability and structural characteristics of different MMT-Clay/epoxy-nanocomposite material,” Polym. Degrad. Stabil., 93, Iss. 1, 201–213 (2008).CrossRef
6.
Zurück zum Zitat J. Jiao, X. Sun, and Th. J. Pinnavaia, “Mesostructured silica for the reinforcement and toughening of rubbery and glassy epoxy polymers,” Polymer, 50, Iss. 4, 983–989 (2009).CrossRef J. Jiao, X. Sun, and Th. J. Pinnavaia, “Mesostructured silica for the reinforcement and toughening of rubbery and glassy epoxy polymers,” Polymer, 50, Iss. 4, 983–989 (2009).CrossRef
7.
Zurück zum Zitat J. Zhu, J. D. Kim, J. L. Margrave, V. N. Khabashesku, and E. V. Barrera, “Improving the dispersion and integration of single-walled carbon nanotubes in epoxy composites through functionalization,” Nano Let., 3, Iss. 8, 1107–1113 (2003).CrossRef J. Zhu, J. D. Kim, J. L. Margrave, V. N. Khabashesku, and E. V. Barrera, “Improving the dispersion and integration of single-walled carbon nanotubes in epoxy composites through functionalization,” Nano Let., 3, Iss. 8, 1107–1113 (2003).CrossRef
8.
Zurück zum Zitat Sh. Deng, J. Zhang, L. Ye, and J. Wu, “Toughening epoxies with halloysite nanotubes,” Polymer, 49, Iss. 23, 5119–5127 (2008).CrossRef Sh. Deng, J. Zhang, L. Ye, and J. Wu, “Toughening epoxies with halloysite nanotubes,” Polymer, 49, Iss. 23, 5119–5127 (2008).CrossRef
9.
Zurück zum Zitat Y. Xu and S. V. Hoa, “Mechanical properties of carbon fiber reinforced epoxy/clay nanocomposites,” Compos. Sci. Technol., 68, Iss. 3–4, 854–861 (2008).CrossRef Y. Xu and S. V. Hoa, “Mechanical properties of carbon fiber reinforced epoxy/clay nanocomposites,” Compos. Sci. Technol., 68, Iss. 3–4, 854–861 (2008).CrossRef
10.
Zurück zum Zitat O. V. Akhmatova, Yu. A. Gorbatkina, I. Yu. Gorbunova, V. G. Ivanova-Mumzhieva, and M. L. Kerber, “Effect of nanoclay particles and thermoplastic modifier on adhesion of epoxy-amine binder and fiber,” Plastmassy, Iss.10, 31–35 (2012). O. V. Akhmatova, Yu. A. Gorbatkina, I. Yu. Gorbunova, V. G. Ivanova-Mumzhieva, and M. L. Kerber, “Effect of nanoclay particles and thermoplastic modifier on adhesion of epoxy-amine binder and fiber,” Plastmassy, Iss.10, 31–35 (2012).
11.
Zurück zum Zitat V. E. Yudin, J. U. Otaigbe, S. I. Nazarenko, W. D. Kim, and E. N. Korytkova, “A comparative study on the mechanical and barrier characteristics of polyimide nanocomposite films filled with nanoparticles of planar and tubular morphology,” Mech. Compos. Mater., 47, Iss. 3, 335–342 (2011).CrossRef V. E. Yudin, J. U. Otaigbe, S. I. Nazarenko, W. D. Kim, and E. N. Korytkova, “A comparative study on the mechanical and barrier characteristics of polyimide nanocomposite films filled with nanoparticles of planar and tubular morphology,” Mech. Compos. Mater., 47, Iss. 3, 335–342 (2011).CrossRef
12.
Zurück zum Zitat P. N. B. Reis, A. P. Silva, P. Santos, and J. A. M. Ferreira, “Hygrothermal effect on the impact response of carbon composites with epoxy resin enhanced by nanoclays,” Mech. Compos. Mater., 49, Iss. 4, 429–436 (2013).CrossRef P. N. B. Reis, A. P. Silva, P. Santos, and J. A. M. Ferreira, “Hygrothermal effect on the impact response of carbon composites with epoxy resin enhanced by nanoclays,” Mech. Compos. Mater., 49, Iss. 4, 429–436 (2013).CrossRef
13.
Zurück zum Zitat Sh.-Y. Gu, J. Ren, and Q.-F. Wang, “Rheology of poly(propelene)/clay nanocomposites,” J. Appl. Polym. Sci., 91, 2427–2434 (2004).CrossRef Sh.-Y. Gu, J. Ren, and Q.-F. Wang, “Rheology of poly(propelene)/clay nanocomposites,” J. Appl. Polym. Sci., 91, 2427–2434 (2004).CrossRef
14.
Zurück zum Zitat X. He, J. Yang, L. Zhu, B. Wang, G. Sun, P. Lv, I. Y. Phang, and T. Liu, “Morphology and melt rheology of nylon11/clay nanocomposites,” J. Appl. Polym. Sci., 102, 542–549 (2006).CrossRef X. He, J. Yang, L. Zhu, B. Wang, G. Sun, P. Lv, I. Y. Phang, and T. Liu, “Morphology and melt rheology of nylon11/clay nanocomposites,” J. Appl. Polym. Sci., 102, 542–549 (2006).CrossRef
15.
Zurück zum Zitat H. J. Choi, S. G. Kim, Y. H. Hyun, and M. S. Jhon, “Preparation and rheological characteristics of solvent-cast poly(ethylene oxide)/montmorillonite nanocomposites,” Macromol. Rapid Commun., 22, Iss. 5, 320–325 (2001).CrossRef H. J. Choi, S. G. Kim, Y. H. Hyun, and M. S. Jhon, “Preparation and rheological characteristics of solvent-cast poly(ethylene oxide)/montmorillonite nanocomposites,” Macromol. Rapid Commun., 22, Iss. 5, 320–325 (2001).CrossRef
16.
Zurück zum Zitat I. Rhoney, S. Brown, N. E. Hudson, and R. A. Pethrick, “Influence of processing method on the exfoliation process of organically modified clay systems. I. Polyurethanes,” J. Appl. Polym. Sci., 91, 1335–1343 (2004).CrossRef I. Rhoney, S. Brown, N. E. Hudson, and R. A. Pethrick, “Influence of processing method on the exfoliation process of organically modified clay systems. I. Polyurethanes,” J. Appl. Polym. Sci., 91, 1335–1343 (2004).CrossRef
17.
Zurück zum Zitat S. McIntyre, I. Kaltazhakorta, J. J. Liggat, R. A. Pethrick, and I. Rhoney, “Influence of the epoxy structure on the physical properties of epoxy resin nanocomposites,” Ind. Eng. Chem. Res., 44, 8573–8579 (2005).CrossRef S. McIntyre, I. Kaltazhakorta, J. J. Liggat, R. A. Pethrick, and I. Rhoney, “Influence of the epoxy structure on the physical properties of epoxy resin nanocomposites,” Ind. Eng. Chem. Res., 44, 8573–8579 (2005).CrossRef
18.
Zurück zum Zitat Gh. Sodeifian, H. R. Nikooamal, and A. A. Yusefi, “Molecular dynamics study of epoxy/clay nanocomposites: rheology and molecular confinement,” J. Polym. Res., 19, 9897–9908 (2012).CrossRef Gh. Sodeifian, H. R. Nikooamal, and A. A. Yusefi, “Molecular dynamics study of epoxy/clay nanocomposites: rheology and molecular confinement,” J. Polym. Res., 19, 9897–9908 (2012).CrossRef
19.
Zurück zum Zitat Gh. Sodeifian, H. R. Nikooamal, and A. A. Yusefi, “Effect of mixing condition on rheological behavior of epoxy-clay nanocomposites,” Iran J. Polym. Sci. Technol., 25, Iss. 3, 241–250 (2012). Gh. Sodeifian, H. R. Nikooamal, and A. A. Yusefi, “Effect of mixing condition on rheological behavior of epoxy-clay nanocomposites,” Iran J. Polym. Sci. Technol., 25, Iss. 3, 241–250 (2012).
20.
Zurück zum Zitat S. O. Il’in, I. Yu. Gorbunova, E. P. Plotnikova, and M. L. Kerber, “Rheological and mechanical properties of epoxy composites modified with montmorillonite nanoparticles,” Int. Polym. Sci. Technol., 39, Iss. 7, 57–61 (2012). S. O. Il’in, I. Yu. Gorbunova, E. P. Plotnikova, and M. L. Kerber, “Rheological and mechanical properties of epoxy composites modified with montmorillonite nanoparticles,” Int. Polym. Sci. Technol., 39, Iss. 7, 57–61 (2012).
21.
Zurück zum Zitat S.-A. Gârea, H. Iovu, and A. Bulearca, “New organophilic agents of montmorillonite used as reinforcing agent in epoxy nanocomposites,” Polymer Testing, 27, 100–113 (2008).CrossRef S.-A. Gârea, H. Iovu, and A. Bulearca, “New organophilic agents of montmorillonite used as reinforcing agent in epoxy nanocomposites,” Polymer Testing, 27, 100–113 (2008).CrossRef
22.
Zurück zum Zitat W. S. Wang, H. S. Chen, Y. W. Wu, T. Y. Tsai, and Y. W. Tseng-Yang, “Properties of novel epoxy/clay nanocomposites prepared with a reactive phosphorus-containing organoclay,” Polymer, 49, 4826–4836 (2008).CrossRef W. S. Wang, H. S. Chen, Y. W. Wu, T. Y. Tsai, and Y. W. Tseng-Yang, “Properties of novel epoxy/clay nanocomposites prepared with a reactive phosphorus-containing organoclay,” Polymer, 49, 4826–4836 (2008).CrossRef
23.
Zurück zum Zitat E. Franchini, G. Galy, and J.-F. Gerard, “Sepiolite-based epoxy nanocomposites: Relation between processing, rheology and morphology,” J. Colloid Interface Sci., 329, 38–47 (2009).CrossRef E. Franchini, G. Galy, and J.-F. Gerard, “Sepiolite-based epoxy nanocomposites: Relation between processing, rheology and morphology,” J. Colloid Interface Sci., 329, 38–47 (2009).CrossRef
24.
Zurück zum Zitat Q. H. Zheng, A. B. Yu, G. Q. Lu, and D. R. Paul, “Clay-based polymer nanocomposites: research and commercial development,” J. Nanosci. Nanotechnol., 5, 1574–1592 (2005).CrossRef Q. H. Zheng, A. B. Yu, G. Q. Lu, and D. R. Paul, “Clay-based polymer nanocomposites: research and commercial development,” J. Nanosci. Nanotechnol., 5, 1574–1592 (2005).CrossRef
25.
Zurück zum Zitat K. Owusu-Adom and C. A. Guymon, “Chemical compatibility and reaction-induced exfoliation in photopolymerizable clay nanocomposites,” Macromolecules, 42, 180–187 (2009).CrossRef K. Owusu-Adom and C. A. Guymon, “Chemical compatibility and reaction-induced exfoliation in photopolymerizable clay nanocomposites,” Macromolecules, 42, 180–187 (2009).CrossRef
26.
Zurück zum Zitat J. S. Smith, D. Bedrov, and G. D. Smith, “A molecular dynamics simulation study of nanoparticles interactions in a model polymer-nanoparticle composite,” Compos. Sci. Technol., 63, 1599–1605 (2003).CrossRef J. S. Smith, D. Bedrov, and G. D. Smith, “A molecular dynamics simulation study of nanoparticles interactions in a model polymer-nanoparticle composite,” Compos. Sci. Technol., 63, 1599–1605 (2003).CrossRef
27.
Zurück zum Zitat S. Pavlidou and C. D. Papaspyrides, “A review on polymer-layered silicate nanocomposites,” Progress Polym. Sci., 33, 1119–1198 (2008).CrossRef S. Pavlidou and C. D. Papaspyrides, “A review on polymer-layered silicate nanocomposites,” Progress Polym. Sci., 33, 1119–1198 (2008).CrossRef
28.
Zurück zum Zitat Y. Ye, H. Chen, J. Wu, and L. Ye, “High impact strength epoxy nanocomposites with natural nanotubes,” Polymer, 48, 6426–6433 (2007).CrossRef Y. Ye, H. Chen, J. Wu, and L. Ye, “High impact strength epoxy nanocomposites with natural nanotubes,” Polymer, 48, 6426–6433 (2007).CrossRef
Metadaten
Titel
A Study on the Structure and Adhesive Properties of Epoxy-Silicate Composites
verfasst von
T. V. Brantseva
S. O. Ilyin
I. Yu. Gorbunova
S. V. Antonov
M. L. Kerber
Publikationsdatum
01.11.2014
Verlag
Springer US
Erschienen in
Mechanics of Composite Materials / Ausgabe 5/2014
Print ISSN: 0191-5665
Elektronische ISSN: 1573-8922
DOI
https://doi.org/10.1007/s11029-014-9453-8

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