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Erschienen in: Adsorption 1-2/2015

01.02.2015

Adsorption removal of arsine by modified activated carbon

verfasst von: Ming Jiang, Yangwei Bai, Ping Ning, Xiaofeng Huang, Hongpan Liu, Jianqiu Fu

Erschienen in: Adsorption | Ausgabe 1-2/2015

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Abstract

The modified activated carbon adsorbents were prepared by impregnation method for removal of arsine (AsH3). The results show that the activated carbons modified with sulfonated cobalt phthalocyanine (CoPcS) and Cu(NO3)2 (denoted as Co/Cu) is found to have significantly enhanced adsorption removal ability. The effects of CoPcS content, calcination temperature, O2 content and pore structure on the AsH3 adsorption are investigated. The optimum conditions for removal of AsH3 are 0.02 wt% of CoPcS content, 400 °C of calcination temperature and 4 vol% of O2 content, respectively. The regions of micropores (14.7 Å < pore width < 20 Å) and mesopores (20 Å < pore width < 43.4 Å) play the predominant role for adsorbing AsH3. The regeneration efficiency of deactivated Co/Cu/AC adsorbent is up to 71.2 %.

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Metadaten
Titel
Adsorption removal of arsine by modified activated carbon
verfasst von
Ming Jiang
Yangwei Bai
Ping Ning
Xiaofeng Huang
Hongpan Liu
Jianqiu Fu
Publikationsdatum
01.02.2015
Verlag
Springer US
Erschienen in
Adsorption / Ausgabe 1-2/2015
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI
https://doi.org/10.1007/s10450-015-9656-x

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