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Biomass Conversion and Biorefinery

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13.06.2022 | Original Article

Aromatic sulfonic acid-catalyzed conversion of safflower stalk into levulinic acid

verfasst von: Doğan Emre Yüksel, Levent Ballice, Nihal Cengiz, Mehmet Sağlam, Mithat Yüksel

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 1/2024

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Abstract

Safflower stalk is a suitable lignocellulosic biomass that can replace fossil resources for the production of platform chemicals. In this study, the production of levulinic acid (LA) from safflower stalk using aromatic sulfonic acids as environmentally friendly catalysts was investigated. A Taguchi experimental design was used to determine the conditions for the highest product yield. The variations of valuable by-products such as 5-HMF, formic acid, and acetic acid, which may occur depending on the reaction conditions were also analyzed. Optimum conditions for maximum LA yield were found using para-toluenesulfonic acid (PTSA) with concentration of 0.3 M, solvent/biomass ratio as 20 at a temperature of 200 °C. Experiments were also carried out to verify the optimum LA yield found using analysis of variance (ANOVA). Comparison experiments were performed with sulfuric acid (H₂SO₄) under optimum conditions, and it was concluded that PTSA could be an alternative catalyst to H₂SO₄ in terms of LA yield.

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Vorheriger Artikel Multifunctional B, N, P, and S-doped fluorescent carbon quantum dot synthesis from pigeon manure: highly effective Hg (II) sensor and fluorescent ink properties

Nächster Artikel Fungal-integrated second-generation lignocellulosic biorefinery: utilization of agricultural biomass for co-production of lignocellulolytic enzymes, mushroom, fungal polysaccharides, and bioethanol

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Titel: Aromatic sulfonic acid-catalyzed conversion of safflower stalk into levulinic acid
verfasst von: Doğan Emre Yüksel
Levent Ballice
Nihal Cengiz
Mehmet Sağlam
Mithat Yüksel
Publikationsdatum: 13.06.2022
Verlag: Springer Berlin Heidelberg
Erschienen in: Biomass Conversion and Biorefinery / Ausgabe 1/2024
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI: https://doi.org/10.1007/s13399-022-02920-4

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Abstract

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