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Polymer Bulletin

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18.04.2017 | Original Paper

Bio-based poly(pentamethylene oxamide) synthesized by spray/solid-state polycondensation

verfasst von: Cong Cheng, Fredrick Nzioka Mutua, Yusheng Dong, Bo Zhu, Yong He

Erschienen in: Polymer Bulletin | Ausgabe 1/2018

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Abstract

In this study, an attempt was made to prepare bio-based poly(pentamethylene oxamide) (PA52) using a novel process of spray/solid-state polycondensation. A prepolymer of relative viscosity of 1.3 was prepared by spray polycondensation, where the monomers (dibutyl oxalate and 1,5-pentanediamine) were separately injected into the nozzle, atomized simultaneously under nitrogen flow, mixed, and polymerized at room temperature. After solid-state polycondensation, PA52 with relative viscosity of 3.2, weight-average molecular weight of 4.3 × 10⁴, and melting point of 301 °C was obtained. FTIR and ¹H-NMR analysis confirmed the formation of PA52 while the DSC results suggested that the resultant polymer possessed high heat resistance and good crystallizability.

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Titel: Bio-based poly(pentamethylene oxamide) synthesized by spray/solid-state polycondensation
verfasst von: Cong Cheng
Fredrick Nzioka Mutua
Yusheng Dong
Bo Zhu
Yong He
Publikationsdatum: 18.04.2017
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 1/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-017-2023-1

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