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25.03.2024 | Original Paper

Biodiesel Synthesis Using Magnetizable Geopolymer as Heterogeneous Catalysts Nanocomposite Assisted by Artificial Intelligence

verfasst von: Daniele Silvéria Brandão, Fernando Gomes de Souza Jr, Fabíola da Silveira Maranhão, Kaushik Pal, Michelle Colão de Paula Pereira, Andreina Catarina Torres, Gabriel Bezerra Silva, Thiago do Nascimento Peçanha, Sophia Elizabeth Cesar e Silva, Jean Carlos Carelo, Antonieta Middea

Erschienen in: Topics in Catalysis | Ausgabe 9-12/2024

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Abstract

Biodiesel stands out as a promising contender in the quest for renewable energy solutions, offering a greener alternative to traditional fossil fuels. Derived primarily from the transesterification of vegetable oils or animal fats, biodiesel offers an eco-friendly energy avenue with a minimized carbon footprint. Catalysts are central to the success of this process, which significantly enhance yield rates. Geopolymers, traditionally associated with construction applications due to their inorganic nature, have been derived from aluminosilicate sources activated using alkaline solutions. However, recent advancements spotlight geopolymers in a new light, emphasizing their prospective role as nanocatalytic agents for biodiesel synthesis. This paradigm shift suggests improved production efficiency and an innovative method of repurposing industrial waste. This study centers on the pioneering application of geopolymers, fortified with magnetite, as potent heterogeneous catalysts for biodiesel generation from soybean and safflower oils. By leveraging a meticulously crafted geopolymer matrix—consisting of metakaolin, sodium hydroxide, and magnetite—this research replaced traditional catalysts with this advanced nanostructured geopolymer variant in the biodiesel methylation process. The research delved deep to ascertain the prime synthesis conditions. Furthermore, utilizing cutting-edge machine learning methodologies provided an analytical lens to navigate the extensive experimental data, thereby fine-tuning the optimization trajectory. One of the salient takeaways from this research is the validation that geopolymer catalysts, rooted in kaolinite, can be ingeniously tailored to ensure elevated biodiesel yields across a spectrum of oil sources, underscoring their unparalleled efficiency and versatility in the biofuel domain.

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Titel: Biodiesel Synthesis Using Magnetizable Geopolymer as Heterogeneous Catalysts Nanocomposite Assisted by Artificial Intelligence
verfasst von: Daniele Silvéria Brandão
Fernando Gomes de Souza Jr
Fabíola da Silveira Maranhão
Kaushik Pal
Michelle Colão de Paula Pereira
Andreina Catarina Torres
Gabriel Bezerra Silva
Thiago do Nascimento Peçanha
Sophia Elizabeth Cesar e Silva
Jean Carlos Carelo
Antonieta Middea
Publikationsdatum: 25.03.2024
Verlag: Springer US
Erschienen in: Topics in Catalysis / Ausgabe 9-12/2024
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-024-01929-5

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