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Cellulose

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01.04.2015 | Original Paper

Cellulose diacetate films as a solid-phase matrix for fluorescence analysis of pyrene traces in aqueous media

verfasst von: Anna B. Shipovskaya, Tamara I. Gubina, Anna V. Strashko, Olga N. Malinkina

Erschienen in: Cellulose | Ausgabe 2/2015

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Abstract

We report on the possibility of using cellulose diacetate (CDA) films as a solid-phase matrix for the fluorescence analysis of pyrene in aqueous micellar media. We examined the effect of the concentration of three surfactants—the anionic sodium dodecyl sulfate (SDS), the cationic cetyltrimethylammonium bromide (CTAB), and the nonionic polyoxyethylene (10) mono-4-isooctylphenyl ether (TX-100)—on the fluorescence of pyrene in aqueous micellar solutions before and after sorptional concentration and as adsorbed on CDA films. The increased fluorescence intensity of pyrene on the solid-phase matrix was due to pyrene solubilization in the surfactant hemimicelles formed on the sorbent surface. The highest degree of pyrene recovery on CDA was achieved in the presence of micelles of the cationic CTAB. The surface electric potential of the CDA films was negative (−31.5 ± 2.5 mV), affecting the hydrocarbon recovery degree. The recovery degree and the polarity index of the pyrene molecules’ microenvironment in solution decreased in the sequence CTAB > SDS > TX-100.

Vorheriger Artikel Fibrous cellulose membrane mass produced via forcespinning® for lithium-ion battery separators

Nächster Artikel Structure and properties of novel cellulose-based fibers spun from aqueous NaOH solvent under various drawing conditions

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Titel: Cellulose diacetate films as a solid-phase matrix for fluorescence analysis of pyrene traces in aqueous media
verfasst von: Anna B. Shipovskaya
Tamara I. Gubina
Anna V. Strashko
Olga N. Malinkina
Publikationsdatum: 01.04.2015
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 2/2015
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-015-0572-8

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