nach oben

Arabian Journal for Science and Engineering

Erschienen in:

15.06.2023 | Research Article-Physics

Chitosan/In situ Gelatin-Mg₃Si₂O₅(OH)₄ Nanocomposites via Sol–Gel Method: Preparation, Characterization and Antimicrobial Properties

verfasst von: A. M. Mansour, Ali B. Abou Hammad, Alaa Omar Balkhtb, Thoraya Maamoun Elhelali, Amel Mohamed Abouelnaga, Amany M. El Nahrawy

Erschienen in: Arabian Journal for Science and Engineering | Ausgabe 1/2024

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The qualities of a composite may be enhanced by the addition of several components, including nanoparticles. Different moieties can interact with one another through strong covalent bonds as well as weak physical interactions such as hydrogen bonds, Van der Waals contacts, hydrophobic interactions, and electrostatic interactions. Chitosan/in situ gelatin-magnesium silicate nanocomposites were prepared by the sol–gel method. The composition and structure of the nanocomposites were studied by FTIR and XRD techniques. The morphology is obtained by FE-SEM. The optical diffuse reflectance (R_d) was employed to study the absorbance behavior of the nanocomposite and extract their energy gap, refractive indices, optical dielectric, and optical electronegativity. Scanning electron microscope images reveal that a large portion of the sample surface was occupied by regularly distributed caves over the gelatin-MgO/chitosan construct, which occurred because of the dense aggregated polymeric clusters. The antimicrobial effectiveness of the nanocomposites exhibited remarkable enhancement in the antimicrobial activities that candidate it for bio-applications. The biocomposites exhibit a developed antibacterial activity which increased with increasing chitosan content and cross-linking density.

Vorheriger Artikel Nonlinear Electrostatic Excitations in Magnetized Plasma with Mono-Energetic Electron Beam

Nächster Artikel Evaluation of Interaction Properties of Some Ionizing Radiation with Selected Nitrogen-Based Explosives

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

El Nahrawy, A.M.; Montaser, A.S.; Bakr, A.M.; Abou Hammad, A.B.; Mansour, A.M.: Impact of ZnO on the spectroscopic, mechanical and UPF properties of Fe₂O₃-tough polystyrene-based nanocomposites. J. Mater. Sci. Mater. Electron. 32, 28019–28031 (2021). https://doi.org/10.1007/s10854-021-07182-wCrossRef

Nahrawy, A.M.E.; Bakr, A.M.; Hammad, A.B.A.; Mansour, A.M.: Nano-architecture of CaO/Ag-chitosan nanocomposite by sol gel process: formation and characterization. Egypt. J. Chem. 64, 7293–7306 (2021). https://doi.org/10.21608/EJCHEM.2021.80608.3995CrossRef

El Nahrawy, A.M.; Montaser, A.S.; Abou Hammad, A.B.; Ezzat, M.; El-shakankery, M.: Copper lithium silicate/ZrO₂ nanoparticles-coated Kevlar for improving UV–Vis absorbance/protection properties. SILICON 12, 1743–1750 (2020). https://doi.org/10.1007/s12633-019-00271-wCrossRef

Abouelnaga, A.M.; Meaz, T.M.; El Nahrawy, A.M.: Expansion of nanosized MgSiO₃/chitosan nanocomposite structural and spectroscopic for loading velosef by nanomaterial intervention. ECS J. Solid State Sci. Technol. 10, 121003 (2021). https://doi.org/10.1149/2162-8777/ac4386CrossRef

Higazy, A.A.; Afifi, H.; Khafagy, A.H.; El-Shahawy, M.A.; Mansour, A.M.: Ultrasonic studies on polystyrene/styrene butadiene rubber polymer blends filled with glass fiber and talc. Ultrasonics 44, e1439–e1445 (2006). https://doi.org/10.1016/j.ultras.2006.05.142CrossRef

El Nahrawy, A.M.; Hammad, A.B.A.; Youssef, A.M.; Mansour, A.M.; Othman, A.M.: Thermal, dielectric and antimicrobial properties of polystyrene-assisted/ITO:Cu nanocomposites. Appl. Phys. A Mater. Sci. Process. (2019). https://doi.org/10.1007/s00339-018-2351-5CrossRef

Song, R.; Murphy, M.; Li, C.; Ting, K.; Soo, C.; Zheng, Z.: Current development of biodegradable polymeric materials for biomedical applications. Drug Des. Dev. Ther. 12, 3117–3145 (2018). https://doi.org/10.2147/DDDT.S165440CrossRef

Baranwal, J.; Barse, B.; Fais, A.; Delogu, G.L.; Kumar, A.: Biopolymer: a sustainable material for food and medical applications. Polymers (Basel) 14, 983 (2022). https://doi.org/10.3390/polym14050983CrossRef

Elsabee, M.Z.; Abdou, E.S.: Chitosan based edible films and coatings: a review. Mater. Sci. Eng. C 33, 1819–1841 (2013). https://doi.org/10.1016/j.msec.2013.01.010CrossRef

10.

León-López, A.; Morales-Peñaloza, A.; Martínez-Juárez, V.M.; Vargas-Torres, A.; Zeugolis, D.I.; Aguirre-Álvarez, G.: Hydrolyzed collagen-sources and applications. Molecules 24, 4031 (2019). https://doi.org/10.3390/molecules24224031CrossRef

11.

Ikram, S.; Ahmed, S.: Natural polymers: derivatives, blends and composites. Nat. Polym. Deriv. Blends Compos. 2, 1–278 (2017)

12.

Duthen, S.; Rochat, C.; Kleiber, D.; Violleau, F.; Daydé, J.; Raynaud, C.; Levasseur-Garcia, C.: Physicochemical characterization and study of molar mass of industrial gelatins by AsFlFFFUV/MALS and chemometric approach. PLoS ONE 13, e203595 (2018). https://doi.org/10.1371/journal.pone.0203595CrossRef

13.

Eysturskard, J.; Haug, I.J.; Ulset, A.S.; Draget, K.I.: Mechanical properties of mammalian and fish gelatins based on their weight average molecular weight and molecular weight distribution. Food Hydrocoll. 23, 2315–2321 (2009). https://doi.org/10.1016/j.foodhyd.2009.06.007CrossRef

14.

Schroeder, W.A.; Kay, L.M.; LeGette, J.; Honnen, L.; Green, F.C.: The constitution of gelatin: separation and estimation of peptides in partial hydrolysates. J. Am. Chem. Soc. 76, 3556–3564 (1954). https://doi.org/10.1021/ja01642a062CrossRef

15.

El Nahrawy, A.M.; Mansour, A.M.; Abou Hammad, A.B.; Ibrahim, R.S.; Abouelnaga, A.M.; Abdel-Aziz, M.S.: Optical, functional impact and antimicrobial of chitosan/phosphosilicate/Al₂O₃ nanosheets. J. Inorg. Organomet. Polym. Mater. 30, 3084–3094 (2020). https://doi.org/10.1007/s10904-020-01469-xCrossRef

16.

Peng, W.; Ren, S.; Zhang, Y.; Fan, R.; Zhou, Y.; Li, L.; Xu, X.; Xu, Y.: MgO nanoparticles-incorporated PCL/gelatin-derived coaxial electrospinning nanocellulose membranes for periodontal tissue regeneration. Front. Bioeng. Biotechnol. 9, 216 (2021). https://doi.org/10.3389/fbioe.2021.668428CrossRef

17.

Liu, X.; He, X.; Jin, D.; Wu, S.; Wang, H.; Yin, M.; Aldalbahi, A.; El-Newehy, M.; Mo, X.; Wu, J.: A biodegradable multifunctional nanofibrous membrane for periodontal tissue regeneration. Acta Biomater. 108, 207–222 (2020). https://doi.org/10.1016/j.actbio.2020.03.044CrossRef

18.

Karthik, K.; Dhanuskodi, S.; Gobinath, C.; Prabukumar, S.; Sivaramakrishnan, S.: Fabrication of MgO nanostructures and its efficient photocatalytic, antibacterial and anticancer performance. J. Photochem. Photobiol. B Biol. 190, 8–20 (2019). https://doi.org/10.1016/j.jphotobiol.2018.11.001CrossRef

19.

Monzavi, A.; Eshraghi, S.; Hashemian, R.; Momen-Heravi, F.: In vitro and ex vivo antimicrobial efficacy of nano-MgO in the elimination of endodontic pathogens. Clin. Oral Investig. 19, 349–356 (2015). https://doi.org/10.1007/S00784-014-1253-YCrossRef

20.

Mansour, A.M.; Abou Hammad, A.B.; El Nahrawy, A.M.: Sol–gel synthesis and physical characterization of novel MgCrO₄–MgCu₂O₃ layered films and MgCrO₄-MgCu₂O₃/p-Si based photodiode. Nano-Struct. Nano-Objects 25, 100646 (2021). https://doi.org/10.1016/j.nanoso.2020.100646CrossRef

21.

Hemdan, B.A.; El Nahrawy, A.M.; Mansour, A.F.M.; Hammad, A.B.A.: Green sol–gel synthesis of novel nanoporous copper aluminosilicate for the eradication of pathogenic microbes in drinking water and wastewater treatment. Environ. Sci. Pollut. Res. 26, 9508–9523 (2019). https://doi.org/10.1007/s11356-019-04431-8CrossRef

22.

El Nahrawy, A.M.; Hemdan, B.A.; Mansour, A.M.; Elzwawy, A.; Abou Hammad, A.B.: Integrated use of nickel cobalt aluminoferrite/Ni²⁺ nano-crystallites supported with SiO₂ for optomagnetic and biomedical applications. Mater. Sci. Eng. B Solid-State Mater. Adv. Technol. 274, 115491 (2021). https://doi.org/10.1016/j.mseb.2021.115491CrossRef

23.

El Nahrawy, A.M.; Hemdan, B.A.; Mansour, A.M.; Elzwawy, A.; AbouHammad, A.B.: Structural and opto-magnetic properties of nickel magnesium copper zircon silicate nano-composite for suppress the spread of foodborne pathogenic bacteria. SILICON (2021). https://doi.org/10.1007/s12633-021-01295-xCrossRef

24.

El Nahrawy, A.M.; Mansour, A.M.; ElAttar, H.A.; Sakr, E.M.M.; Soliman, A.A.; Hammad, A.B.A.: Impact of Mn-substitution on structural, optical, and magnetic properties evolution of sodium–cobalt ferrite for opto-magnetic applications. J. Mater. Sci. Mater. Electron. 31, 6224–6232 (2020). https://doi.org/10.1007/s10854-020-03176-2CrossRef

25.

El Nahrawy, A.M.; Mansour, A.M.; Abou Hammad, A.B.: Spectroscopic study of Eu³⁺-doped magnesium lanthanum phosphate (MLPO) films on SiO₂ substrate. SILICON 14, 1227–1234 (2022). https://doi.org/10.1007/s12633-020-00855-xCrossRef

26.

El Nahrawy, A.M.; Elzwawy, A.; Abou Hammad, A.B.; Mansour, A.M.: Influence of NiO on structural, optical, and magnetic properties of Al₂O₃–P₂O₅–Na₂O magnetic porous nanocomposites nucleated by SiO₂. Solid State Sci. 108, 106454 (2020). https://doi.org/10.1016/j.solidstatesciences.2020.106454CrossRef

27.

Abou Hammad, A.B.; Mansour, A.M.; El Nahrawy, A.M.: Ni²⁺doping effect on potassium barium titanate nanoparticles: enhancement optical and dielectric properties. Phys. Scr. 96, 125821 (2021)CrossRef

28.

El Nahrawy, A.M.; Mansour, A.M.; Abou Hammad, A.B.; Wassel, A.R.: Effect of Cu incorporation on morphology and optical band gap properties of nano-porous lithium magneso-silicate (LMS) thin films. Mater. Res. Express. 6, 016404 (2019). https://doi.org/10.1088/2053-1591/aae343CrossRef

29.

Bakr, A.M.; Abou Hammad, A.B.; Wassel, A.R.; El Nahrawy, A.M.; Mansour, A.M.: Influence of Al, Fe, and Cu on the microstructure, diffused reflectance, THz, and dielectric properties for ZnTiO₃ nanocrystalline. Int. J. Mater. Eng. Innov. 12, 115–133 (2021). https://doi.org/10.1504/IJMATEI.2021.115604CrossRef

30.

Youssef, A.M.; El-Nahrawy, A.M.; Abou Hammad, A.B.: Sol–gel synthesis and characterizations of hybrid chitosan-PEG/calcium silicate nanocomposite modified with ZnO-NPs and (E102) for optical and antibacterial applications. Int. J. Biol. Macromol. 97, 561–567 (2017). https://doi.org/10.1016/J.IJBIOMAC.2017.01.059CrossRef

31.

Chaibakhsh, N.; Moradi-Shoeili, Z.: Enzyme mimetic activities of spinel substituted nanoferrites (MFe₂O₄): a review of synthesis, mechanism and potential applications. Mater. Sci. Eng. C 99, 1424–1447 (2019). https://doi.org/10.1016/J.MSEC.2019.02.086CrossRef

32.

Liu, L.; Liang, H.; Zhang, J.; Zhang, P.; Xu, Q.; Lu, Q.; Zhang, C.: Poly(vinyl alcohol)/chitosan composites: physically transient materials for sustainable and transient bioelectronics. J. Clean. Prod. 195, 786–795 (2018). https://doi.org/10.1016/J.JCLEPRO.2018.05.216CrossRef

33.

Singh, V.; Ahmed, S.: Silver nanoparticle (AgNPs) doped gum acacia–gelatin–silica nanohybrid: an effective support for diastase immobilization. Int. J. Biol. Macromol. 50, 353–361 (2012). https://doi.org/10.1016/j.ijbiomac.2011.12.017CrossRef

34.

Pincus, L.N.; Petrović, P.V.; Gonzalez, I.S.; Stavitski, E.; Fishman, Z.S.; Rudel, H.E.; Anastas, P.T.; Zimmerman, J.B.: Selective adsorption of arsenic over phosphate by transition metal cross-linked chitosan. Chem. Eng. J. 412, 128582 (2021). https://doi.org/10.1016/J.CEJ.2021.128582CrossRef

35.

Malwal, D.; Gopinath, P.: Silica stabilized magnetic-chitosan beads for removal of arsenic from water. Colloid Interface Sci. Commun. 19, 14–19 (2017). https://doi.org/10.1016/j.colcom.2017.06.003CrossRef

36.

Mohebbi, S.; Nezhad, M.N.; Zarrintaj, P.; Jafari, S.H.: Gholizadeh, S.S.; Saeb, M.R.; Mozafari, M.: Chitosan in biomedical engineering: a critical review. Curr. Stem Cell Res. Ther. 14, 93–116 (2019). https://doi.org/10.2174/1574888X13666180912142028CrossRef

37.

Abou Hammad, A.B.; Elnahrawy, A.M.; Youssef, A.M.; Youssef, A.M.: Sol–gel synthesis of hybrid chitosan/calcium aluminosilicate nanocomposite membranes and its application as support for CO₂ sensor. Int. J. Biol. Macromol. 125, 503–509 (2019). https://doi.org/10.1016/j.ijbiomac.2018.12.077CrossRef

38.

Naz, A., Arun, S., Kumari, R., Narvi, S.S., Alam, M.S.: CuII-metalated silica-based inorganic-organic hybrid: synthesis, characterization and its evaluation for dye degradation and oxidation of organic substrates. Chem. Biochem. Eng. Q 35: 225–250 (2021). https://doi.org/10.15255/CABEQ.2020.1906

39.

El Nahrawy, A.M.; Abou Hammad, A.B.; Mansour, A.M.: Compositional effects and optical properties of P₂O₅ doped magnesium silicate mesoporous thin films. Arab. J. Sci. Eng. 46, 5893–5906 (2021). https://doi.org/10.1007/s13369-020-05067-4CrossRef

40.

Mansour, A.M.: Fabrication and characterization of a photodiode based on 5′,5″-dibromo-o-cresolsulfophthalein (BCP). SILICON 11, 1989–1996 (2019). https://doi.org/10.1007/s12633-018-0016-9CrossRef

41.

Ibrahim, R.S.; Azab, A.A.; Mansour, A.M.: Synthesis and structural, optical, and magnetic properties of Mn-doped CdS quantum dots prepared by chemical precipitation method. J. Mater. Sci. Mater. Electron. 32, 19980–19990 (2021). https://doi.org/10.1007/s10854-021-06522-0CrossRef

42.

Thamilarasan, V.; Sethuraman, V.; Gopinath, K.; Balalakshmi, C.; Govindarajan, M.; Mothana, R.A.; Siddiqui, N.A.; Khaled, J.M.; Benelli, G.: Single step fabrication of chitosan nanocrystals using penaeus semisulcatus: potential as new insecticides, antimicrobials and plant growth promoters. J. Clust. Sci. 29, 375–384 (2018). https://doi.org/10.1007/s10876-018-1342-1CrossRef

43.

Bdewi, S.F.; Abdullah, O.G.; Aziz, B.K.; Mutar, A.A.R.: Synthesis, structural and optical characterization of MgO nanocrystalline embedded in PVA matrix. J. Inorg. Organomet. Polym. Mater. 26, 326–334 (2016). https://doi.org/10.1007/s10904-015-0321-3CrossRef

44.

Aziz, S.B.; Abdullah, O.G.; Saber, D.R.; Rasheed, M.A.; Ahmed, H.M.: Investigation of metallic silver nanoparticles through UV–Vis and optical micrograph techniques. Int. J. Electrochem. Sci. 12, 363–373 (2017). https://doi.org/10.20964/2017.01.22CrossRef

45.

Shehap, A.M.; Mahmoud, Kh.H.; Abdelkader, M.F.H.; El-Basheer, M.T.: Optical properties of gelatin/TGS composites (ETN)—MISD. Exp. Theor. Nanotechnol. 2, 103–121 (2017)CrossRef

46.

Attayil Sukumaran, S.; Kalimuthu, B.; Selvamurugan, N.; Mani, P.: Wound dressings based on chitosan/gelatin/MgO composite films. Int. J. Polym. Mater. Polym. Biomater. 71, 1252–1261 (2022). https://doi.org/10.1080/00914037.2021.1960342CrossRef

47.

Tripathy, S.K.: Refractive indices of semiconductors from energy gaps. Opt. Mater. (Amst) 46, 240–246 (2015). https://doi.org/10.1016/j.optmat.2015.04.026CrossRef

48.

Pal, S.; Kumar Tiwari, R.; Chandra Gupta, D.; Singh Verma, A.: Simplistic theoretical model for optoelectronic properties of compound semiconductors. J. Mater. Phys. Chem. 2, 20–27 (2014). https://doi.org/10.12691/jmpc-2-2-2CrossRef

49.

Duffy, J.A.: Ultraviolet transparency of glass: A chemical approach in terms of band theory, polarisability and electronegativity, https://abdn.pure.elsevier.com/en/publications/ultraviolet-transparency-of-glass-a-chemical-approach-in-terms-of

50.

Pauling, L.: The Nature of the Chemical Bond: An Introduction to Modern Structural Chemistry. Cornell University Press, Ethaca (1960)

51.

El Nahrawy, A.M.; Ali, A.I.; Mansour, A.M.; Abou Hammad, A.B.; Hemdan, B.A.; Kamel, S.: Talented Bi_0.5Na_0.25K_0.25TiO₃/oxidized cellulose films for optoelectronic and bioburden of pathogenic microbes. Carbohydr. Polym. 291, 119656 (2022). https://doi.org/10.1016/j.carbpol.2022.119656CrossRef

52.

Xiao, G.; Su, H.; Tan, T.: Synthesis of core–shell bioaffinity chitosan–TiO2 composite and its environmental applications. J. Hazard. Mater. 283, 888–896 (2015). https://doi.org/10.1016/J.JHAZMAT.2014.10.047CrossRef

53.

Vinsova, J.; Vavrikova, E.: Chitosan derivatives with antimicrobial, antitumour and antioxidant activities—a review. Curr. Pharm. Des. 17, 3596–3607 (2011). https://doi.org/10.2174/138161211798194468CrossRef

54.

Sudatta, B.P.; Sugumar, V.; Varma, R.; Nigariga, P.: Extraction, characterization and antimicrobial activity of chitosan from pen shell. Pinna Bicolor. Int. J. Biol. Macromol. 163, 423–430 (2020). https://doi.org/10.1016/J.IJBIOMAC.2020.06.291CrossRef

Titel: Chitosan/In situ Gelatin-Mg3Si2O5(OH)4 Nanocomposites via Sol–Gel Method: Preparation, Characterization and Antimicrobial Properties
verfasst von: A. M. Mansour
Ali B. Abou Hammad
Alaa Omar Balkhtb
Thoraya Maamoun Elhelali
Amel Mohamed Abouelnaga
Amany M. El Nahrawy
Publikationsdatum: 15.06.2023
Verlag: Springer Berlin Heidelberg
Erschienen in: Arabian Journal for Science and Engineering / Ausgabe 1/2024
Print ISSN: 2193-567X
Elektronische ISSN: 2191-4281
DOI: https://doi.org/10.1007/s13369-023-07935-1

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 1/2024

A Novel Synthesis of Hydrothermally Prepared Europium Sulfide and Cerium Sulfide Nanomaterials Doped with Yttrium

ZnFe2O4/SiO2 Nanocomposites Prepared via the Natural Surfactant Morus alba L. as an Excellent Candidate for Drug Delivery Agent

Calculation of Neutron Microdosimetry Spectra in Some Real Tissues Compared to Alternative Tissue Equivalent Materials

Green Synthesis of Polyurethanes Using Soybean Oil-Based Polyols for Bioactive Functional Fabrics

Optical and Electrical Properties and Thermal Stability of Nanocomposites Containing CuO and ZrO2 Doped into Carboxy Methyl Cellulose for Batteries Applications

Optimisation of Adsorption Removal of Bisphenol A Using Sludge-Based Activated Carbons: Application of Response Surface Methodology with a Box–Behnken Design

Premium Partner

Marktübersichten