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08.12.2022 | Original Research

Chitosan Schiff base for the spectrofluorimetric analysis of E-waste toxins: Pentabromophenol, Fe³⁺, and Cu²⁺ ions

verfasst von: Harshita Gupta, Kulwinder Kaur, Raghubir Singh, Varinder Kaur

Erschienen in: Cellulose | Ausgabe 3/2023

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Abstract

A chitosan Schiff base (SB@Chitosan) has been prepared by the condensation reaction of 5-bromosalicyldehyde and chitosan. The structural properties of SB@Chitosan have been investigated through FT-IR, ¹H NMR, PXRD, TGA, and SEM analysis. The SB@Chitosan exhibited a fluorescence emission signal centred at 501 nm (λ_exc = 340 nm). However, the signal was quenched in the presence of e-waste toxins i.e. pentabrominated phenol, Fe³⁺, and Cu²⁺ ions. Therefore, SB@Chitosan was investigated as a spectrofluorimetric probe for the recognition and quantification of Fe³⁺, Cu²⁺, and pentabromophenol in organic-aqueous medium (H₂O/DMSO; 30:70% v/v). The density-functional theory suggested the acid–base pair formation between azomethinic functionality and pentabromophenol which led to the quenching of fluorescent signal due to the photoinduced electron transfer mechanism. It also supported the mechanism of interaction between SB@Chitosan and heavy metals based on the HOMO–LUMO energy gap. The probe was also tested for practical applications like the analysis of water and soil samples.

Vorheriger Artikel Efficient separation of cellulose from bamboo by organic alkali

Nächster Artikel Impact of degree of substitution of quaternary cellulose on the adsorption on charged surfaces and associated thermodynamics

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Titel: Chitosan Schiff base for the spectrofluorimetric analysis of E-waste toxins: Pentabromophenol, Fe3+, and Cu2+ ions
verfasst von: Harshita Gupta
Kulwinder Kaur
Raghubir Singh
Varinder Kaur
Publikationsdatum: 08.12.2022
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 3/2023
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-022-04966-z

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