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Journal of Materials Science

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04.03.2021 | Metals & corrosion

Corrosion resistant and conductive TiN/TiAlN multilayer coating on 316L SS: a promising metallic bipolar plate for proton exchange membrane fuel cell

verfasst von: S. Pugal Mani, M. Kalaiarasan, K. Ravichandran, N. Rajendran, Y. Meng

Erschienen in: Journal of Materials Science | Ausgabe 17/2021

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Abstract

The single layers of TiN, TiAlN and TiN/TiAlN multilayer coatings were deposited on 316L SS bipolar plate by physical vapor deposition technique. The X-ray diffraction studies revealed that the formed coatings exhibited single-phase cubic structure. The low surface roughness and high contact angles of the TiAlN and TiN/TiAlN coatings governed the better water management in the fuel cell. Nyquist and Bode-impedance studies of TiN/TiAlN coating ensured higher electrochemical impedance behavior. The polarization results revealed that the current densities (i_corr) of TiN/TiAlN coating were below 1 µA/cm² in the PEMFC environments, which satisfied the U.S. Department of Energy’s 2020 target. The contact resistance of the TiN/TiAlN-coated 316L SS was the lowest and fulfilled the requirements of bipolar plate (≤ 10 mΩ cm²) in PEMFC environment. Surface morphology results revealed that the surface of 316L SS is well protected by multilayer TiN/TiAlN coating. Inductive coupled plasma-optical emission spectroscopy results are in good agreement with electrochemical studies revealing the TiN/TiAlN coating significantly reduced the metal ions dissolution.

Vorheriger Artikel Preparation and electrochemical properties of ionic-liquid-modified Na3SbS4 membrane composite electrolytes

Nächster Artikel Dissolution and isothermal solidification behaviour of commercially pure titanium brazed using a pure nickel filler under TLPB conditions

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Atyabi SA, Afshari E (2019) Three-dimensional multiphase model of proton exchange membrane fuel cell with honeycomb flow field at the cathode side. J Clean Prod 214:738–748CrossRef

Chatrattanawet N, Hakhen T, Kheawhom S, Arpornwichanop A (2017) Control structure design and robust model predictive control for controlling a proton exchange membrane fuel cell. J Clean Prod 148:934–937CrossRef

Yi P, Dong C, Zhang T, Xiao K, Ji Y, Wu J, Li X (2019) Effect of plasma electrolytic nitriding on the corrosion behavior and interfacial contact resistance of titanium in the cathode environment of proton-exchange membrane fuel cells. J Power Sourc 418:42–49CrossRef

Shanmugham C, Rajendran N (2019) Poly (m-phenylenediamine)-coated 316L SS: a promising material for bipolar plates in PEMFC environment. Mater Corros 76:1646–1656CrossRef

Nikolov K, Bunk K, Jung A, Gerlach JW, Kaestner P, Klages C-P (2017) Combined plasma surface modification of austenitic stainless steel for bipolar plates. Surf Goat Technol 328:142–151CrossRef

Hou K, Yi P, Peng L, Lai X (2019) Niobium doped amorphous carbon film on metallic bipolar plates for PEMFCs: first principle calculation, microstructure and performance. Int J Hydrog Energy 44:3144–3156CrossRef

Yi P, Zhu L, Dong C, Xiao K (2019) Corrosion and interfacial contact resistance of 316L stainless steel coated with magnetron sputtered ZrN and TiN in the simulated cathodic environment of a proton-exchange membrane fuel cell. Surf Coat Technol 363:198–202CrossRef

Li R, Cai Y, Wippermann K, Lehnert W (2019) Bilayer CrN/Cr coating modified 316L stainless steel bipolar plates for high temperature polymer electrolyte fuel cells. J Power Sourc 434:226718–226725CrossRef

Jin CK, Lee JH, Kang CG (2015) Performance and characteristics of titanium nitride, chromium nitride, multi-coated stainless steel 304 bipolar plates fabricated through a rubber forming process. Int J Hydrog Energy 40:6681–6688CrossRef

10.

Asri NF, Husaini T, Sulong AB, Majlan EH, Daud WRW (2017) Coating of stainless steel and titanium bipolar plates for anticorrosion in PEMFC: a review. Int J Hydrog Energy 42:9135–9148CrossRef

11.

Pugal Mani S, Rikhari B, Agilan P, Rajendran N (2018) Evaluation of the corrosion behaviour of a TiN coated 316L SS bipolar plate using dynamic electrochemical impedance spectroscopy. New J Chem 42:14394–14494CrossRef

12.

Faizan Khan M, Adesina AK, Gasem ZM (2019) Electrochemical and electrical resistance behavior of cathodic arc PVD TiN, CrN, AlCrN, and AlTiN coatings in simulated proton exchange membrane fuel cell environment. Mater Corros 70:281–292CrossRef

13.

Adesina AY, Al-Badour FA, Gasem ZM (2018) Wear resistance performance of AlCrN and TiAlN coated H13 tools during friction stir welding of A2124/SiC composite. J Manuf Process 33:111–125CrossRef

14.

Aihua L, Jianxin D, Haibing C, Yangyang C, Jun Z (2012) Friction and wear properties of TiN, TiAlN, AlTiN and CrAlN PVD nitride coatings. Int J Refract Met Hard Mater 31:82–88CrossRef

15.

Nam ND, Vaka M, Hung NT (2014) corrosion behavior of TiN, TiAlN, TiAlSiN—coated 316L stainless steel in simulated proton exchange membrane fuel cell environment. J Power Sourc 268:240–245CrossRef

16.

Feng K, Guo X, Li Z, Yao C, Wu Y (2016) Investigation of multi-coating process treated magnesium alloy as bipolar plate in polymer electrolyte membrane fuel cell. Int J Hydrog Energy 41:6020–6028CrossRef

17.

Omrani M, Habibi M, Moti Birjandi MS (2016) Enhanced electrical conductivity of two layers AlN–TiN coating on SS316L as bipolar plate using plasma focus device. Int J Hydrog energy 41:5028–5036CrossRef

18.

Jin J, Zheng D, Liu H (2017) The corrosion behavior and mechanical properties of CrN/Ni–P multilayer coated mild steel as bipolar plates for proton exchange membrane fuel cells. Int J Hydrog energy 42:28883–28897CrossRef

19.

Alishahi M, Mahboubi F, Mousavihoie SM, Aparicio M, Hübner R, Soldera F, Gago R (2016) Electrochemical behavior of nanocrystalline Ta/TaN multilayer on 316L stainless steel: novel bipolar plates for proton exchange membrane fuel-cells. J Power Sourc 322:1–9CrossRef

20.

Bi F, Feng L, Yi P, Lai X (2016) Multilayered Zr–C/a–C film on stainless steel 316L as bipolar plates for proton exchange membrane fuel cells. J Power Sourc 314:58–65CrossRef

21.

Pugal Mani S, Srinivasan A, Rajendran N (2015) Effect of nitrides on the corrosion behavior of 316L SS bipolar plates for proton exchange membrane fuel cell (PEMFC). Int J Hydrog Energy 40:3359–3369CrossRef

22.

Li WW, Jing S, Wang SB, Wang C, Xie XF (2016) Experimental investigation of expanded graphite/phenolic resin composite bipolar plate. Int J Hydrog Energy 41:16240–16246CrossRef

23.

Wang XZ, Muneshwar TP, Fan HQ, Cadien K, Luo JL (2018) Achieving ultrahigh corrosion resistance and conductive zirconium oxynitride coating on metal bipolar plates by plasma enhanced atomic layer deposition. J Power Sourc 397:32–36CrossRef

24.

Lee SH, Yang TH, Hyun SH, Yoon YS (2012) Corrosion behavior of pre-oxidized and thermally nitrided stainless steel for polymer electrolyte membrane fuel cell bipolar plates. Corros Sci 58:79–85CrossRef

25.

Antunus RA, Oliveira L, Ett G, Ett V (2010) Corrosion of metal bipolar plates for PEM fuel cells: a review. Int J Hydrog Energy 35:3632–3647CrossRef

26.

Wang L, Tao Y, Zhang Z, Wang Y, Feng Q, Wang H, Lui H (2019) Molybdenum carbide coated 316L stainless steel for bipolar plates of proton exchange membrane fuel cells. Int J Hydrog Energy 44:4940–4950CrossRef

27.

Mingge W, Congda L, Tao H, Guohai C, Donghui W, Haifeng Z, Dong Z, Aiying W (2016) Chromium interlayer amorphous carbon film for 304 stainless steel bipolar plate of proton exchange membrane fuel cell. Surf Goat Technol 307:374–381CrossRef

28.

Jin J, Zhu Z, Zheng D (2017) Influence of Ti content on the corrosion properties and contact resistance of CrTiN coating in simulated proton exchange membrane fuel cells. Int J Hydrog Energy 42:11758–11770CrossRef

29.

Wang L, Northwood DO, Nie X, Housden J, Spain E, Leyland A, Matthews A (2010) Corrosion properties and contact resistance of TiN, TiAlN and CrN coatings in simulated proton exchange membrane fuel cell environments. J Power Sources 195:3814–3821CrossRef

30.

Deng Y, Tan C, Wang Y, Chen L, Cai P, Kuang T, Lei S, Zhou K (2017) Effects of tailored nitriding layers on comprehensive properties of duplex plasma-treated AlTiN coatings. Ceram Int 43:8721–8729CrossRef

31.

Yong-Qiang W, Chun-Wei LI, Chun-Zhi G, Xiu-Bo T, Shi-Qin Y (2011) Microstructure and mechanical Properties of TiN/TiAlN multilayer coatings deposited by arc ion plating with separate targets. Trans Nanoferrous Met Soc China 11:1068–1073

32.

Caicedo JC, Cabrera G, Caicedo HH, Amaya C, Aperador W (2012) Nature in corrosion–erosion surface for [TiN/TiAlN] nanometric multilayers growth on AII 1045 steel. Thin Solid Films 520:4350–4361CrossRef

33.

Pugal Mani S, Anandan C, Rajendran N (2015) Formation of a protective nitride layer on 316L SS bipolar plates for proton exchange membrane fuel cell (PEMFC). RSC Adv 5:64466–64470CrossRef

34.

Pugal Mani S, Rajendran N (2017) Corrosion and interfacial contact resistance behavior of electrochemically nitrided 316L SS bipolar plates for proton exchange membrane fuel cells. Energy 133:1050–1062CrossRef

35.

Elangovan N, Srinivasan A, Pugal Mani S, Rajendran N, Rajendiran N (2017) Development of poly (vinylcarbazole)/alumina nanocomposite coatings for corrosion protection of 316L stainless steel in 3.5% NaCl medium. J Appl Polym Sci 134:44937–44949CrossRef

36.

Rikhari B, Pugal Mani S, Rajendran N (2016) Investigation of corrosion behavior of polypyrrole coated Ti using dynamic electrochemical impedance spectroscopy (DEIS). RSC Adv 6:80275–80285CrossRef

37.

Wang Y, Zhang S, Lu Z, Wang L, Li W (2018) Preparation and performances of electrically conductive Nb-doped TiO₂ coatings for 316 stainless steel bipolar plates of proton-exchange membrane fuel cells. Corros Sci 142:249–257CrossRef

38.

Ren YJ, Anisur MR, Qiu W, He JJ, Al-Saadi S, Singh Raman RK (2017) Degradation of graphene coated copper in simulated proton exchange membrane fuel cell environment: electrochemical impedance spectroscopy study. J Power Sources 362:366–372CrossRef

39.

Rikhari B, Pugal Mani S, Rajendran N (2018) Electrochemical behavior of polypyrrole/chitosan composite coating on Ti metal for biomedical applications. Carbohydr Polym 189:126–137CrossRef

40.

Jin J, Liu H, Zheng D, Zhu Z (2018) Effects of Mo content on the interfacial contact resistance and corrosion properties of CrN coatings on SS316L as bipolar plates in simulated PEMFCs environment. Int J Hydrog Energy 43:10048–10060CrossRef

41.

Panjan P, Cekada M, Panjan M, Kek Merl D (2010) Growth defects in PVD hard coatings. Vacuum 84:209–214CrossRef

42.

Bi F, Yi P, Zhou T, Peng L, Lai X (2015) Effects of Al incorporation on the interfacial conductivity and corrosion resistance of CrN film on SS316L as bipolar plates for proton exchange membrane fuel cells. Int J Hydrog Energy 40:9790–97802CrossRef

43.

Simi V, Rajendran N (2017) Influence of tunable diameter on the electrochemical behavior and antibacterial activity of titania nanotube arrays for biomedical applications. Mater Charact 129:67–79CrossRef

44.

Feng K, Wu G, Li Z, Cai X, Chu PK (2011) Corrosion behavior of SS316L in simulated and accelerated PEMFC environments. Int J Hydrog Energy 36:13032–13042CrossRef

45.

Yang Y, Nang X, Tang H, Guo L, Liu H (2014) Effect of passive films on corrosion resistance of uncoated 316L SS bipolar plates for proton exchange membrane fuel cell application. App Surf Sci 320:274–280CrossRef

46.

TIBTECH Innovations (2015) Properties table of stainless steel, metals and other conductive materials. http://www.tibtech.com/conductivity.php

47.

Dadfar M, Salehi M, Golozar MA, Trasatti S (2016) Surface modification of 304 stainless steels to improve corrosion behavior and interfacial contact resistance of bipolar plates. Int J Hydrog Energy 41:21375–21384CrossRef

48.

Lee YH, Noh S, Lee JH, Chun SH, Cha SW, Chang I (2017) Durable graphene-coated bipolar plates for polymer electrolyte fuel cells. Int J Hydrog Energy 42:27350–27353CrossRef

49.

Jin J, Zheng D, Han S, Ma J, Zhu Z (2017) Effect of Ni content on the electrical and corrosion properties of CrNiN coating in simulated proton exchange membrane fuel cell. Int J Hydrog Energy 42:1142–1153CrossRef

50.

Peng S, Xu J, Li Z, Jiang S, Munroe P, Xie Z, Lu H (2020) A reactive-sputter-deposited TiSiN nanocomposite coating for the protection of metallic bipolar plates in proton exchange membrane fuel cell. Ceram Int 46:2743–2757CrossRef

Titel: Corrosion resistant and conductive TiN/TiAlN multilayer coating on 316L SS: a promising metallic bipolar plate for proton exchange membrane fuel cell
verfasst von: S. Pugal Mani
M. Kalaiarasan
K. Ravichandran
N. Rajendran
Y. Meng
Publikationsdatum: 04.03.2021
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 17/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-020-05682-4

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