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Cellulose
Erschienen in: Cellulose 5/2013

01.10.2013 | Original Paper

Decomposition behaviors of various crystalline celluloses as treated by semi-flow hot-compressed water

verfasst von: Rosnah Abdullah, Kazuyoshi Ueda, Shiro Saka

Erschienen in: Cellulose | Ausgabe 5/2013

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Abstract

Various types of crystalline cellulose consisting of group I (cell I, IIII, IVI) and group II (cell II, IIIII, IVII) prepared from cotton linter were adjusted for their degree of polymerization (DP) as starting materials. These celluloses were then treated by semi-flow hot-compressed water (HCW) at 230–270 °C/10 MPa/2–15 min to study their decomposition behaviors. The treatments performed resulted in residues of celluloses and water-soluble (WS) portions. Consequently, the crystallinity of the residues was found to remain the same, but the DP was reduced as the temperature increased. Additionally, X-ray diffractometry and Fourier transform-infrared analyses demonstrated that crystallographic changes occurred for residues of cell IIII, IVI and IIIII. Despite these changes, the overall results of the residues showed that group I has higher resistance to decomposing than group II. As for the WS portions, the yields of the hydrolyzed and degraded products were higher in group II than group I, indicating that group II is less resistant to decomposition by HCW treatment. Results for both the residues and WS portions are in agreement with each other, showing that the degree of difficulty of decomposition was higher in group I than group II. Therefore, the decomposition behaviors of the celluloses are due to differences in the crystalline forms.
Vorheriger Artikel Effect of temperature on high pressure cellulose compression
Nächster Artikel Effects of pressurized hot water extraction on the nanoscale structure of birch sawdust

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Metadaten
Titel
Decomposition behaviors of various crystalline celluloses as treated by semi-flow hot-compressed water
verfasst von
Rosnah Abdullah
Kazuyoshi Ueda
Shiro Saka
Publikationsdatum
01.10.2013
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 5/2013
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-013-0022-4

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