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Erschienen in: Journal of Nanoparticle Research 4/2013

01.04.2013 | Research Paper

Design and experimental evaluation of a new nanoparticle thermophoretic personal sampler

verfasst von: Nkwenti Azong-Wara, Christof Asbach, Burkhard Stahlmecke, Heinz Fissan, Heinz Kaminski, Sabine Plitzko, Dieter Bathen, Thomas A. J. Kuhlbusch

Erschienen in: Journal of Nanoparticle Research | Ausgabe 4/2013

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Abstract

A personal sampler that thermophoretically samples particles between a few nanometers and approximately 300 nm has been designed and first prototypes built. The thermal precipitator (TP) is designed to take samples in the breathing zone of a worker in order to determine the personal exposure to airborne nanomaterials. In the sampler, particles are deposited onto silicon substrates that can be used for consecutive electron microscopic (EM) analysis of the particle size distribution and chemical composition of the sampled particles. Due to very homogeneous size-independent particle deposition on a large portion of the substrate, representative samples can be taken for offline analysis. The experimental evaluation revealed a good general agreement with numerical simulations concerning homogeneity of the deposit and a very high correlation (R² = 0.98) of the deposition rate per unit area with number concentrations simultaneously measured with an SMPS for particle sizes between 14 and 305 nm. The samplers’ small size of only 45 x 32 × 97 mm3 and low weight of only 140 g make it perfectly suitable as a personal sampler. The power consumption for temperature control and pump is around 1.5 W and can be easily provided by batteries.

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Literatur
Zurück zum Zitat Asbach C, Kuhlbusch TAJ, Fissan H (2005) Effect of corona discharge on the gas composition of the sample flow in the gas particle partitioner. J Environ Mon 7:877–882CrossRef Asbach C, Kuhlbusch TAJ, Fissan H (2005) Effect of corona discharge on the gas composition of the sample flow in the gas particle partitioner. J Environ Mon 7:877–882CrossRef
Zurück zum Zitat Azong-Wara N, Asbach C, Stahlmecke B, Fissan H, Kaminski H, Plitzko S, Kuhlbusch TAJ (2009) Optimisation of a thermophoretic personal sampler for nanoparticle exposure studies. J Nanoparticle Res 11:1611–1624CrossRef Azong-Wara N, Asbach C, Stahlmecke B, Fissan H, Kaminski H, Plitzko S, Kuhlbusch TAJ (2009) Optimisation of a thermophoretic personal sampler for nanoparticle exposure studies. J Nanoparticle Res 11:1611–1624CrossRef
Zurück zum Zitat Bang JJ, Elizabeth AT, Lawrence EM (2003) Utilization of selected area electron diffraction patterns for characterization of air submicron particulate matter collected by a thermophoretic precipitator. J Air Waste Manage Assoc 53:227–236CrossRef Bang JJ, Elizabeth AT, Lawrence EM (2003) Utilization of selected area electron diffraction patterns for characterization of air submicron particulate matter collected by a thermophoretic precipitator. J Air Waste Manage Assoc 53:227–236CrossRef
Zurück zum Zitat Berner A (1972) Praktische erfahrungen mit einem 20-stufen-impaktor. Staub, Reinhaltung der Luft 32:315–320 Berner A (1972) Praktische erfahrungen mit einem 20-stufen-impaktor. Staub, Reinhaltung der Luft 32:315–320
Zurück zum Zitat Boelter KJ, Davidson JH (1997) Ozone generation by indoor, electrostatic air cleaners. Aerosol Sci Technol 27:689–708CrossRef Boelter KJ, Davidson JH (1997) Ozone generation by indoor, electrostatic air cleaners. Aerosol Sci Technol 27:689–708CrossRef
Zurück zum Zitat Borm PJA, Robbins D, Haubold S, Kuhlbusch T, Fissan H, Donaldson K, Schins R, Stone V, Kreyling W, Lademann J, Krutmann J, Warheit D, Oberdorster E (2006) The potential risks of nanomaterials: a review carried out for ECETOC. Part Fibre Toxicol 3:11CrossRef Borm PJA, Robbins D, Haubold S, Kuhlbusch T, Fissan H, Donaldson K, Schins R, Stone V, Kreyling W, Lademann J, Krutmann J, Warheit D, Oberdorster E (2006) The potential risks of nanomaterials: a review carried out for ECETOC. Part Fibre Toxicol 3:11CrossRef
Zurück zum Zitat Brock JR (1962) On the theory of thermal forces acting on aerosol particles. J Colloid Sci 17:768–770CrossRef Brock JR (1962) On the theory of thermal forces acting on aerosol particles. J Colloid Sci 17:768–770CrossRef
Zurück zum Zitat Brouwer D, van Duuren-Stuurman B, Berges M, Jankowska E, Bard D, Mark D (2009) From workplace air measurement results towards estimates of exposure? Development of a strategy to assess exposure to manufactured nano-objects. J Nanopart Res 11:1867–1881CrossRef Brouwer D, van Duuren-Stuurman B, Berges M, Jankowska E, Bard D, Mark D (2009) From workplace air measurement results towards estimates of exposure? Development of a strategy to assess exposure to manufactured nano-objects. J Nanopart Res 11:1867–1881CrossRef
Zurück zum Zitat Cardello N, Volckens J, Tolocka MP, Wiener R, Buckley TJ (2002) Technical note: performance of a personal electrostatic precipitator particle sampler. Aerosol Sci Technol 36:162–165CrossRef Cardello N, Volckens J, Tolocka MP, Wiener R, Buckley TJ (2002) Technical note: performance of a personal electrostatic precipitator particle sampler. Aerosol Sci Technol 36:162–165CrossRef
Zurück zum Zitat Cena LG, Anthony R, Peters TM (2011) A personal nanoparticle respiratory deposition (NRD) sampler. Environ Sci Technol 45:6483–6490CrossRef Cena LG, Anthony R, Peters TM (2011) A personal nanoparticle respiratory deposition (NRD) sampler. Environ Sci Technol 45:6483–6490CrossRef
Zurück zum Zitat Donaldson K, Li XY, MacNee W (1998) Ultrafine (nanometer) particle mediated lung injury. J Aerosol Sci 29(5–6):553–560CrossRef Donaldson K, Li XY, MacNee W (1998) Ultrafine (nanometer) particle mediated lung injury. J Aerosol Sci 29(5–6):553–560CrossRef
Zurück zum Zitat Donaldson K, Brown D, Clouter A, Duffin R, MacNee W, Renwick L, Tran L, Stone V (2002) The pulmonary toxicology of ultrafine particles. J Aerosol Med 15(2):213–220CrossRef Donaldson K, Brown D, Clouter A, Duffin R, MacNee W, Renwick L, Tran L, Stone V (2002) The pulmonary toxicology of ultrafine particles. J Aerosol Med 15(2):213–220CrossRef
Zurück zum Zitat Epstein PS (1929) Zur theorie des radiometers. Zeitschrift Phys 54:537–563CrossRef Epstein PS (1929) Zur theorie des radiometers. Zeitschrift Phys 54:537–563CrossRef
Zurück zum Zitat Furuuchi M, Choosong T, Hata M, Otani Y, Tekasakul P, Takizawa M, Nagura M (2010) Development of a personal sampler for evaluating exposure to ultrafine particles. Aerosol Air Qual Res 10:30–37 Furuuchi M, Choosong T, Hata M, Otani Y, Tekasakul P, Takizawa M, Nagura M (2010) Development of a personal sampler for evaluating exposure to ultrafine particles. Aerosol Air Qual Res 10:30–37
Zurück zum Zitat Gonzalez D, Nasibulin AG, Baklanov AM, Shandakov SD, Brown DP, Queipo P, Kauppinen EI (2005) A new thermophoretic precipitator for collection of nanometer-sized aerosol particles. Aerosol Sci Technol 39:1064–1071CrossRef Gonzalez D, Nasibulin AG, Baklanov AM, Shandakov SD, Brown DP, Queipo P, Kauppinen EI (2005) A new thermophoretic precipitator for collection of nanometer-sized aerosol particles. Aerosol Sci Technol 39:1064–1071CrossRef
Zurück zum Zitat Green HL, Watson HH (1935) Medical research council, special report series, no. 199. KMS, London Green HL, Watson HH (1935) Medical research council, special report series, no. 199. KMS, London
Zurück zum Zitat Hering SV, Flagan RC, Friedlander SK (1978) Design and evaluation of new low pressure impactor. Env Sci Technol 12:667–673CrossRef Hering SV, Flagan RC, Friedlander SK (1978) Design and evaluation of new low pressure impactor. Env Sci Technol 12:667–673CrossRef
Zurück zum Zitat Keskinen J, Pietarinen K, Lehtmäki M (1992) Electrical low pressure impactor. J Aerosol Sci 23:353–360CrossRef Keskinen J, Pietarinen K, Lehtmäki M (1992) Electrical low pressure impactor. J Aerosol Sci 23:353–360CrossRef
Zurück zum Zitat Kethley TH, Gordon MR, Orr C (1952) A thermal precipitator for aerobacteriology. Science 116:368–369CrossRef Kethley TH, Gordon MR, Orr C (1952) A thermal precipitator for aerobacteriology. Science 116:368–369CrossRef
Zurück zum Zitat Kodas T, Hampden-Smith M (1999) Aerosol processing of materials. Willey, New York Kodas T, Hampden-Smith M (1999) Aerosol processing of materials. Willey, New York
Zurück zum Zitat Krames J, Büttner H, Ebert F (1991) Submicron particle generation by evaporation of water droplets. J Aerosol Sci 35:143–176 Krames J, Büttner H, Ebert F (1991) Submicron particle generation by evaporation of water droplets. J Aerosol Sci 35:143–176
Zurück zum Zitat Kuhlbusch TAJ, Fissan H (2006) Particle characteristics in the reactor and pelletizing areas of carbon black production. J Occup Env Hygiene 3:558–567CrossRef Kuhlbusch TAJ, Fissan H (2006) Particle characteristics in the reactor and pelletizing areas of carbon black production. J Occup Env Hygiene 3:558–567CrossRef
Zurück zum Zitat Kuhlbusch TAJ, Fissan H, Neumann S (2004) Number size distribution, mass concentration, and particle composition of PM1, PM2.5 and PM10 in bag filling areas of carbon black production, ICBA-study. J Occup Env Hygiene 1:660–674CrossRef Kuhlbusch TAJ, Fissan H, Neumann S (2004) Number size distribution, mass concentration, and particle composition of PM1, PM2.5 and PM10 in bag filling areas of carbon black production, ICBA-study. J Occup Env Hygiene 1:660–674CrossRef
Zurück zum Zitat Kuhlbusch TAJ, Asbach C, Fissan H, Göhler D, Stintz M (2011) Nanoparticle exposure at nanotechnology workplaces: a review. Part Fibre Toxicol 8:22CrossRef Kuhlbusch TAJ, Asbach C, Fissan H, Göhler D, Stintz M (2011) Nanoparticle exposure at nanotechnology workplaces: a review. Part Fibre Toxicol 8:22CrossRef
Zurück zum Zitat Lee SJ, Demokritou P, Koutrakis P, Delgado-Saborit JM (2006) Development and evaluation of personal respirable particulate sampler. Atm Environ 40:212–224 Lee SJ, Demokritou P, Koutrakis P, Delgado-Saborit JM (2006) Development and evaluation of personal respirable particulate sampler. Atm Environ 40:212–224
Zurück zum Zitat Martinez P, Brandvold DK (1996) Laboratory and field measurements of NOx produced from corona discharge. Atm Environ 30:4177–4182CrossRef Martinez P, Brandvold DK (1996) Laboratory and field measurements of NOx produced from corona discharge. Atm Environ 30:4177–4182CrossRef
Zurück zum Zitat Maynard AD (1995) The development of a new thermophoretic precipitator for scanning transmission electron microscope analysis of ultrafine aerosol particles. Aerosol Sci Technol 23(4):521–533CrossRef Maynard AD (1995) The development of a new thermophoretic precipitator for scanning transmission electron microscope analysis of ultrafine aerosol particles. Aerosol Sci Technol 23(4):521–533CrossRef
Zurück zum Zitat Miller A, Marinos A, Wendel C, King G, Bugarski A (2012) Design optimization of a portable thermophoretic precipitator nanoparticle sampler. Aerosol Sci Technol 46:897–904CrossRef Miller A, Marinos A, Wendel C, King G, Bugarski A (2012) Design optimization of a portable thermophoretic precipitator nanoparticle sampler. Aerosol Sci Technol 46:897–904CrossRef
Zurück zum Zitat Misra C, Singh M, Shen S, Sioutas C, Hall PM (2002) Development and evaluation of a personal cascade impactor (PCIS). J Aerosol Sci 33:1027–1047CrossRef Misra C, Singh M, Shen S, Sioutas C, Hall PM (2002) Development and evaluation of a personal cascade impactor (PCIS). J Aerosol Sci 33:1027–1047CrossRef
Zurück zum Zitat Montassier N, Boulaud D, Renoux A (1991) Experimental study of thermophoretic particle deposition in laminar tube flow. J Aerosol Sci 22:677–687CrossRef Montassier N, Boulaud D, Renoux A (1991) Experimental study of thermophoretic particle deposition in laminar tube flow. J Aerosol Sci 22:677–687CrossRef
Zurück zum Zitat Oberdörster G (2001) Pulmonary effects of inhaled ultrafine particles. In Arch Occup Environ Health 74:1–8CrossRef Oberdörster G (2001) Pulmonary effects of inhaled ultrafine particles. In Arch Occup Environ Health 74:1–8CrossRef
Zurück zum Zitat Oberdörster G, Sharp Z, Atudorei V, Elder A, Gelein R, Lunts A, Kreyling W, Cox C (2002) Extrapulmonary translocation of ultrafine carbon particles following whole-body inhalation exposure of rats. J Toxicol Environ Health A 65:1531–1543CrossRef Oberdörster G, Sharp Z, Atudorei V, Elder A, Gelein R, Lunts A, Kreyling W, Cox C (2002) Extrapulmonary translocation of ultrafine carbon particles following whole-body inhalation exposure of rats. J Toxicol Environ Health A 65:1531–1543CrossRef
Zurück zum Zitat PALAS (2003) Model GFG-1000, aerosol generator instruction manual. PALAS® GmbH, Karlsruhe PALAS (2003) Model GFG-1000, aerosol generator instruction manual. PALAS® GmbH, Karlsruhe
Zurück zum Zitat Peters TM, Heitbrink WA, Evans DE, Slavin TJ, Maynard AD (2006) The mapping of fine and ultrafine particle number concentrations in an engine machining and assembly facility. Ann Occup Hyg 50:249–257CrossRef Peters TM, Heitbrink WA, Evans DE, Slavin TJ, Maynard AD (2006) The mapping of fine and ultrafine particle number concentrations in an engine machining and assembly facility. Ann Occup Hyg 50:249–257CrossRef
Zurück zum Zitat Romay FJ, Takagaki SS, Pui DYH, Liu BYH (1998) Thermophoretic deposition of aerosol particles in turbulent pipe flow. J Aerosol Sci 29:943–959CrossRef Romay FJ, Takagaki SS, Pui DYH, Liu BYH (1998) Thermophoretic deposition of aerosol particles in turbulent pipe flow. J Aerosol Sci 29:943–959CrossRef
Zurück zum Zitat Rubow KL, Marple VA, Olin J, McCawley MA (1987) A personal cascade impactor—design, evaluation and calibration. Am Ind Hyg Assoc J 48:532–538CrossRef Rubow KL, Marple VA, Olin J, McCawley MA (1987) A personal cascade impactor—design, evaluation and calibration. Am Ind Hyg Assoc J 48:532–538CrossRef
Zurück zum Zitat Sioutas C, Chang MC, Kim S, Koutrakis P, Ferguson ST (1999) Design and experimental characterization of a PM1 and a PM2.5 personal sampler. J Aerosol Sci 6:693–707CrossRef Sioutas C, Chang MC, Kim S, Koutrakis P, Ferguson ST (1999) Design and experimental characterization of a PM1 and a PM2.5 personal sampler. J Aerosol Sci 6:693–707CrossRef
Zurück zum Zitat Stratmann F, Otto E, Fissan H (1994) Thermophoretical and diffusional particle transport in cooled laminar tube flow. J Aerosol Sci 25:1305–1319CrossRef Stratmann F, Otto E, Fissan H (1994) Thermophoretical and diffusional particle transport in cooled laminar tube flow. J Aerosol Sci 25:1305–1319CrossRef
Zurück zum Zitat Talbot L, Cheng RK, Schefer RW, Willis (1980) Thermophoresis of particles in a heated boundary layer. J Fluid Mech 101(part 4):737–758CrossRef Talbot L, Cheng RK, Schefer RW, Willis (1980) Thermophoresis of particles in a heated boundary layer. J Fluid Mech 101(part 4):737–758CrossRef
Zurück zum Zitat Thayer D, Koehler KA, Marchese A, Volckens J (2011) A personal thermophoretic sampler for airborne nanoparticles. Aerosol Sci Technol 45:744–750CrossRef Thayer D, Koehler KA, Marchese A, Volckens J (2011) A personal thermophoretic sampler for airborne nanoparticles. Aerosol Sci Technol 45:744–750CrossRef
Zurück zum Zitat Tsai C-J, Lu H-C (1995) Design and evaluation of a plate-to-plate thermophoretic precipitator. Aerosol Sci Technol 22(2):172–180CrossRef Tsai C-J, Lu H-C (1995) Design and evaluation of a plate-to-plate thermophoretic precipitator. Aerosol Sci Technol 22(2):172–180CrossRef
Zurück zum Zitat Tsai C-J, Lin J-S, Aggarwal SG, Chen D-R (2004) Thermophoretic deposition of particles in laminar and turbulent flows. Aerosol Sci Technol 38:131–139CrossRef Tsai C-J, Lin J-S, Aggarwal SG, Chen D-R (2004) Thermophoretic deposition of particles in laminar and turbulent flows. Aerosol Sci Technol 38:131–139CrossRef
Zurück zum Zitat Tsai SJ, Ashter A, Ada E, Mead JL, Barry CF, Ellenbecker MJ (2008) Airborne nanoparticle release associated with the compounding of nanocomposites using nanoalumina as fillers. Aerosol Air Qual Res 8:160–177 Tsai SJ, Ashter A, Ada E, Mead JL, Barry CF, Ellenbecker MJ (2008) Airborne nanoparticle release associated with the compounding of nanocomposites using nanoalumina as fillers. Aerosol Air Qual Res 8:160–177
Zurück zum Zitat Tsai CJ, Liu CN, Hung SM, Chen SC, Uang SN, Cheng YS, Zhou Y (2012) Novel active personal nanoparticle sampler for the exposure assessment of nanoparticles in workplaces. Environ Sci Technol 46:4546–4552CrossRef Tsai CJ, Liu CN, Hung SM, Chen SC, Uang SN, Cheng YS, Zhou Y (2012) Novel active personal nanoparticle sampler for the exposure assessment of nanoparticles in workplaces. Environ Sci Technol 46:4546–4552CrossRef
Zurück zum Zitat TSI (2003) Model 3936, scanning mobility particle sizer (SMPS) instruction manual. TSI Inc., St. Paul TSI (2003) Model 3936, scanning mobility particle sizer (SMPS) instruction manual. TSI Inc., St. Paul
Zurück zum Zitat TSI (2007) Model 3776, condensation particle counter (CPC) instruction manual. TSI Inc., St. Paul TSI (2007) Model 3776, condensation particle counter (CPC) instruction manual. TSI Inc., St. Paul
Zurück zum Zitat TSI (2008) Model 3076, constant output atomizer instruction manual. TSI Inc., St. Paul TSI (2008) Model 3076, constant output atomizer instruction manual. TSI Inc., St. Paul
Zurück zum Zitat Tyndall J (1870) On dust and disease. Proc. R. Inst. 6:1–14 Tyndall J (1870) On dust and disease. Proc. R. Inst. 6:1–14
Zurück zum Zitat Viner AS, Lawless PA, Ensor DS, Sparks LE (1992) Ozone generation in DC-energized electrostatic precipitators. IEEE Trans Ind Appl 28:504–512CrossRef Viner AS, Lawless PA, Ensor DS, Sparks LE (1992) Ozone generation in DC-energized electrostatic precipitators. IEEE Trans Ind Appl 28:504–512CrossRef
Zurück zum Zitat Waldmann L, Schmitt KH (1966) Thermophoresis and diffusiophoresis of aerosol. In: Davis CN (ed) Aerosol science. Academic Press, London Waldmann L, Schmitt KH (1966) Thermophoresis and diffusiophoresis of aerosol. In: Davis CN (ed) Aerosol science. Academic Press, London
Zurück zum Zitat Wang SC, Flagan RC (1990) Scanning electrical mobility spectrometer. Aerosol Sci Technol 13:230–240CrossRef Wang SC, Flagan RC (1990) Scanning electrical mobility spectrometer. Aerosol Sci Technol 13:230–240CrossRef
Zurück zum Zitat Wang B, Ou Q, Tao S, Chen D-R (2012) Performance study of a disk-to-disk thermal precipitator. J Aerosol Sci 52:45–56CrossRef Wang B, Ou Q, Tao S, Chen D-R (2012) Performance study of a disk-to-disk thermal precipitator. J Aerosol Sci 52:45–56CrossRef
Zurück zum Zitat Watson HH (1937) Trans Inst Min Metall 46:155 Watson HH (1937) Trans Inst Min Metall 46:155
Zurück zum Zitat Wright BW (1953) Gravimetric thermal precipitator. Sci, New Ser 118(3059):195 Wright BW (1953) Gravimetric thermal precipitator. Sci, New Ser 118(3059):195
Zurück zum Zitat Wu Y-H, Vincent J (2007) A modified Marple-type cascade impactor for assessing aerosol particle size distributions in workplaces. J Occup Environ Hyg 4(10):798–807CrossRef Wu Y-H, Vincent J (2007) A modified Marple-type cascade impactor for assessing aerosol particle size distributions in workplaces. J Occup Environ Hyg 4(10):798–807CrossRef
Zurück zum Zitat Zheng F (2002) Thermophoresis of spherical and non-spherical particles: a review of theories and experiments. Adv Colloid Interface 97:255–278CrossRef Zheng F (2002) Thermophoresis of spherical and non-spherical particles: a review of theories and experiments. Adv Colloid Interface 97:255–278CrossRef
Metadaten
Titel
Design and experimental evaluation of a new nanoparticle thermophoretic personal sampler
verfasst von
Nkwenti Azong-Wara
Christof Asbach
Burkhard Stahlmecke
Heinz Fissan
Heinz Kaminski
Sabine Plitzko
Dieter Bathen
Thomas A. J. Kuhlbusch
Publikationsdatum
01.04.2013
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 4/2013
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-013-1530-8

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