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Biomass Conversion and Biorefinery
Erschienen in: Biomass Conversion and Biorefinery 6/2021

11.02.2020 | Original Article

Designing a novel N-doped adsorbent with ultrahigh selectivity for CO2: waste biomass pyrolysis and two-step activation

verfasst von: Zhixiu Yang, Guojie Zhang, Xiaofei Guo, Ying Xu

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 6/2021

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Abstract

In the research, N-doped cost-effective carbon dioxide adsorbents with ultrahigh selectivity are prepared using waste walnut shell pyrolysis by two-step activation and urea modification. The carbonaceous adsorbent exhibits excellent pore structure due to the catalytic degradation of H3PO4 and the etching action of KOH. The optimized sample, HAC-850-1.5, shows high CO2 adsorption 5.13 mmol/g at 0 °C. The study also indicates that nitrogen content, Vm/Vt, and porous texture characteristics play indispensable parts in impacting the CO2 adsorption of these prepared N-doped porous materials under atmospheric pressure. Furthermore, prepared carbonaceous adsorbents possess other superiorities including reasonable Qst and good recyclability and stability. It should not be overlooked that the adsorbent has a selectivity of more than 800 for CO2/N2 at low pressure, which is highly promising in CO2 adsorption through flue gas when contrasted with diverse solid adsorbents.
Vorheriger Artikel Torrefaction of biomass pellets using the thermogravimetric analyser
Nächster Artikel Kinetics and physical analyses for pyrolyzed Egyptian agricultural and woody biomasses: effect of microwave drying

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Metadaten
Titel
Designing a novel N-doped adsorbent with ultrahigh selectivity for CO2: waste biomass pyrolysis and two-step activation
verfasst von
Zhixiu Yang
Guojie Zhang
Xiaofei Guo
Ying Xu
Publikationsdatum
11.02.2020
Verlag
Springer Berlin Heidelberg
Erschienen in
Biomass Conversion and Biorefinery / Ausgabe 6/2021
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI
https://doi.org/10.1007/s13399-020-00633-0

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