nach oben

Polymer Bulletin

Erschienen in:

16.12.2019 | Original Paper

Dielectric properties of natural rubber/polyethylene oxide block copolymer complexed with transition metal ions

verfasst von: M. S. Mrudula, M. R. Gopinathan Nair

Erschienen in: Polymer Bulletin | Ausgabe 11/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Transition metal ion complexes of natural rubber/polyethylene oxide block copolymer (NR/PEO block copolymer, BC) are prepared by the process of adsorption in aqueous solutions and subjected to electrical analysis and XRD studies. AC conductance, impedance, dielectric relaxation and modulus have been measured as a function of frequency. The conductivity shows a linear relation with frequency. Among the complexes studied, BC–Co(II) shows the highest conductivity, while BC–Cu(II) shows the lowest value which may be due to different coordination pattern adopted. The Nyquist plot of impedance shows that except BC and BC–Cu(II), other samples give single skewed semicircles, while the former two yield arc bending towards the abscissa. The relaxation studies indicate electrode polarisation effect at lower frequencies and ion migration at higher frequencies. Argand plot indicates the presence of viscoelastic relaxation, and a distribution of relaxation time occurs in all the samples. XRD results support the electrical properties observed for the BC and the complexes.

Vorheriger Artikel Synthesis by plasma of potentially biodegradable oxidized polyethylene obtained from ethanol

Nächster Artikel Preparation and characterization of aliphatic polyurethane and modified hydroxyapatite composites for bone tissue engineering

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Kumar JS, Subrahmanyam AR, Reddy MJ, Rao UVS (2006) Preparation and study of properties of polymer electrolyte system (PEO+NaClO₃). Mater Lett 60:3346–3349. https://doi.org/10.1016/j.matlet.2006.03.015CrossRef

Ahmad A, Saqan S, Ramadin Y, Zihlif A (2006) The thermoelectrical behaviour of PEO films doped with MnCl₂ salt. J Thermoplast Compos Mater 19:531–544. https://doi.org/10.1177/0892705706063926CrossRef

Dygas JR, Misztal-Faraj B, Florjanczyk Z et al (2003) Effects of inhomogeneity on ionic conductivity and relaxations in PEO and PEO–salt complexes. Solid State Ion 157:249–256. https://doi.org/10.1016/S0167-2738(02)00217-5CrossRef

Biryan F, Tuncer H, Demirelli K (2019) Electrical, thermal behaviors and synthesis of intramolecular cobalt phthalocyanine with single-chain polymer structure. Polym Bull. https://doi.org/10.1007/s00289-019-02871-3CrossRef

Basha SKS, Sundari GS, Kumar KV, Rao MC (2018) Preparation and dielectric properties of PVP-based polymer electrolyte films for solid-state battery application. Polym Bull 75:925–945. https://doi.org/10.1007/s00289-017-2072-5CrossRef

Kumar KN, Saijyothi K, Vijayalakshmi L, Kang M (2017) Copper—constantan nanoparticles impregnated PEO + PVP : Li+ blended solid polymer electrolyte films for lithium battery applications. Polym Bull 74:2545–2564. https://doi.org/10.1007/s00289-016-1849-2CrossRef

Saqan SA, Ayesh AS, Zihlif AM et al (2004) Physical properties of polystyrene / alum composites. Polym Test 23:739–745. https://doi.org/10.1016/j.polymertesting.2004.04.008CrossRef

Singh PK, Chandra A (2003) Role of the dielectric constant of ferroelectric ceramic in enhancing the ionic conductivity of a polymer electrolyte composite. J Phys D Appl Phys 36:L93–L96. https://doi.org/10.1088/0022-3727/36/19/L01CrossRef

Vincent CA (1987) Polymer electrolytes. Prog Solid St Chem 17:145–261. https://doi.org/10.1016/0079-6786(87)90003-3CrossRef

10.

Armand M (1983) Polymer solid electrolytes—an overview. Solid State Ion 9 & 10:745–754. https://doi.org/10.1016/0167-2738(83)90083-8CrossRef

11.

Berthier C, Gorecki W, Minier M et al (1983) Microscopic investigation of ionic conductivity in alkali metal salts-poly(ethylene oxide) adducts. Solid State Ion 11:91–95. https://doi.org/10.1016/0167-2738(83)90068-1CrossRef

12.

Ramesh S, Yuen TF, Shen CJ (2008) Conductivity and FTIR studies on PEO-LiX [X: CF₃SO₃^-, SO₄²⁻] polymer electrolytes. Spectrochim Acta Part A 69:670–675. https://doi.org/10.1016/j.saa.2007.05.029CrossRef

13.

Karan NK, Pradhan DK, Thomas R et al (2008) Solid polymer electrolytes based on polyethylene oxide and lithium trifluoro- methane sulfonate (PEO-LiCF₃SO₃): Ionic conductivity and dielectric relaxation. Solid State Ion 179:689–696. https://doi.org/10.1016/j.ssi.2008.04.034CrossRef

14.

Fanggao C, Saunders GA, Lambson EF et al (1996) Temperature and frequency dependencies of the complex dielectric constant of poly(ethylene oxide) under hydrostatic pressure. J Polym Sci Part B Polym Phys 34:425–433. https://doi.org/10.1002/(SICI)1099-0488(199602)34:3%3c425:AID-POLB3%3e3.0.CO;2-SCrossRef

15.

Pandey GP, Kumar Y, Hashmi SA (2011) Ionic liquid incorporated PEO based polymer electrolyte for electrical double layer capacitors: a comparative study with lithium and magnesium systems. Solid State Ion 190:93–98. https://doi.org/10.1016/j.ssi.2011.03.018CrossRef

16.

Michael MS, Jacob MME, Prabaharan SRS, Radhakrishna S (1997) Enhanced lithium ion transport in PEO-based solid polymer electrolytes employing a novel class of plasticizers. Solid State Ion 98:167–174. https://doi.org/10.1016/S0167-2738(97)00117-3CrossRef

17.

Murugendrappa MV, Khasim S, Ambika Prasad MVN (2000) Conductivity and DSC studies of poly(ethylene glycol) and its salt complexes. Indian J Eng Mater Sci 7:456–458

18.

Sreekanth T, Jaipal Reddy M, Subramanyam S, Subba Rao UV (1999) Ion conducting polymer electrolyte films based on (PEO+KNO₃) system and its application as an electrochemical cell. Mater Sci Eng B 64:107–112. https://doi.org/10.1016/S0921-5107(99)00147-6CrossRef

19.

Ayesh AS (2009) Dielectric properties of polyethylene oxide doped with NH₄I Salt. Polym J 41:616–621. https://doi.org/10.1295/polymj.PJ2009047CrossRef

20.

Glasse MD, Idris R, Latham RJ et al (2002) Polymer electrolytes based on modified natural rubber. Solid State Ion 147:289–294CrossRef

21.

Nair RC, Gopakumar S, Nair MRG (2007) Synthesis and characterization of block copolymers based on natural rubber and polypropylene oxide. J Appl Polym Sci 103:955–962. https://doi.org/10.1002/appCrossRef

22.

Mrudula MS, Tiwari N, Jha SN et al (2019) Structural studies on transition metal ion complexes of polyethylene oxide-natural rubber block copolymers. J Polym Res 26:1–16. https://doi.org/10.1007/s10965-019-1837-yCrossRef

23.

Tripathi SK, Gupta A, Kumari M (2012) Studies on electrical conductivity and dielectric behaviour of PVdF–HFP–PMMA–NaI polymer blend electrolyte. Bull MaterSci 35:969–975. https://doi.org/10.1007/s12034-012-0387-2CrossRef

24.

Mohomed K, Gerasimov TG, Moussy F, Harmon JP (2005) A broad spectrum analysis of the dielectric properties of poly(2-hydroxyethyl methacrylate). Polymer 46:3847–3855. https://doi.org/10.1016/j.polymer.2005.02.100CrossRef

25.

Sambhudevan S, Shankar B, Saritha A et al (2017) Development of X-ray protective garments from rare earth-modified natural rubber composites. J Elastomers Plast 49:527–544. https://doi.org/10.1177/0095244316676866CrossRef

26.

Johns J, Rao V (2009) Thermal stability, morphology, and X-ray diffraction studies of dynamically vulcanized natural rubber/chitosan blends. J Mater Sci 44:4087–4094. https://doi.org/10.1007/s10853-009-3589-2CrossRef

27.

Bhat NV, Deshmukh RR (2002) X-ray crystallographic studies of polymeric materials. Indian J Pure Appl Phys 40:361–366

28.

Yu LQ, Zheng LJ, Yang JX (2000) Study of preparation and properties on magnetization and stability for ferromagnetic fluids. Mater Chem Phys 66:6–9. https://doi.org/10.1016/S0254-0584(00)00236-4CrossRef

29.

Sundaramahalingam K, Vanitha D, Nallamuthu N et al (2019) Electrical properties of lithium bromide poly ethylene oxide/poly vinyl pyrrolidone polymer blend electrolyte. Phys B Condens Matter 553:120–126. https://doi.org/10.1016/j.physb.2018.10.040CrossRef

30.

Yoshizawa M, Marwanta E, Ohno H (2000) Preparation and characteristics of natural rubber/poly(ethylene oxide) salt hybrid mixtures as novel polymer electrolytes. Polymer 41:9049–9053. https://doi.org/10.1016/S0032-3861(00)00277-9CrossRef

31.

Abdullah A, Abdullah SZ, Ali AMM et al (2009) Electrical properties of PEO–LiCF₃SO₃–SiO₂ nanocomposite polymer electrolytes. Mater Res Innov 13:255–258. https://doi.org/10.1179/143307509X440451CrossRef

32.

Noor SAM, Ahmad A, Talib IA, Rahman MYA (2010) Morphology, chemical interaction, and conductivity of a PEO-ENR50 based on solid polymer electrolyte. Ionics 16:161–170. https://doi.org/10.1007/s11581-009-0385-6CrossRef

33.

Ma Q, Liu J, Qi X et al (2017) New Na[(FSO₂)(n-C₄F₉SO₂)N]-based polymer electrolyte for solid-state sodium batteries. J Mater Chem A 5:7738–7743. https://doi.org/10.1039/C7TA01820GCrossRef

Titel: Dielectric properties of natural rubber/polyethylene oxide block copolymer complexed with transition metal ions
verfasst von: M. S. Mrudula
M. R. Gopinathan Nair
Publikationsdatum: 16.12.2019
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 11/2020
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-019-03035-z

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 11/2020

Adsorptive abatement of ciprofloxacin using NiFe2O4 nanoparticles incorporated into G. ghatti-cl-P(AAm) nanocomposites hydrogel: isotherm, kinetic, and thermodynamic studies

Synthesis and properties of degradable gels and porous polymers including acetal group in the network structure by addition reaction of multi-functional phenols and divinyl ether compounds

Fabrication of trichlorovinylsilane-modified-chitosan film with enhanced solubility and antibacterial activity

Effect of organoclay content on mechanical and rheological properties of dynamically cross-linked acrylonitrile-butadiene rubber/poly(ethylene-co-vinyl acetate)/organoclay nanocomposites

Cross-linked poly(vinyl alcohol) nanofibers as drug carrier of clindamycin

Preparation and characterization of aliphatic polyurethane and modified hydroxyapatite composites for bone tissue engineering

Premium Partner

Marktübersichten