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Erschienen in: Journal of Materials Engineering and Performance 5/2020

19.05.2020

Effect of Chloride Concentration on Stress Corrosion Behavior and Mechanism of SA516Gr70N Steel in Alkaline NaCl/Na2S Solution

verfasst von: Baijie Zhao, Yi Fan, Bo Zhao, Hao Li, Hongchi Ma, Shiqi Wang

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 5/2020

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Abstract

The effects of chloride on the electrochemical process and susceptibility to stress corrosion cracking (SCC) of SA516Gr70N steel in alkaline NaCl/Na2S solution were investigated by using electrochemical techniques (impedance spectroscopy and polarization curve measurement) and slow strain rate tensile (SSRT) tests. SA516Gr70N steel exhibited SCC susceptibility to a certain extent in alkaline NaCl/Na2S solution. The susceptibility to SCC decreased with increasing chloride concentrations in solutions with pH values of 9 and 11, while susceptibility was not apparent in higher pH solutions. Electrochemical analysis showed that the corrosion potential became more negative, and the anodic corrosion rate decreased with increasing chloride concentration due to the competitive adsorption of HS and Cl. The mechanism of SCC is mainly controlled by anodic dissolution with the addition of chloride.

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Metadaten
Titel
Effect of Chloride Concentration on Stress Corrosion Behavior and Mechanism of SA516Gr70N Steel in Alkaline NaCl/Na2S Solution
verfasst von
Baijie Zhao
Yi Fan
Bo Zhao
Hao Li
Hongchi Ma
Shiqi Wang
Publikationsdatum
19.05.2020
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 5/2020
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-020-04849-z

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