Skip to main content
Erschienen in: Journal of Materials Engineering and Performance 7/2016

31.05.2016

Effect of Minor Zn Additions on the Mechanical and Corrosion Properties of Solution-Treated AM60-2%RE Magnesium Alloy

verfasst von: Z. L. Liu, Y. Liu, X. Q. Liu, M. M. Wang

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 7/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The microstructure, mechanical properties, and corrosion behaviors of solution-treated AM60-2%RE magnesium alloy containing 0.2-0.8% wt.% Zn were investigated. With the increase of Zn, the volume fraction of dispersed rod-like Al4RE and granular-like Al11RE3 phases of solution-treated AM60-2%RE + x%Zn increased, which improved the mechanical properties by dispersion strengthening. With increasing Zn content, the corrosion current density decreased, and the corrosion potential and electrochemical impedance of the alloys increased, and the corrosion resistance of solution-treated AM60-2%RE + x%Zn was improved. With the increase of Zn content, the leaf-like corrosion products of the alloy became smaller and more compact, and the content of Zn, Al, Ce, and La in corrosion products increased, which was beneficial to inhibit the corrosion progress.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat M.E. Moussa, M.A. Waly, and A.M. El-Sheikh, Combined Effect of High-Intensity Ultrasonic Treatment and Ca Addition on Modification of Primary Mg2Si and Wear Resistance in Hypereutectic Mg-Si Alloys, J. Alloys Comp, 2014, 615, p 576–581CrossRef M.E. Moussa, M.A. Waly, and A.M. El-Sheikh, Combined Effect of High-Intensity Ultrasonic Treatment and Ca Addition on Modification of Primary Mg2Si and Wear Resistance in Hypereutectic Mg-Si Alloys, J. Alloys Comp, 2014, 615, p 576–581CrossRef
2.
Zurück zum Zitat H. Zhang, G.S. Huang, L.F. Wang, H.J. Roven, and F.S. Pan, Enhanced Mechanical Properties of AZ31 Magnesium Alloy Sheets Processed by Three-Directional Rolling, J. Alloys Comp, 2013, 575, p 408–413CrossRef H. Zhang, G.S. Huang, L.F. Wang, H.J. Roven, and F.S. Pan, Enhanced Mechanical Properties of AZ31 Magnesium Alloy Sheets Processed by Three-Directional Rolling, J. Alloys Comp, 2013, 575, p 408–413CrossRef
3.
Zurück zum Zitat Z.Y. Cui, X.G. Li, K. Xiao, C.F. Dong, Z.Y. Liu, and L.W. Wang, Pitting Corrosion Behaviour of AZ31 Magnesium in Tropical Marine Atmosphere, Corros Eng. Sci and Technol, 2014, 49, p 363–371CrossRef Z.Y. Cui, X.G. Li, K. Xiao, C.F. Dong, Z.Y. Liu, and L.W. Wang, Pitting Corrosion Behaviour of AZ31 Magnesium in Tropical Marine Atmosphere, Corros Eng. Sci and Technol, 2014, 49, p 363–371CrossRef
4.
Zurück zum Zitat J.H. Zhang, M.L. Zhang, J. Meng, and R.Z. Wu, D and X. Tang: ‘Microstructures and Mechanical Properties of Heat-Resistant High-Pressure Die-Cast Mg-4Al-xLa-0.3Mn (x = 1, 2, 4, 6) Alloys’, Mater. Sci. Eng., A, 2010, 527, p 2527–2537CrossRef J.H. Zhang, M.L. Zhang, J. Meng, and R.Z. Wu, D and X. Tang: ‘Microstructures and Mechanical Properties of Heat-Resistant High-Pressure Die-Cast Mg-4Al-xLa-0.3Mn (x = 1, 2, 4, 6) Alloys’, Mater. Sci. Eng., A, 2010, 527, p 2527–2537CrossRef
5.
Zurück zum Zitat J.H. Zhang, P. Yu, K. Liu, D.Q. Fang, D.X. Tang, and J. Meng, Effect of Substituting Cerium-Rich Mischmetal with Lanthanum on Microstructure and Mechanical Properties of Die-Cast Mg-Al-RE Alloys, Mater. Des., 2009, 30, p 2372–2378CrossRef J.H. Zhang, P. Yu, K. Liu, D.Q. Fang, D.X. Tang, and J. Meng, Effect of Substituting Cerium-Rich Mischmetal with Lanthanum on Microstructure and Mechanical Properties of Die-Cast Mg-Al-RE Alloys, Mater. Des., 2009, 30, p 2372–2378CrossRef
6.
Zurück zum Zitat F. Mert, A. Özdemir, K.U. Kainer, and N. Hort, Influence of Ce Addition on Microstructure and Mechanical Properties of High Pressure Die Cast AM50 Magnesium Alloy, Trans. Nonferrous Met. Soc. China, 2013, 23, p 66–72CrossRef F. Mert, A. Özdemir, K.U. Kainer, and N. Hort, Influence of Ce Addition on Microstructure and Mechanical Properties of High Pressure Die Cast AM50 Magnesium Alloy, Trans. Nonferrous Met. Soc. China, 2013, 23, p 66–72CrossRef
7.
Zurück zum Zitat T. Takenaka, T. Ono, Y. Narazaki, Y. Narazaki, Y. Naka, and M. Kawakami, Improvement of Corrosion Resistance of Magnesium Metal By Rare Earth Elements, Electrochim. Acta, 2007, 53, p 117–121CrossRef T. Takenaka, T. Ono, Y. Narazaki, Y. Narazaki, Y. Naka, and M. Kawakami, Improvement of Corrosion Resistance of Magnesium Metal By Rare Earth Elements, Electrochim. Acta, 2007, 53, p 117–121CrossRef
8.
Zurück zum Zitat R. Arrabal, B. Mingo, A. Pardo, E. Matykina, M. Mohedano, M.C. Merino, and A. Maroto, Role of Alloyed Nd in the Microstructure and Atmospheric Corrosion of As-Cast Magnesium Alloy AZ91, Corros. Sci., 2015, 97, p 38–48CrossRef R. Arrabal, B. Mingo, A. Pardo, E. Matykina, M. Mohedano, M.C. Merino, and A. Maroto, Role of Alloyed Nd in the Microstructure and Atmospheric Corrosion of As-Cast Magnesium Alloy AZ91, Corros. Sci., 2015, 97, p 38–48CrossRef
9.
Zurück zum Zitat D.P. Jang and Z.X. Yao, Effects of Zn Addition and Heat Treatment on the Structure and Mechanical Property of AM Magnesium Alloy, J. Chongqing Uni. Tech. (Nat. Sci. Ed), 2011, 13, p 127-130. (in Chinese) D.P. Jang and Z.X. Yao, Effects of Zn Addition and Heat Treatment on the Structure and Mechanical Property of AM Magnesium Alloy, J. Chongqing Uni. Tech. (Nat. Sci. Ed), 2011, 13, p 127-130. (in Chinese)
10.
Zurück zum Zitat Y.S. Wang, Q.D. Wang, C.J. Ma, W.J. Ding, and Y.P. Zhu, Effects of Zn and RE Additions on the Solidification Behavior of Mg-9Al Magnesium Alloy, Mater. Sci. Eng., A, 2003, 342, p 178–182CrossRef Y.S. Wang, Q.D. Wang, C.J. Ma, W.J. Ding, and Y.P. Zhu, Effects of Zn and RE Additions on the Solidification Behavior of Mg-9Al Magnesium Alloy, Mater. Sci. Eng., A, 2003, 342, p 178–182CrossRef
11.
Zurück zum Zitat F. Wang, Z. Liu, L.J. Chen, B.Y. Yu, and L. Lin, Mechanical Properties and Microstructures of Hot Extruded AE42 Alloy with Addition of Zinc, Trans. Nonferrous Met. Soc. China, 2006, 16, p 1762–1765 F. Wang, Z. Liu, L.J. Chen, B.Y. Yu, and L. Lin, Mechanical Properties and Microstructures of Hot Extruded AE42 Alloy with Addition of Zinc, Trans. Nonferrous Met. Soc. China, 2006, 16, p 1762–1765
12.
Zurück zum Zitat A.A. Luo and A.K. Sachdev, Development of a New Wrought Magnesium-Aluminum-Manganese Alloy AM30, Metal. Mater. Trans. A, 2007, 38, p 1184–1192CrossRef A.A. Luo and A.K. Sachdev, Development of a New Wrought Magnesium-Aluminum-Manganese Alloy AM30, Metal. Mater. Trans. A, 2007, 38, p 1184–1192CrossRef
13.
Zurück zum Zitat L. Cao, W.C. Liu, Z.Q. Li, G.H. Wu, L. Xiao, S.H. Wang, and W.J. Ding, Effect of Heat Treatment on Microstructures and Mechanical Properties of Sand-Cast Mg-10Gd-3Y-0.5Zr Magnesium Alloy, Trans. Nonferrous Met. Soc. China, 2014, 24, p 611–618CrossRef L. Cao, W.C. Liu, Z.Q. Li, G.H. Wu, L. Xiao, S.H. Wang, and W.J. Ding, Effect of Heat Treatment on Microstructures and Mechanical Properties of Sand-Cast Mg-10Gd-3Y-0.5Zr Magnesium Alloy, Trans. Nonferrous Met. Soc. China, 2014, 24, p 611–618CrossRef
14.
Zurück zum Zitat X.F. Zhao, S.B. Li, Q.F. Wang, W.B. Du, and K. Liu, Effect of Heat Treatment on Microstructure and Mechanical Properties of Mg-5Zn-0.63Er Alloy, Trans. Nonferrous Met. Soc. China, 2013, 23, p 59–65CrossRef X.F. Zhao, S.B. Li, Q.F. Wang, W.B. Du, and K. Liu, Effect of Heat Treatment on Microstructure and Mechanical Properties of Mg-5Zn-0.63Er Alloy, Trans. Nonferrous Met. Soc. China, 2013, 23, p 59–65CrossRef
15.
Zurück zum Zitat Y. Gang, “Effect of Ca solidification behavior of Mg-Al-RE system heat-resistant magnesium alloys,” Master thesis, Xi Hua University, 2013. (in Chinese) Y. Gang, “Effect of Ca solidification behavior of Mg-Al-RE system heat-resistant magnesium alloys,” Master thesis, Xi Hua University, 2013. (in Chinese)
16.
Zurück zum Zitat N. Pourkia, M. Emamy, H. Farhangi, and S.H. Seyed Ebrahimi, The Effect of Ti and Zr Elements and Cooling Rate on the Microstructure and Tensile Properties of a New Developed Super High-Strength Aluminum Alloy, Mater. Sci. Eng., A, 2010, 527, p 5318–5325CrossRef N. Pourkia, M. Emamy, H. Farhangi, and S.H. Seyed Ebrahimi, The Effect of Ti and Zr Elements and Cooling Rate on the Microstructure and Tensile Properties of a New Developed Super High-Strength Aluminum Alloy, Mater. Sci. Eng., A, 2010, 527, p 5318–5325CrossRef
17.
Zurück zum Zitat H.J. Liao, X.F. Zhou, H.Z. Li, M. Deng, X.P. Xiao, and R.M. Liu, Effect of Aging Time on Corrosion Behavior of As-Forged AZ80 Magnesium Alloy, Trans. Nonferrous Met. Soc. China, 2015, 25, p 3921–3927CrossRef H.J. Liao, X.F. Zhou, H.Z. Li, M. Deng, X.P. Xiao, and R.M. Liu, Effect of Aging Time on Corrosion Behavior of As-Forged AZ80 Magnesium Alloy, Trans. Nonferrous Met. Soc. China, 2015, 25, p 3921–3927CrossRef
18.
Zurück zum Zitat Y.D. Huang, H. Dieringa, N. Hort, P. Maier, K.U. Kainer, and Y.L. Liu, Evolution of Microstructure and Hardness of AE42 Alloy After Heat Treatments, J. Alloys Comp, 2008, 463, p 238–245CrossRef Y.D. Huang, H. Dieringa, N. Hort, P. Maier, K.U. Kainer, and Y.L. Liu, Evolution of Microstructure and Hardness of AE42 Alloy After Heat Treatments, J. Alloys Comp, 2008, 463, p 238–245CrossRef
19.
Zurück zum Zitat S.X. Zhang, Y.P. Zhu, and G.Y. Cai, Influence of Overburning on Microstructure and Property of 2024 Aluminum Alloy, Adv. Mater. Res., 2014, 941, p 3–7 S.X. Zhang, Y.P. Zhu, and G.Y. Cai, Influence of Overburning on Microstructure and Property of 2024 Aluminum Alloy, Adv. Mater. Res., 2014, 941, p 3–7
20.
Zurück zum Zitat C.J. Wang, B.L. Jiang, M. Liu, and Y.F. Ge, Corrosion Characterization of Micro-Arc Oxidization Composite Electrophoretic Coating on AZ31B Magnesium Alloy, J. Alloys Comp, 2015, 621, p 53–61CrossRef C.J. Wang, B.L. Jiang, M. Liu, and Y.F. Ge, Corrosion Characterization of Micro-Arc Oxidization Composite Electrophoretic Coating on AZ31B Magnesium Alloy, J. Alloys Comp, 2015, 621, p 53–61CrossRef
21.
Zurück zum Zitat Z. Shi, M. Liu, and A. Atrens, Measurement of the Corrosion Rate of Magnesium Alloys Using Tafel Extrapolation, Corros. Sci., 2010, 52, p 579–588CrossRef Z. Shi, M. Liu, and A. Atrens, Measurement of the Corrosion Rate of Magnesium Alloys Using Tafel Extrapolation, Corros. Sci., 2010, 52, p 579–588CrossRef
22.
Zurück zum Zitat Z. Shi and A. Atrens, An Innovative Specimen Configuration for the Study of Mg Corrosion, Corros. Sci., 2011, 53, p 226–246CrossRef Z. Shi and A. Atrens, An Innovative Specimen Configuration for the Study of Mg Corrosion, Corros. Sci., 2011, 53, p 226–246CrossRef
23.
Zurück zum Zitat J.W. Zhang, S.B. Wang, J.Y. Zhang, J.L. Zhang, and B.S. Xu, Effects of Nd on Microstructures and Mechanical Properties of AM60 Magnesium Alloy in Vacuum Melting, Rare. Met. Mater. Eng, 2009, 38, p 1141–1145CrossRef J.W. Zhang, S.B. Wang, J.Y. Zhang, J.L. Zhang, and B.S. Xu, Effects of Nd on Microstructures and Mechanical Properties of AM60 Magnesium Alloy in Vacuum Melting, Rare. Met. Mater. Eng, 2009, 38, p 1141–1145CrossRef
24.
Zurück zum Zitat Y. Song, D.Y. Shan, R.S. Chen, and E.H. Han, Corrosion Characterization of Mg-8Li Alloy in NaCl Solution, Corros. Sci., 2009, 51, p 1087–1094CrossRef Y. Song, D.Y. Shan, R.S. Chen, and E.H. Han, Corrosion Characterization of Mg-8Li Alloy in NaCl Solution, Corros. Sci., 2009, 51, p 1087–1094CrossRef
25.
Zurück zum Zitat G.M. Abady, N.H. Hilal, M. El-Rabiee, and W.A. Badawy, Effect of Al Content on the Corrosion Behavior of Mg-Al Alloys in Aqueous Solutions of Different pH, Electrochim. Acta, 2010, 55, p 6651–6658CrossRef G.M. Abady, N.H. Hilal, M. El-Rabiee, and W.A. Badawy, Effect of Al Content on the Corrosion Behavior of Mg-Al Alloys in Aqueous Solutions of Different pH, Electrochim. Acta, 2010, 55, p 6651–6658CrossRef
26.
Zurück zum Zitat Z.L. Liu, G.B. Zhou, X.Q. Liu, and J. Li, Effects of Sb Addition on Corrosion Resistance of AM50-Y Magnesium Alloy, Chin. J. Mater. Res, 2011, 25, p 527–533 (in Chinese) Z.L. Liu, G.B. Zhou, X.Q. Liu, and J. Li, Effects of Sb Addition on Corrosion Resistance of AM50-Y Magnesium Alloy, Chin. J. Mater. Res, 2011, 25, p 527–533 (in Chinese)
27.
Zurück zum Zitat L. Hang, The Influence of Aluminum and Rare Earth Elements on the Corrosion Resistance of Magnesium Alloys in Sodium Chloride Solution, The Chinese Academy of Sciences, Shanghai Institute of Metallurgy, Shang hai, 2001 (in Chinese) L. Hang, The Influence of Aluminum and Rare Earth Elements on the Corrosion Resistance of Magnesium Alloys in Sodium Chloride Solution, The Chinese Academy of Sciences, Shanghai Institute of Metallurgy, Shang hai, 2001 (in Chinese)
28.
Zurück zum Zitat M.C. Zhao, M. Liu, G.L. Song, and A. Atrens, Influence of the β-Phase Morphology on the Corrosion of the Mg Alloy AZ91, Corros. Sci., 2008, 50, p 1939–1953CrossRef M.C. Zhao, M. Liu, G.L. Song, and A. Atrens, Influence of the β-Phase Morphology on the Corrosion of the Mg Alloy AZ91, Corros. Sci., 2008, 50, p 1939–1953CrossRef
29.
Zurück zum Zitat D.S. Yin, E.L. Zhang, and S.Y. Zhang, Effect of Zn on Mechanical Property and Corrosion Property of Extruded Mg-Zn-Mn Alloy, Trans. Nonferrous Met. Soc. China, 2008, 18, p 763–768CrossRef D.S. Yin, E.L. Zhang, and S.Y. Zhang, Effect of Zn on Mechanical Property and Corrosion Property of Extruded Mg-Zn-Mn Alloy, Trans. Nonferrous Met. Soc. China, 2008, 18, p 763–768CrossRef
30.
Zurück zum Zitat I. Popov, D. Starosvetsky, and D. Shechtman, Initial Stages of Corrosion Within Mg-Zn-Y-Zr alloy in 1 g/l NaCl Solution, J. Mater. Sci., 2000, 35, p 1–8CrossRef I. Popov, D. Starosvetsky, and D. Shechtman, Initial Stages of Corrosion Within Mg-Zn-Y-Zr alloy in 1 g/l NaCl Solution, J. Mater. Sci., 2000, 35, p 1–8CrossRef
31.
Zurück zum Zitat G. Song and A. Atrens, Understanding Magnesium Corrosion, Adv. Eng. Mater., 2003, 5, p 837–858CrossRef G. Song and A. Atrens, Understanding Magnesium Corrosion, Adv. Eng. Mater., 2003, 5, p 837–858CrossRef
32.
Zurück zum Zitat W.J. Liu, F.H. Cao, L.R. Chang, Z. Zhang, and J.Q. Zhang, Effect of Rare Earth Element Ce and La on Corrosion Behavior of AM60 Magnesium Alloy, Corros. Sci., 2009, 51, p 1334–1343CrossRef W.J. Liu, F.H. Cao, L.R. Chang, Z. Zhang, and J.Q. Zhang, Effect of Rare Earth Element Ce and La on Corrosion Behavior of AM60 Magnesium Alloy, Corros. Sci., 2009, 51, p 1334–1343CrossRef
Metadaten
Titel
Effect of Minor Zn Additions on the Mechanical and Corrosion Properties of Solution-Treated AM60-2%RE Magnesium Alloy
verfasst von
Z. L. Liu
Y. Liu
X. Q. Liu
M. M. Wang
Publikationsdatum
31.05.2016
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 7/2016
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-016-2077-5

Weitere Artikel der Ausgabe 7/2016

Journal of Materials Engineering and Performance 7/2016 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.