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Erschienen in: Journal of Materials Engineering and Performance 2/2021

08.01.2021

Effect of Potential on the Characteristics of Passive Film on a CoCrFeMnNi High-Entropy Alloy in Carbonate/Bicarbonate Solution

verfasst von: M. Zhu, Q. Zhang, B. Z. Zhao, Y. F. Yuan, S. Y. Guo

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 2/2021

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Abstract

Effect of passive potential on the protective capacity of passive film formed on CoCrFeMnNi high-entropy alloy was investigated in carbonate/bicarbonate solution by using electrochemical measurements, atomic force microscopy and x-ray photoelectron spectroscopy (XPS). The results reveal that the protective ability of passive film is sensitive to the applied potential, and the anti-corrosion property of passive film at high potential is significantly enhanced as indicated by the high film resistance and the low donor densities. The Cr2O3 content and the ratios of Mn/Mnox as well as O2−/OH in the secondary passive film are greater than those in the primary passive film. Moreover, increasing the potential facilitates the formation of a homogeneous and thick passive film, which considerably improves the protective ability of the film.

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Metadaten
Titel
Effect of Potential on the Characteristics of Passive Film on a CoCrFeMnNi High-Entropy Alloy in Carbonate/Bicarbonate Solution
verfasst von
M. Zhu
Q. Zhang
B. Z. Zhao
Y. F. Yuan
S. Y. Guo
Publikationsdatum
08.01.2021
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 2/2021
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-020-05361-0

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