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Polymer Bulletin
Erschienen in: Polymer Bulletin 6/2019

27.09.2018 | Original Paper

Electrochemical supercapacitors of PANI/MWCNT, PEDOT/MWCNT and P(ANI-co-EDOT)/MWCNT nanocomposites

verfasst von: Murat Ates, Mehmet Akif Serin, Sinan Calisskan

Erschienen in: Polymer Bulletin | Ausgabe 6/2019

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Abstract

In this study, the composite formations of polyaniline (PANI)/multi-walled carbon nanotube (MWCNT), poly(3,4-ethylenedioxythiophene) (PEDOT)/MWCNT, and poly(aniline-co-3,4-ethylenedioxythiophene) (P(ANI-co-EDOT))/MWCNT were synthesized on glassy carbon electrode by cyclic voltammetry (CV) method. The composite films were characterized by CV, Fourier transform infrared–attenuated reflection spectroscopy, Raman spectroscopy, scanning electron microscopy–energy-dispersive X-ray analysis, thermogravimetric analysis–differential thermal analysis, Brunauer–Emmett–Teller surface analysis, transmission electron microscopy and electrochemical impedance spectroscopy (EIS). The modified electrodes were characterized by CV, galvanostatic charge/discharge and EIS analysis to measure the capacitance, energy and power density values. The highest specific capacitance was obtained as Csp = 590.71 F/g for PANI/MWCNT at a scan rate of 50 mV/s by CV method. The PANI/MWCNT composites are promising electrode materials for high-performance electrical energy storage devices compared to PEDOT/MWCNT or P(ANI-co-EDOT)/MWCNT. The stability tests were also taken for nanocomposite films. PEDOT/MWCNT composites present excellent long cycle life with 97.44% specific capacitance retained after 500 cycles.

Graphical abstract

Vorheriger Artikel Building an electron push–pull system of linear conjugated polymers for improving photocatalytic hydrogen evolution efficiency
Nächster Artikel Advances in the synthesis of non-isocyanate polyurethanes

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Metadaten
Titel
Electrochemical supercapacitors of PANI/MWCNT, PEDOT/MWCNT and P(ANI-co-EDOT)/MWCNT nanocomposites
verfasst von
Murat Ates
Mehmet Akif Serin
Sinan Calisskan
Publikationsdatum
27.09.2018
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 6/2019
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-018-2539-z

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