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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 8/2020

05.03.2020

Fabrication and characterization of Zn-ion-conducting solid polymer electrolyte films based on PVdF-HFP/Zn(Tf)2 complex system

verfasst von: Jianghe Liu, Zeba Khanam, Ravi Muchakayala, Shenhua Song

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 8/2020

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Abstract

The present work is aimed at developing the Zn-ion-conducting solid polymer electrolyte (SPE) films based on PVdF-HFP/Zn(Tf)2 complex system via solution casting method. The structural and morphological characteristics of the as-prepared films are elucidated by X-ray diffraction and scanning electron microscopy. Further, impedance spectroscopy and cyclic voltammetry are performed to investigate their electrical and electrochemical properties. The structural analysis confirms that the PVdF-HFP is semi-crystalline and its amorphous domain increases with the addition of Zn(Tf)2 salt. The impedance results reveal that the ionic conductivity of the electrolyte film is raised up to a maximum value of 2.44 × 10–5 S cm−1 at room temperature when the mass ratio of Zn(Tf)2:PVdF-HFP is 0.4 (named as PE/Zn-4). However, further loading of salt degrades the overall properties of the film. Hence, the PE/Zn-4 system is regarded to be the optimal composition for efficient SPE films. Additionally, the PE/Zn-4 electrolyte exhibits sound thermal stability and mechanical properties. The electrochemical stability window of the PE/Zn-4 system is evaluated as approximately 3.45 V, being acceptable for energy storage applications. In addition, the present polymer electrolyte may well suppress the formation of Zn dendrites on Zn electrodes. Conclusively, the development of high-performance SPEs could be potentially very useful for the next-generation Zn-based devices.
Vorheriger Artikel High performance supercapacitor electrodes using functionalized CNTs/MoO3 with natural polysaccharide binders
Nächster Artikel Facile solvent deficient synthesis of mesoporous Co3O4 nanoparticles for electrochemical energy storage

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Metadaten
Titel
Fabrication and characterization of Zn-ion-conducting solid polymer electrolyte films based on PVdF-HFP/Zn(Tf)2 complex system
verfasst von
Jianghe Liu
Zeba Khanam
Ravi Muchakayala
Shenhua Song
Publikationsdatum
05.03.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 8/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-03169-1

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