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04.03.2021 | Original Research

Graft copolymerization of MA/(TFEA or TFPM) onto cellulosic fibers for surface hydrophobicity

verfasst von: Rongrong Liu, Qun Li, Jiaxuan Liu, Yan Duan, Ting Gao

Erschienen in: Cellulose | Ausgabe 7/2021

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Abstract

Highly hydrophobicity was imparted to cellulose paper substrate by grafting trifluoroethyl acrylate/methyl acrylate (TFEA/MA) and tetrafluoropropyl methacrylate/methyl acrylate (TFPM/MA) with Fenton reagent initiator (Fe²⁺–H₂O₂). The influences of modifications in chemical structure and hydrophobicity were examined. The chemical structure and surface morphology of the modified filter paper was characterized by FT-IR, XPS, solid-state ¹³C NMR, and SEM. The results from ¹³C NMR spectroscopy revealed that MA was mainly grafted onto cellulose C6-OH by selecting cellobiose as the model compound of cellulose. The water contact angle of the treated filter paper reached 139° and 145° with MA/TFPM grafting at MA:TFPM = 3:1 ratio and with MA/TFEA grafting at MA:TFEA = 3:1 ratio, respectively. The resulting highly hydrophobic paper was used to separate water from oil/water mixtures. The efficiency of separating water from their mixture with n-hexane, cyclohexane, ethyl acetate, and 1, 2-dichloroethane exceeded 90%.

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Vorheriger Artikel Lignocellulosic biomass and carbohydrates as feed-stock for scalable production of 5-hydroxymethylfurfural

Nächster Artikel Diffusion of polyethyleneimine with different molecular weights into cotton fibers at low concentration

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Titel: Graft copolymerization of MA/(TFEA or TFPM) onto cellulosic fibers for surface hydrophobicity
verfasst von: Rongrong Liu
Qun Li
Jiaxuan Liu
Yan Duan
Ting Gao
Publikationsdatum: 04.03.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 7/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-03773-2

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