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Erschienen in: Journal of Materials Science 11/2018

09.03.2018 | Energy materials

Hierarchical bicomponent TiO2 hollow spheres as a new high-capacity anode material for lithium-ion batteries

verfasst von: Ruiping Liu, Chao Shen, Chao Zhang, James Iocozzia, Qi Wang, Shiqiang Zhao, Kunjie Yuan, Zhiqun Lin

Erschienen in: Journal of Materials Science | Ausgabe 11/2018

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Abstract

Hierarchical TiO2-based hollow spheres were successfully synthesized via a hydrothermal method using FeSO4·7H2O, CoSO4·7H2O and ZnSO4·7H2O as soft templates. The as-prepared hollow spheres are well dispersed with the diameters of 2–4 μm. The shell and the interior surface of the spheres are composed of loosely packed grains, which provide a large specific surface area to facilitate lithium-ion diffusion processes. Among the three types of hybrid hollow spheres, TiO2/Fe2O3 shows the highest reversible capacity and best cycling stability (discharge capacities of 290.8 and 210.5 mAh/g were achieved after 100 cycles at 0.1C and 1C, respectively) and rate performance (from 461.1 mAh/g at 0.1C to 79.3 mAh/g at 5C with recovery to 288.6 mAh/g at 0.1C) for anode materials in lithium-ion batteries.

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Metadaten
Titel
Hierarchical bicomponent TiO2 hollow spheres as a new high-capacity anode material for lithium-ion batteries
verfasst von
Ruiping Liu
Chao Shen
Chao Zhang
James Iocozzia
Qi Wang
Shiqiang Zhao
Kunjie Yuan
Zhiqun Lin
Publikationsdatum
09.03.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 11/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2195-6

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