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Erschienen in: Journal of Materials Science 9/2019

31.01.2019 | Chemical routes to materials

In situ green preparation of silver nanoparticles/chemical pulp fiber composites with excellent catalytic performance

verfasst von: Hao Gong, Mengru Liu, Hailong Li

Erschienen in: Journal of Materials Science | Ausgabe 9/2019

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Abstract

In this paper, silver nanoparticles (Ag NPs) were successfully prepared in situ by chemical pulp fiber (CPF) without any additional reductants. In the green synthesis of Ag NPs, CPF acted as both a weak reductant and a stable carrier. The effect of different synthesis conditions was investigated, and the Ag NP load rate was up to 28.12 wt%. The size of the Ag NPs followed a standard Gaussian distribution, ranging from 10 to 50 nm, and a face-centered cubic structure was identified by XRD and TEM. In addition, the AgNPs/CPF composites exhibited good thermostability below 280 °C according to TG analysis. Owing to the high load rate and large specific surface area of Ag NPs, AgNPs/CPF composites exhibited excellent catalytic performance in the reduction of 4-nitrophenol to 4-aminophenol by NaBH4. The conversion rate was up to 95.91% after recycling 50 times, and the catalyst was easily separated from the reaction system. Based on the advantages of high conversion rate, excellent catalytic activity and reusability, AgNPs/CPF composites hold tremendous potential in eliminating nitrophenol and its derivatives from industrial pollution.

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Literatur
1.
Zurück zum Zitat Sharma VK, Yngard RA, Lin Y (2009) Silver nanoparticles: green synthesis and their antimicrobial activities. Adv Colloid Interface Sci 145:83–96CrossRef Sharma VK, Yngard RA, Lin Y (2009) Silver nanoparticles: green synthesis and their antimicrobial activities. Adv Colloid Interface Sci 145:83–96CrossRef
2.
Zurück zum Zitat El-Nour K, Eftaiha A, Al-Warthan A, Ammar RAA (2010) Synthesis and applications of silver nanoparticles. Arab J Chem 3:135–140CrossRef El-Nour K, Eftaiha A, Al-Warthan A, Ammar RAA (2010) Synthesis and applications of silver nanoparticles. Arab J Chem 3:135–140CrossRef
3.
Zurück zum Zitat Hsieh CT, Pan C, Chen WY (2011) Synthesis of silver nanoparticles on carbon papers for electrochemical catalysts. J Power Sources 196:6055–6061CrossRef Hsieh CT, Pan C, Chen WY (2011) Synthesis of silver nanoparticles on carbon papers for electrochemical catalysts. J Power Sources 196:6055–6061CrossRef
4.
Zurück zum Zitat Liu X, Cheng H, Cui P (2014) Catalysis by silver nanoparticles/porous silicon for the reduction of nitroaromatics in the presence of sodium borohydride. Appl Surf Sci 292:695–701CrossRef Liu X, Cheng H, Cui P (2014) Catalysis by silver nanoparticles/porous silicon for the reduction of nitroaromatics in the presence of sodium borohydride. Appl Surf Sci 292:695–701CrossRef
5.
Zurück zum Zitat Tsukamoto D, Shiro A, Shiraishi Y, Sugano Y, Ichikawa S, Tanaka S, Hirai T (2012) Photocatalytic H2O2 Production from Ethanol/O2 System Using TiO2 Loaded with Au–Ag Bimetallic Alloy Nanoparticles. Acs Catal 2:599–603CrossRef Tsukamoto D, Shiro A, Shiraishi Y, Sugano Y, Ichikawa S, Tanaka S, Hirai T (2012) Photocatalytic H2O2 Production from Ethanol/O2 System Using TiO2 Loaded with Au–Ag Bimetallic Alloy Nanoparticles. Acs Catal 2:599–603CrossRef
6.
Zurück zum Zitat Zheng LQ, Yu XD, Xu JJ, Chen HY (2014) Reversible catalysis for the reaction between methyl orange and NaBH4 by silver nanoparticles. Chem Commun 51:1050–1053CrossRef Zheng LQ, Yu XD, Xu JJ, Chen HY (2014) Reversible catalysis for the reaction between methyl orange and NaBH4 by silver nanoparticles. Chem Commun 51:1050–1053CrossRef
7.
Zurück zum Zitat Morones JR, Elechiguerra JL, Camacho A, Holt K, Kouri JB, Ramã-Rez JT, Yacaman MJ (2005) The bactericidal effect of silver nanoparticles. Nanotechnology 16:2346–2353CrossRef Morones JR, Elechiguerra JL, Camacho A, Holt K, Kouri JB, Ramã-Rez JT, Yacaman MJ (2005) The bactericidal effect of silver nanoparticles. Nanotechnology 16:2346–2353CrossRef
8.
Zurück zum Zitat Kim JS, Kuk E, Yu KN et al (2007) Antimicrobial effects of silver nanoparticles. Nanomed-Nanaotechnol 3:95–101CrossRef Kim JS, Kuk E, Yu KN et al (2007) Antimicrobial effects of silver nanoparticles. Nanomed-Nanaotechnol 3:95–101CrossRef
9.
Zurück zum Zitat Dong HW, Park KH, Seo JH et al (2011) Enhanced power conversion efficiency in PCDTBT/PC70BM Bulk heterojunction photovoltaic devices with embedded silver nanoparticle clusters. Adv Energy Mater 1:766–770CrossRef Dong HW, Park KH, Seo JH et al (2011) Enhanced power conversion efficiency in PCDTBT/PC70BM Bulk heterojunction photovoltaic devices with embedded silver nanoparticle clusters. Adv Energy Mater 1:766–770CrossRef
10.
Zurück zum Zitat Hakonen A, Andersson PO, Stenbæk SM, Rindzevicius T, Käll M (2015) Explosive and chemical threat detection by surface-enhanced Raman scattering: a review. Anal Chim Acta 893:1–13CrossRef Hakonen A, Andersson PO, Stenbæk SM, Rindzevicius T, Käll M (2015) Explosive and chemical threat detection by surface-enhanced Raman scattering: a review. Anal Chim Acta 893:1–13CrossRef
11.
Zurück zum Zitat Sondi I, Goia DV, Matijević E (2003) Preparation of highly concentrated stable dispersions of uniform silver nanoparticles. J Colloid Interface Sci 260:75–81CrossRef Sondi I, Goia DV, Matijević E (2003) Preparation of highly concentrated stable dispersions of uniform silver nanoparticles. J Colloid Interface Sci 260:75–81CrossRef
15.
Zurück zum Zitat Dong X, Ji X, Wu H, Zhao L, Li J, Yang W (2009) Shape control of silver nanoparticles by stepwise citrate reduction. J Phys Chem C 113:6573–6576CrossRef Dong X, Ji X, Wu H, Zhao L, Li J, Yang W (2009) Shape control of silver nanoparticles by stepwise citrate reduction. J Phys Chem C 113:6573–6576CrossRef
18.
Zurück zum Zitat Pol VG, Srivastava DN, Palchik O, Palchik V, Slifkin MA, Weiss AM, Gedanken A (2002) Sonochemical Deposition of Silver Nanoparticles on Silica Spheres. Langmuir 18:3352–3357CrossRef Pol VG, Srivastava DN, Palchik O, Palchik V, Slifkin MA, Weiss AM, Gedanken A (2002) Sonochemical Deposition of Silver Nanoparticles on Silica Spheres. Langmuir 18:3352–3357CrossRef
19.
Zurück zum Zitat Shahverdi AR, Minaeian S, Shahverdi HR, Jamalifar H, Nohi AA (2007) Rapid synthesis of silver nanoparticles using culture supernatants of Enterobacteria: a novel biological approach. Process Biochem 42:919–923CrossRef Shahverdi AR, Minaeian S, Shahverdi HR, Jamalifar H, Nohi AA (2007) Rapid synthesis of silver nanoparticles using culture supernatants of Enterobacteria: a novel biological approach. Process Biochem 42:919–923CrossRef
20.
Zurück zum Zitat Mukherjee P, Ahmad A, Mandal D et al (2001) Fungus-mediated synthesis of silver nanoparticles and their immobilization in the mycelial matrix: a novel biological approach to nanoparticle synthesis. Nano Lett 1:515–519CrossRef Mukherjee P, Ahmad A, Mandal D et al (2001) Fungus-mediated synthesis of silver nanoparticles and their immobilization in the mycelial matrix: a novel biological approach to nanoparticle synthesis. Nano Lett 1:515–519CrossRef
21.
Zurück zum Zitat Suman TY, Rajasree SRR, Kanchana A, Elizabeth SB (2013) Biosynthesis, characterization and cytotoxic effect of plant mediated silver nanoparticles using Morinda citrifolia root extract. Colloid Surface B 106:74–78CrossRef Suman TY, Rajasree SRR, Kanchana A, Elizabeth SB (2013) Biosynthesis, characterization and cytotoxic effect of plant mediated silver nanoparticles using Morinda citrifolia root extract. Colloid Surface B 106:74–78CrossRef
22.
Zurück zum Zitat Liu JF, Yu SJ, Yin YG, Chao JB (2012) Methods for separation, identification, characterization and quantification of silver nanoparticles. Trend Anal Chem 33:95–106CrossRef Liu JF, Yu SJ, Yin YG, Chao JB (2012) Methods for separation, identification, characterization and quantification of silver nanoparticles. Trend Anal Chem 33:95–106CrossRef
23.
Zurück zum Zitat Blaker JJ, Lee KY, Bismarck A (2011) Hierarchical composites made entirely from renewable resources. J Biobased Mater Bio 5:1–16CrossRef Blaker JJ, Lee KY, Bismarck A (2011) Hierarchical composites made entirely from renewable resources. J Biobased Mater Bio 5:1–16CrossRef
25.
Zurück zum Zitat Gessler K, Krauss N, Steiner T, Betzel C, Sandmann C, Saenger W (1994) Crystal structure of beta-d-cellotetraose hemihydrate with implications for the structure of cellulose II. Science 266:1027–1029CrossRef Gessler K, Krauss N, Steiner T, Betzel C, Sandmann C, Saenger W (1994) Crystal structure of beta-d-cellotetraose hemihydrate with implications for the structure of cellulose II. Science 266:1027–1029CrossRef
26.
Zurück zum Zitat Yang HP, Yan R, Chen HP, Zheng CG, Lee DH, Liang DT (2006) In-depth investigation of biomass pyrolysis based on three major components: hemicellulose, cellulose and lignin. Energy Fuel 20:388–393CrossRef Yang HP, Yan R, Chen HP, Zheng CG, Lee DH, Liang DT (2006) In-depth investigation of biomass pyrolysis based on three major components: hemicellulose, cellulose and lignin. Energy Fuel 20:388–393CrossRef
27.
Zurück zum Zitat Csóka L, Božanić DK, Nagy V, Dimitrijevićbranković S, Luyt AS, Grozdits G, Djoković V (2012) Viscoelastic properties and antimicrobial activity of cellulose fiber sheets impregnated with Ag nanoparticles. Carbohyd Polym 90:1139–1146CrossRef Csóka L, Božanić DK, Nagy V, Dimitrijevićbranković S, Luyt AS, Grozdits G, Djoković V (2012) Viscoelastic properties and antimicrobial activity of cellulose fiber sheets impregnated with Ag nanoparticles. Carbohyd Polym 90:1139–1146CrossRef
28.
Zurück zum Zitat Kamal T, Ahmad I, Khan SB, Asiri AM (2017) Synthesis and catalytic properties of silver nanoparticles supported on porous cellulose acetate sheets and wet-spun fibers. Carbohyd Polym 157:294–302CrossRef Kamal T, Ahmad I, Khan SB, Asiri AM (2017) Synthesis and catalytic properties of silver nanoparticles supported on porous cellulose acetate sheets and wet-spun fibers. Carbohyd Polym 157:294–302CrossRef
29.
Zurück zum Zitat He JH, Kunitake T, Nakao A (2003) Facile in situ synthesis of noble metal nanoparticles in porous cellulose fibers. Chem Mater 15:4401–4406CrossRef He JH, Kunitake T, Nakao A (2003) Facile in situ synthesis of noble metal nanoparticles in porous cellulose fibers. Chem Mater 15:4401–4406CrossRef
30.
Zurück zum Zitat Omrani AA, Taghavinia N (2012) Photo-induced growth of silver nanoparticles using UV sensitivity of cellulose fibers. Appl Surf Sci 258:2373–2377CrossRef Omrani AA, Taghavinia N (2012) Photo-induced growth of silver nanoparticles using UV sensitivity of cellulose fibers. Appl Surf Sci 258:2373–2377CrossRef
31.
Zurück zum Zitat Dan VG, Matijević E (1998) Preparation of monodispersed metal particles. New J Chem 22:1203–1215CrossRef Dan VG, Matijević E (1998) Preparation of monodispersed metal particles. New J Chem 22:1203–1215CrossRef
32.
Zurück zum Zitat Liz-Marzán LM (2004) Nanometals: formation and color. Mater Today 7:26–31CrossRef Liz-Marzán LM (2004) Nanometals: formation and color. Mater Today 7:26–31CrossRef
33.
Zurück zum Zitat Texier I, Rémita S, Pierre Archirel A, Mostafavi M (1996) Reduction of Ag 1 I (NH3) 2 + to Ag 1 0 (NH3)2 in solution. Redox potential and spectral study. J Phys Chem 100:12472–12476CrossRef Texier I, Rémita S, Pierre Archirel A, Mostafavi M (1996) Reduction of Ag 1 I (NH3) 2 + to Ag 1 0 (NH3)2 in solution. Redox potential and spectral study. J Phys Chem 100:12472–12476CrossRef
34.
Zurück zum Zitat Shrivastava S, Bera T, Roy A, Singh G, Ramachandrarao P, Dash D (2007) Characterization of enhanced antibacterial effects of novel silver nanoparticles. Nanotechnology 18:225103CrossRef Shrivastava S, Bera T, Roy A, Singh G, Ramachandrarao P, Dash D (2007) Characterization of enhanced antibacterial effects of novel silver nanoparticles. Nanotechnology 18:225103CrossRef
35.
Zurück zum Zitat Ahmad N, Sharma S, Alam MK, Singh VN, Shamsi SF, Mehta BR, Fatma A (2010) Rapid synthesis of silver nanoparticles using dried medicinal plant of basil. Colloid Surface B 81:81–86CrossRef Ahmad N, Sharma S, Alam MK, Singh VN, Shamsi SF, Mehta BR, Fatma A (2010) Rapid synthesis of silver nanoparticles using dried medicinal plant of basil. Colloid Surface B 81:81–86CrossRef
37.
Zurück zum Zitat Park SY, Baker JO, Himmel ME, Parilla PA, Johnson DK (2010) Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance. Biotechnol Biofuels 3:1–10CrossRef Park SY, Baker JO, Himmel ME, Parilla PA, Johnson DK (2010) Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance. Biotechnol Biofuels 3:1–10CrossRef
38.
Zurück zum Zitat Segal L, Creely JJ, Martin AEJ, Conrad AE (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794CrossRef Segal L, Creely JJ, Martin AEJ, Conrad AE (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794CrossRef
39.
Zurück zum Zitat Li RJ, Fei JM, Cai YR, Li YF, Feng JQ, Yao JM (2009) Cellulose whiskers extracted from mulberry: a novel biomass production. Carbohyd Polym 76:94–99CrossRef Li RJ, Fei JM, Cai YR, Li YF, Feng JQ, Yao JM (2009) Cellulose whiskers extracted from mulberry: a novel biomass production. Carbohyd Polym 76:94–99CrossRef
40.
Zurück zum Zitat Chou KS, Lu YC (2007) The application of nanosized silver colloids in far infrared low-emissive coating. Thin Solid Films 515:7217–7221CrossRef Chou KS, Lu YC (2007) The application of nanosized silver colloids in far infrared low-emissive coating. Thin Solid Films 515:7217–7221CrossRef
41.
Zurück zum Zitat Hu S, Hsieh YL (2015) Synthesis of surface bound silver nanoparticles on cellulose fibers using lignin as multi-functional agent. Carbohyd Polym 131:134–141CrossRef Hu S, Hsieh YL (2015) Synthesis of surface bound silver nanoparticles on cellulose fibers using lignin as multi-functional agent. Carbohyd Polym 131:134–141CrossRef
42.
Zurück zum Zitat Abdel-Mohsen AM, Hrdina R, Burgert L et al (2013) Antibacterial activity and cell viability of hyaluronan fiber with silver nanoparticles. Carbohyd Polym 92:1177–1187CrossRef Abdel-Mohsen AM, Hrdina R, Burgert L et al (2013) Antibacterial activity and cell viability of hyaluronan fiber with silver nanoparticles. Carbohyd Polym 92:1177–1187CrossRef
Metadaten
Titel
In situ green preparation of silver nanoparticles/chemical pulp fiber composites with excellent catalytic performance
verfasst von
Hao Gong
Mengru Liu
Hailong Li
Publikationsdatum
31.01.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 9/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-03205-w

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