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Erschienen in: Journal of Materials Science: Materials in Electronics 13/2021

06.06.2021

Influence of V/Ni-doping on electrical properties and aging stability of ZnFe2O4-based NTC ceramics

verfasst von: Wenbin Hao, Hong Zhang, Caiyun Gao, Bicai Li, Zhiyuan Ma, Zhicheng Li

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 13/2021

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Abstract

V/Ni co-doped zinc ferrite (Zn1-yNiyFe2-xVxO4, x = 0.01, 002, 0.03, 0.04, 0.05; y = 0.05, 015, 0.25) ceramics were prepared by solid-state reaction method. The effect of V and Ni contents on the electrical property and aging property of the ceramics were investigated. All the ceramics have a cubic spinel structure and show typical characteristics of negative temperature coefficient (NTC) of resistivity. For being doped with various V and Ni contents, the room temperature resistivities (ρ25) of the ceramics range from 0.037 MΩ·cm to 4.8 MΩ·cm, and NTC material constants (B values) vary between 3255 K and 6614 K. The Zn1-yNiyFe2-xVxO4 ceramic with x = 0.04 and y = 0.15 has high electrical stability with a resistance drift rate of 0.19% after having been aged at 150 °C for 500 h in air. The aging characteristic was investigated by analyzing cationic valences using X-ray photoelectron spectroscopy before and after aging treatment.

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Metadaten
Titel
Influence of V/Ni-doping on electrical properties and aging stability of ZnFe2O4-based NTC ceramics
verfasst von
Wenbin Hao
Hong Zhang
Caiyun Gao
Bicai Li
Zhiyuan Ma
Zhicheng Li
Publikationsdatum
06.06.2021
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 13/2021
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-021-06316-4

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